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1.
Sci Total Environ ; : 174481, 2024 Jul 03.
Article in English | MEDLINE | ID: mdl-38969132

ABSTRACT

To shift towards low-fossil carbon economies, making more out of residual biomass is increasingly promoted. Yet, it remains unclear if implementing advanced technologies to reuse these streams really achieves net environmental benefits compared to current management practices. By integrating spatially-explicit resource flow analysis, consequential life cycle assessment (LCA), and uncertainty analysis, we propose a single framework to quantify the residual biomass environmental baseline of a territory, and apply it to the case of France. The output is the environmental threshold that a future large-scale territorial bioeconomy strategy should overpass. For France, we estimate the residual biomass baseline to generate 18.4 ±â€¯2.7 MtCO2-eq·y-1 (climate change), 255 ±â€¯35 ktN-eq·y-1 (marine eutrophication), and 12,300 ±â€¯800 disease incidences per year (particulate matter formation). The current use of crop residues and livestock effluents, being essentially a return to arable lands, was found to represent more than 90 % of total environmental impacts and uncertainties, uncovering a need for more certain data. At present, utilizing residual streams as organic fertilizers fulfills over half of France's total phosphorus (P) and potassium (K) demands. However, it only meets 6 % of the nitrogen demand, primarily because nitrogen is lost through air and water. This, coupled with the overall territorial diagnosis, led us to revisit the idea of using the current situation (based on 2018 data) as a baseline for future bioeconomy trajectories. We suggest that these should rather be compared to a projected baseline accounting for ongoing basic mitigation efforts, estimated for France at 8.5 MtCO2-eq·y-1.

2.
Article in English | MEDLINE | ID: mdl-38970630

ABSTRACT

A growing amount of waste electrical and electronic equipment (WEEE) indicates the need to verify the effectiveness of its management both nationally and globally. An analysis of the WEEE economy in Poland conducted over 5 years confirmed a 16.64% increase in the mass of collected equipment. The maximum annual mass of electrical and electronic equipment introduced to the market during this period was 607,240 Mg, with the average value exceeding 500,000 Mg. The WEEE category with the largest collected mass was waste code 20 01 36, which exceeded 235,000 Mg, whilst the highest waste weight accumulation rate of 45.98 kg per capita was recorded in one of the smallest voivodeships in Poland. This result showed the diversity of WEEE accumulation on a national scale. Overall, a noticeable increase in the WEEE accumulation rate has occurred as Poland's gross domestic product has increased, despite a decreasing population. An analysis based on the waste accumulation indicators, including socioeconomic factors, confirmed the need to develop forms of WEEE recovery and recycling to transition to a circular economy and promote the synergy of activities amongst all players in WEEE management.

3.
Article in English | MEDLINE | ID: mdl-38971893

ABSTRACT

Biomass energy is a type of renewable energy and animal waste is one of the main resources for its production. The purpose of this study is to investigate the effect of raw material type (cow and chicken manure) and the type of reactor (digester) on the biogas produced by measuring the amount of methane in the product. Three types of digester (metal, simple PVC, and PVC with leachate rotation) with the same volume (10 L) were prepared. Equipment was installed on the digesters to measure the pH and volume of produced gas. The experiments were carried out in controlled temperature conditions (28-30 °C) and in two stages. The first experiment was to load the digesters with cow excrement, and the second experiment was to load the digesters with chicken excrement. In both experiments, the digesters were fed with 1.5 kg of animal manure and water with a ratio of 1:1. During a period of 60 days, the volume of biogas and methane produced was measured and recorded. The results showed that the amount of biogas produced from chicken waste is more than the amount obtained from cow waste. However, the amount of methane produced using cow excrement was more than that of chicken excrement. Also, the performance of PVC digester with leachate rotation was better than the other two digesters, which could be due to the mixing of raw materials in this type of digester.

