Tensile modulus of polymer halloysite nanotubes nanocomposites assuming stress transferring through an imperfect interphase.

In this work, Hui-Shia model is developed to reveal the efficiency of a deficient interphase on the tensile modulus of polymer halloysite nanotube (HNT) nanocomposites. "Lc" as essential HNT length providing full stress transferring is defined and effective HNT size, effective HNT concentration, and efficiency of stress transferring (Q) are expressed by "Lc". Furthermore, the influences of all terms on the "Q" and nanocomposite's modulus are clarified, and also the calculations of the model are linked to the tested data of some nanocomposites. Original Hui-Shia model overpredicts the moduli, but the innovative model's predictions appropriately fit the measured data. Lc = 200 nm maximizes the sample's modulus to 2.6 GPa, but the modulus reduces to 2.11 GPa at Lc = 700 nm. Therefore, there is a reverse relation between the sample's modulus and "Lc". Q = 0.5 produces the system's modulus of 2.1 GPa, while the modulus of 2.35 GPa is achieved at Q = 1 providing a direct relation between the nanocomposite's modulus and "Q". Generally, narrow and big HNTs, along with a low "Lc", enhance the "Q", because a lower "Lc", reveals a tougher interphase improving the stress transferring.

Preparation and Stability Study of an Injectable Hydrogel for Artificial Intraocular Lenses.

Currently available intraocular lenses (IOLs) on the market often differ significantly in elastic modulus compared to the natural human lens, which impairs their ability to respond effectively to the tension of the ciliary muscles for focal adjustment after implantation. In this study, we synthesized a polyacrylamide-sodium acrylate hydrogel (PAH) through the cross-linking polymerization of acrylamide and sodium acrylate. This hydrogel possesses excellent biocompatibility and exhibits several favorable properties. Notably, the hydrogel demonstrates high transparency (94%) and a refractive index (1.41 ± 0.07) that closely matches that of the human lens (1.42). Additionally, it shows strong compressive strength (14.00 kPa), good extensibility (1400%), and an appropriate swelling ratio (50 ± 2.5%). Crucially, the tensile modulus of the hydrogel is 2.07 kPa, which closely aligns with the elastic modulus of the human lens (1.70-2.10 kPa), enabling continuous focal adjustment under the tension exerted by the ciliary muscles.

A novel technique including two steps for modulus prediction in polymer halloysite nanotube composites.

A two-step methodology has been developed utilizing the models of Paul and Takayanagi to determine the modulus of polymer halloysite nanotube (HNT) products. Initially, HNTs and the adjacent interphase are considered as pseudoparticles, and their modulus is evaluated using the Paul model. Subsequently, the modulus of a nanocomposite, consisting of a polymer medium and pseudoparticles, is predicted by Takayanagi equation. The impacts of various factors on the modulus of the products are analyzed, and the results from the two-step method are compared with experimental data from different samples. It has been observed that the modulus of samples progressively increases with an increase in interphase depth. Also, a higher interphase modulus contributes to an enhanced modulus of samples. Nevertheless, excessively high interphase moduli (Ei > 60 GPa) result in only a marginal improvement in the modulus of nanocomposites. Additionally, narrower HNTs are advantageous for producing stronger samples, though the modulus of the nanocomposites slightly diminishes at very high HNT radii (R > 55 nm). The outputs of two-step method agree with the experimental moduli of various HNT-filled systems.

Morphology-Driven Nanofiller Size Measurement Integrated with Micromechanical Finite Element Analysis for Quantifying Interphase in Polymer Nanocomposites.

