ABSTRACT
The rapid popularization of wearable electronics, soft robots and implanted medical devices has stimulated extensive research in flexible batteries, which are bendable, foldable, knittable, wearable, and/or stretchable. Benefiting from these distinct characteristics, flexible batteries can be seamlessly integrated into various wearable/implantable devices, such as smart home systems, flexible displays, and implantable sensors. In contrast to conventional lithium-ion batteries necessitating the incorporation of stringent current collectors and packaging layers that are typically rigid, flexible batteries require the flexibility of each component to accommodate diverse shapes or sizes. Accordingly, significant advancements have been achieved in the development of flexible electrodes, current collectors, electrolytes, and flexible structures to uphold superior electrochemical performance and exceptional flexibility. In this review, typical structures of flexible batteries are firstly introduced and classified into mono-dimensional, two-dimensional, and three-dimensional structures according to their configurations. Subsequently, five distinct types of flexible batteries, including flexible lithium-ion batteries, flexible sodium-ion batteries, flexible zinc-ion batteries, flexible lithium/sodium-air batteries, and flexible zinc/magnesium-air batteries, are discussed in detail according to their configurations, respectively. Meanwhile, related comprehensive analysis is introduced to delve into the fundamental design principles pertaining to electrodes, electrolytes, current collectors, and integrated structures for various flexible batteries. Finally, the developments and challenges of flexible batteries are summarized, offering viable guidelines to promote the practical applications in the future.