This study focused on an innovative practical method using computer vision for particle size measurement, which serves as a key precursor for predicting the elastic modulus of polymer nanocomposites. This approach involved the morphological segmentation of the nanodispersed phase. It aimed, for the first time, to address the impractical conditions resulting from the assumption of idealized single-particle sizes in a monodispersed system during modeling. Subsequently, a micromechanical finite element framework was employed to determine the interphase thickness and modulus in ultrahigh molecular weight polyethylene/nanozeolite composites, following the quantification of nanoparticle sizes. The size measurement approach relied on morphological images extracted from scanning electron microscopy micrographs of impact-fractured surfaces. To compute the interphase thickness, experimental data was fitted to an interphase-inclusive upper-bound Hashin-Shtrikman model, with the measured average particle size per composition serving as a crucial input. Subsequently, the interphase elastic modulus was computed based on its thickness, employing a hybrid modified-Hashin-Hansen and Maxwell model. These estimated interfacial variables were then utilized as inputs for the finite element model to determine the tensile modulus. A comparison between the model results and measured data revealed a maximum discrepancy of 3.29%, indicating the effectiveness of the methodology employed in quantifying interfacial properties.

Harnessing oriented arrangement of collagen fibers by 3D printing for enhancing mechanical and osteogenic properties of mineralized collagen scaffolds.

As the structural basis of connective and load-bearing tissues, collagen fibers with orientation play an important role in the mechanical properties and physiological and biochemical functions of the tissues, but viable methods for preparing scaffolds with highly oriented collagenous structure still need to be further studied. In this study, pure collagen was used as printing ink to 3D printing. Harnessing oriented collagen fiber structure by 3D printing for promoting mechanical and osteogenic properties of scaffolds. The scaffolds with different printed angles and thicknesses were prepared to fit the bone defect site and realize personalized customization. The orientation assembly of collagen fibers was promoted by shear force action of 3D printing, the regular arrangement of collagen fibers and stabilization of fiber structure were promoted by pH adjustment and glutaraldehyde cross-linking, and the collagen fibers were mineralized by cyclic mineralization method. The microscopic morphology of fiber arrangement in the scaffolds were investigated by scanning electron microscopy. Results demonstrated that collagen fibers were changed from non-oriented to oriented after 3D printing. And the tensile modulus of the scaffolds with oriented collagen fibers was nine times higher than that of the scaffolds with non-oriented fibers. Moreover, the effects of oriented collagen fibers on the proliferation, differentiation and mineralization of MC3T3-E1 cells were studied by CCK-8 assay, live/dead cell staining, alkaline phosphatase activity test, and Alizarin red staining. The results indicated that cell proliferation, differentiation and mineralization were significantly promoted by oriented collagen fibers, and the cells proliferated directionally in the direction of the fibers. Taken together, mineralized collagen fiber scaffolds with oriented collagen fibers have great potential in bone tissue engineering applications.

Analysis of Weld Lines in Micro-Injection Molding.

Micro-injection molding (µIM) is a widespread process for the production of plastic parts with at least one dimension, or feature, in the microscale (conventionally below 500 µm). Despite injection molding being recognized as a robust process for obtaining parts with high geometry accuracy, one last occurrence remains a challenge in micro-injection molding, especially when junctions are present on the parts: the so-called weld lines. As weld lines are crucial in determining mechanical part performances, it is mandatory to clarify weld line position and characteristics, especially at the industrial scale during mold design, to limit failure causes. Many works deal with weld lines and their dependence on processing parameters for conventional injection molding, but only a few works focus on the weld line in µIM. This work examines the influence of mold temperature on the weld line position and strength by both experimental and simulation approaches in µIM. At mold temperatures below 100 °C, only short shots were obtained in the chosen cavity. At increased mold temperatures, weld lines show up to a 40% decrease in the whole length, and the overall tensile modulus doubles. This finding can be attributed to the reduction of the orientation at the weld line location favored by high mold temperatures. Moldflow simulations consistently reproduce the main features of the process, weld line position and length. The discrepancy between experimental and simulated results was attributed to the fact that crystallization in flow conditions was not accounted for in the model.

Effects of Polishing and Artificial Aging on Mechanical Properties of Dental LT Clear® Resin.

Three-dimensional printing has become incorporated into various aspects of everyday life, including dentistry. Novel materials are being introduced rapidly. One such material is Dental LT Clear by Formlabs, a resin used for manufacturing occlusal splints, aligners, and orthodontic retainers. In this study, a total of 240 specimens, comprising two shapes (dumbbell and rectangular), were evaluated through compression and tensile tests. The compression tests revealed that the specimens were neither polished nor aged. However, after polishing, the compression modulus values decreased significantly. Specifically, the unpolished and nonaged specimens measured 0.87 ± 0.02, whereas the polished group measured 0.086 ± 0.03. The results were significantly affected by artificial aging. The polished group measured 0.73 ± 0.05, while the unpolished group measured 0.73 ± 0.03. In contrast, the tensile test proved that the specimens showed the highest resistance when the polishing was applied. The artificial aging influenced the tensile test and reduced the force needed to damage the specimens. The tensile modulus had the highest value when polishing was applied (3.00 ± 0.11). The conclusions drawn from these findings are as follows: 1. Polishing does not change the properties of the examined resin. 2. Artificial aging reduces resistance in both compression and tensile tests. 3. Polishing reduces the damage to the specimens in the aging process.

Comparison of the tensile modulus of three 3D-printable materials used in dentistry.

BACKGROUND: Three-dimensional (3D) printing technology has brought much innovation to medicine and has been successfully adopted in many areas of dentistry. Although 3D printing techniques are being increasingly used, their advantages and disadvantages still need to be investigated, particularly with regard to the materials used in dentistry. Dental materials should be biocompatible and non-cytotoxic, and have sufficient mechanical integrity in the oral environment in which they are intended for use. OBJECTIVES: The present work aimed to identify and compare the mechanical properties of three 3D-printable resins. The materials included IBT Resin, BioMed Amber Resin and Dental LT Clear Resin. The Formlabs Form 2 printer was used. MATERIAL AND METHODS: A tensile strength test was performed on 10 specimens of each resin. Tensile modulus was measured on 2-millimeter-thick dumbbell-shaped specimens, 75 mm in length and 10 mm in width. The 10 specimens of each resin were mounted between the grips of a universal testing machine (Z10-X700). RESULTS: The results showed that BioMed Amber specimens cracked easily, yet no deformation was observed. The amount of force used to test the tensility of the specimens was the lowest for IBT Resin, while it was the highest for Dental LT Clear Resin. CONCLUSIONS: IBT Resin was the weakest material, whereas Dental Clear LT Resin was the strongest.

The Influence of Polishing and Artificial Aging on BioMed Amber® Resin's Mechanical Properties.

Currently, 3D print is becoming more common in all branches of medicine, including dentistry. Some novel resins, such as BioMed Amber (Formlabs), are used and incorporated to more advanced techniques. The aims of the study were to check whether or not polishing and/or artificial aging influences the properties of the 3D-printed resin. A total of 240 specimens of BioMed Resin were printed. Two shapes (rectangular and dumbbell) were prepared. Of each shape, 120 specimens were divided into four groups each (with no influence, after polishing only, after artificial aging only, and after both polishing and artificial aging). Artificial aging took place in water at the temperature of 37 °C for 90 days. For testing, the universal testing machine (Z10-X700, AML Instruments, Lincoln, UK) was used. The axial compression was performed with the speed of 1mm/min. The tensile modulus was measured with the constant speed of 5 mm/min. The highest resistance to compression and tensile test were observed in the specimens that were neither polished nor aged (0.88 ± 0.03 and 2.88 ± 0.26, respectively). The lowest resistance to compression was observed in the specimens that were not polished, but aged (0.70 ± 0.02). The lowest results of the tensile test were observed when specimens were both polished and aged (2.05 ± 0.28). Both polishing and artificial aging weakened the mechanical properties of the BioMed Amber resin. The compressive modulus changed much with or without polishing. The tensile modulus differed in specimens that were either polished or aged. The application of both did not change the properties when compared to the polished or aged probes only.

Evaluation of tensile properties of spherical shaped SiC inclusions inside recycled HDPE matrix using FEM based representative volume element approach.

In the current study, a FEM-based representative volume element (RVE) technique is used to evaluate the elastic modulus of recycled high-density polyethylene (rHDPE) filled spherical-shaped shaped silicon carbide (SiC). In the ANSYS 2019, the material designer (MD) module is used to generate a 3D RVE of 500 × 500 × 500 µm cuboid, with randomly dispersed spherical SiC particles (i.e., 10, 15, 20, and 30% volume fractions) inside rHDPE. The Young's modulus values extracted from the RVE technique at various volume % are substantially nearer to experimental data than other micromechanical models. The tensile performance of the composite is simulated, and it was noted that the maximum equivalent stress of 4.1133 MPa for rHDPE/30% SiC composite, which is decreased to 13.8, 7.8 and 6.8% for rHDPE/10% SiC, rHDPE/15% SiC and rHDPE/20% SiC composite respectively. The results are astounding for immediate application in the relevant field of interest.

A New Approach to the Structure-Properties Relationships Determination for Porous Filled Reinforced Materials.

This study describes a new mathematical approach to the relationship between mechanical properties (tensile modulus, ultimate strength, and strain), composition as well as structure of porous-filled reinforced composites. The composite system consisted of a polyurethane matrix, a rubber filler, and a small amount of polyethylene terephthalate as a reinforcement. The newly proposed equations are based on a special mixing rule with the same basic form for all studied properties. The mixing rule contains a correction parameter η, which differs in different filler content in the filled part of the composite. Here, a cubic exponential function including the product of suitable structural parameters and exponents ensuring the best fitting and describable by matrix properties were successfully defined to fit the different values of correction parameter. The proposed equations should be a suitable step to obtain a relationship for describing the mechanical behavior of porous-filled and reinforced composites in the case of a small amount of reinforcement.

Evaluation of Moisture Damage Potential in Hot Mix Asphalt Using Polymeric Aggregate Treatment.

To enhance the moisture damage performance of hot mix asphalt (HMA), treating the aggregate surface with a suitable additive was a more convenient approach. In this research, two types of aggregate modifiers were used to study the effect of moisture damage on HMA. Three different aggregate sources were selected based on their abundance of use in HMA. To study the impact of these aggregate modifiers on moisture susceptibility of HMA, the indirect tensile strength test and indirect tensile modulus test were used as the performance tests. Moisture conditioning of specimens was carried out to simulate the effect of moisture on HMA. The prepared samples' tensile strength ratio (TSR) and stiffness modulus (Sm) results indicated a decrease in the strength of the HMA after moisture conditioning. After treating the aggregate surface with additives, an improvement was seen in dry and wet strength and stiffness. Moreover, an increasing trend was observed for both additives. The correlation between TSR and strength loss reveals a strong correlation (R2 = 0.7219). Also, the two additives indicate increased wettability of asphalt binder over aggregate, thus improving the adhesion between aggregate and asphalt binder.

In-Situ Synchrotron SAXS and WAXS Investigation on the Deformation of Single and Coaxial Electrospun P(VDF-TrFE)-Based Nanofibers.

Coaxial core/shell electrospun nanofibers consisting of ferroelectric P(VDF-TrFE) and relaxor ferroelectric P(VDF-TrFE-CTFE) are tailor-made with hierarchical structures to modulate their mechanical properties with respect to their constituents. Compared with two single and the other coaxial membranes prepared in the research, the core/shell-TrFE/CTFE membrane shows a more prominent mechanical anisotropy between revolving direction (RD) and cross direction (CD) associated with improved resistance to tensile stress for the crystallite phase stability and good strength-ductility balance. This is due to the better degree of core/shell-TrFE-CTFE nanofiber alignment and the crystalline/amorphous ratio. The coupling between terpolymer P(VDF-TrFE-CTFE) and copolymer P(VDF-TrFE) is responsible for phase stabilization, comparing the core/shell-TrFE/CTFE with the pristine terpolymer. Moreover, an impressive collective deformation mechanism of a two-length scale in the core/shell composite structure is found. We apply in-situ synchrotron X-ray to resolve the two-length scale simultaneously by using the small-angle X-ray scattering to characterize the nanofibers and the wide-angle X-ray diffraction to identify the phase transformations. Our findings may serve as guidelines for the fabrication of the electrospun nanofibers used as membranes-based electroactive polymers.

Compressive and Tensile Elastic Properties of Concrete: Empirical Factors in Span Reinforced Structures Design.

Concretes with the same strength can have various deformability that influences span structures deflection. In addition, a significant factor is the non-linear deformation of concrete dependence on the load. The main deformability parameter of concrete is the instantaneous modulus of elasticity. This research aims to evaluate the relation of concrete compressive and tensile elastic properties testing. The beam samples at 80 × 140 × 1400 cm with one rod Ø8 composite or Ø10 steel reinforcement were experimentally tested. It was shown that instantaneous elastic deformations under compression are much lower than tensile. Prolonged elastic deformations under compression are close to tensile. It results in compressive elasticity modulus exceeding the tensile. The relation between these moduli is proposed. The relation provides operative elasticity modulus testing by the bending tensile method. The elasticity modulus's evaluation for the reinforced span structures could be based only on the bending testing results. A 10% elasticity modulus increase, which seems not significant, increases at 30-40% the stress of the reinforced span structures under load and 30% increases the cracking point stress.

Influence of Microfibrillated Cellulose Additive on Strength, Elastic Modulus, Heat Release, and Shrinkage of Mortar and Concrete.

This work aimed to study the effect of a microfibrillated cellulose additive on strength, elastic modulus, heat release, and shrinkage of mortar and concrete. The dosage of the additive varies from 0.4 to 4.5% by weight of the cement. The change in strength with an increase in the dosage of the additive occurred in a wave-like manner. The uneven character of the change in the results also took place in the determination of heat release and shrinkage. In general, heat release and shrinkage decreased at increasing additive dosage. The additive showed the greatest decrease in the heat release of concrete at a content of 2%. The heat release of concrete practically differed little from the exotherm of the standard at an additive content of 1 and 1.5%. The addition of microfibrillated cellulose additive in small (0.5%) and large (1.5%) amounts reduced shrinkage compared to the reference, and at an intermediate content (1%), the shrinkage was higher than in the reference specimens. In this case, the water evaporation rate from concrete increased with an increase in the additive. With an increase in the additive dosage, the modulus of elasticity decreases. Thus, the microfibrillated cellulose additive provides concrete with lower values of the modulus of elasticity, heat release, and shrinkage, and the additive is recommended for use in concretes with increased crack resistance during the hardening period. The recommended additive content is 0.5% by weight of cement. At the specified dosage, it is possible to provide the class of concrete in terms of compressive strength C35/45.

Investigation of Wood Flour Size, Aspect Ratios, and Injection Molding Temperature on Mechanical Properties of Wood Flour/Polyethylene Composites.

In the present research, wood flour reinforced polyethylene polymer composites with a coupling agent were prepared by injection molding. The effects of wood flour size, aspect ratios, and mold injection temperature on the composites' mechanical properties were investigated. For the preparation of the polymer composites, five different formulations were created. The mechanical properties including tensile strength and the modulus, flexural strength and the modulus, and impact energy were measured. To investigate the changes in the properties resulting from different compositions, mechanical static and impact testing was performed. The obtained results indicate that by reducing the flour size, the tensile strength and modulus, flexural strength, and impact energy were reduced. In contrast, the flexural modulus increased. Furthermore, with the increment of injection molding temperature, the tensile strength and the modulus and the impact energy of the specimens were reduced. On the other hand, the flexural strength and the modulus increased. Thus, an optimized amount of injection molding temperature can provide improvements in the mechanical properties of the composite.

The effect of multiple freeze-thaw cycles on the viscoelastic properties and microstructure of bovine superficial digital flexor tendon.

The most common injuries of the human musculoskeletal system are related to soft tissue structures such as tendons or ligaments. To repair torn structures, surgical intervention and application of a biological or synthetic graft may be required. A typical procedure for the processing, storage, and distribution of soft tissue grafts involves at least two freezing/thawing (F/T) cycles. Even though repeated F/T cycles decrease the mechanical performance and change the structure of tendons, it is unclear whether there exists a maximum number of F/T cycles above which tendons should not be approved for use as a tissue allograft. To fill this research gap, we present an ex vivo study on the effects of repetitive F/T cycles on the biomechanical stability of bovine superficial digital flexor tendon tissue. Using mechanical testing supported with scanning electron microscopy imaging, we show that multiple F/T cycles affect the viscoelastic and structural properties of tissue by significantly reducing its tensile modulus after the 3rd or 4th F/T cycle (depending on the strain range), stress drop during relaxation after the 8th F/T cycle (regardless the strain values), mechanical hysteresis after the 10th F/T cycle, and by causing a significant decrease in collagen fibril diameter. Our results provide a deeper insight into understanding the mechanisms responsible for tissue damage during multiple F/T cycles, and thus, may be useful for the future optimization of tissue storage protocols.

Mechanical Properties of a Chiral Cellular Structure with Semicircular Beams.

Compliant cellular structures are good candidates for morphing applications. This paper proposes a novel chiral cellular structure composed of circular beams with great elastic properties and potential for morphing. The tensile and shear elastic properties of the structure are studied through theoretical derivations and then verified by finite element analysis. Results show that this novel chiral structure exhibits extremely low in-plane tensile and shear moduli, which are many orders of magnitude lower than that of the raw material. The structure also shows tensile-shear and shear-tensile coupling effects that cannot be ignored. The tensile and shear properties of the structure can provide a reference for employing this structure in engineering applications.

Tunable Mechanical and Electrical Properties of Coaxial Electrospun Composite Nanofibers of P(VDF-TrFE) and P(VDF-TrFE-CTFE).

The coaxial core/shell composite electrospun nanofibers consisting of relaxor ferroelectric P(VDF-TrFE-CTFE) and ferroelectric P(VDF-TrFE) polymers are successfully tailored towards superior structural, mechanical, and electrical properties over the individual polymers. The core/shell-TrFE/CTFE membrane discloses a more prominent mechanical anisotropy between the revolving direction (RD) and cross direction (CD) associated with a higher tensile modulus of 26.9 MPa and good strength-ductility balance, beneficial from a better degree of nanofiber alignment, the increased density, and C-F bonding. The interfacial coupling between the terpolymer P(VDF-TrFE-CTFE) and copolymer P(VDF-TrFE) is responsible for comparable full-frequency dielectric responses between the core/shell-TrFE/CTFE and pristine terpolymer. Moreover, an impressive piezoelectric coefficient up to 50.5 pm/V is achieved in the core/shell-TrFE/CTFE composite structure. Our findings corroborate the promising approach of coaxial electrospinning in efficiently tuning mechanical and electrical performances of the electrospun core/shell composite nanofiber membranes-based electroactive polymers (EAPs) actuators as artificial muscle implants.

Studies on Glass Fiber-Reinforced Poly(Ethylene-Grafted-Styrene)-Based Cation Exchange Membrane Composite.

To improve interfacial adhesion between glass fiber (GF) and poly(ethylene-grafted-styrene)-based cation exchange membranes (CEM), GF was modified by four coupling agents: [3-(Methacryloxy)propyl] trimethoxy silane (3-MPS), 1,6-bis (trimethoxysilyl) hexane (1,6 bis), Poly(propylene-graft-maleic anhydride) (PP-g-MA) and Triethoxyvinylsilane (TES). The results indicated the addition of modified GF increased tensile strength, tensile modulus, storage modulus and interfacial adhesion of GF/CEM composite but degraded the strains. The composite with 3-MPS modified GF obtained superior mechanical properties and interfacial adhesion, whereas the modified effect of TES was inconspicuous. The addition of unmodified GF even had negative effects on GF/CEM mechanical properties. The field emission scanning electron microscopes (FE-SEM) showed that the GF treated by 3-MPS and PP-g-MA have better compatibility with the CEM matrix than 1,6 bis and TES-treated GF. The Fourier-transform infrared spectroscopy (FT-IR) verified that the strengthening effects from modified GF were attributed to the formation of Si-O-Si and Si-O-C bonds. The additions of modified GF in CEM positively influence water uptake ability but negatively influence ion exchange capacity (IEC). This research provided a way of strengthening GF/CEM composite and pointed out which functional groups included in coupling agents could be useful to GF-reinforced composite.