4.
Cureus ; 16(6): e61823, 2024 Jun.
Article in English | MEDLINE | ID: mdl-38975390

ABSTRACT

CONTEXT:  The generation of biomedical waste (BMW) in hospitals presents a significant hazard to both healthcare workers (HCWs) and the environment. The management of BMW is a challenge regarding inappropriate behavior among HCWs, leading to improper segregation of the BMW, which deserves attention. The indiscriminate BMW management issue in India has attracted the attention of the highest judicial bodies. The rise in the incidence of needle stick injuries is a severe threat to waste handlers and is mainly due to improper segregation practices. AIM: This study aimed to identify the challenges in BMW management in the institute and develop a strategy to improve the knowledge and practices of healthcare professionals (HCPs) in BMW management. METHODOLOGY:  A process-based intervention was developed and implemented that involved facility inspection rounds, focused group discussions with HCWs, preparation of information, education, and communication (IEC) materials, signage, staff training, and improved infrastructure and supplies for waste collection. A questionnaire-based evaluation of the staff's knowledge of BMW management was conducted, and the impact of the intervention was assessed from the hospital infection control audit reports. RESULTS:  Multiple reasons for poor compliance with BMW segregation practices were identified, and it improved from 57% to 91% with interventions. A significant difference was noted in the knowledge level of staff before and after the interventions. Post-intervention score was highest among the nurses (98.5%), followed by sanitation staff (92.7%), doctors (89.25%), and paramedics (81.7%). CONCLUSIONS:  Incorrect segregation practices of BMW and incidents of occupational exposure to blood and body fluids are reduced with interventions in the study. Robust supply chain management with regular training of staff is vital to ensure compliance in BMW management.

5.
J Environ Manage ; 366: 121758, 2024 Jul 09.
Article in English | MEDLINE | ID: mdl-38986372

ABSTRACT

The agricultural processing industry produces a large amount of waste on a global scale whose disposal is simultaneously a nuisance and of special interest. The by-products are rich in bioactive phytoconstituents that might be beneficial to the production of bio-functional textiles. The present work uses agricultural wastes for the eco-friendly dyeing of woolen yarns. Response surface methodology based on 23- Central Composite Design was used to design experiments, evaluate the main dyeing parameters, develop efficient mathematical models to predict the dyeing process, and optimize the procedure. The quadratic regression models developed were found to be statistically significant using ANOVA, with R2 -value of 0.9734 and 0.9820 for color strength and lightness responses, respectively. Also, eye-soothing tone and hues with a good resistance to durability (4-5) and light (4) were achieved. The banana shell and gallnut bio-mordants improved UV protection by up to 25.33% and 59.79%, respectively. Generally speaking, the results showed that C. Oblonga leaf as well as gallnut and banana shells could be used as whole crop products in an ecologically sound textile dyeing process through a sustainable approach and that the proposed innovative application might serve as an attractive procedure for recycling and green waste management.

6.
Heliyon ; 10(12): e32700, 2024 Jun 30.
Article in English | MEDLINE | ID: mdl-38988510

ABSTRACT

Cheese whey (CW), by-product of cheese production, has potential as a valuable resource due to its nutritional composition. Although options for CW degradation have been explored, a biological treatment with black soldier fly larvae (BSFL) has not been reported. This study evaluated the growth and composition of BSFL in four experimental diets with CW under different conditions. Results show that the use of CW allows larval development and weight gain, also, the conversion into larval biomass was up to 0.215. Diets ED3 (fresh CW, 38 °C) and ED4 (fresh CW, room temperature) allowed higher weight accumulation (final weight up to 0.285 g); the highest fat accumulation (12 % higher than control) was observed in ED3 (up to 45.57 %), which had less protein. Moreover, higher amounts of saturated fatty acids are generated. This study highlights the importance of an appropriate pretreatment designed for a specific waste to control desired by-products.

7.
Waste Manag ; 186: 280-292, 2024 Sep 15.
Article in English | MEDLINE | ID: mdl-38954920

ABSTRACT

This work outlines the first microwave (MW)-assisted protocol for the production of biofuel precursor furfural (FF) from the raw agricultural waste almond hull (AH), olive stone (OS), and the winemaking-derived grape stalk (GS), grape marc (GM) and exhausted grape marc (EGM) through a one-pot synthesis process. To enhance the overall yield, a catalytic process was firstly developed from xylose, major constituent of hemicellulose present in lignocellulosic biomass. This method afforded FF with 100 % selectivity, yielding over 85 % in isolated product when using H2SO4, as opposed to a 37 % yield with AlCl3·6H2O, at 150 °C in only 10 min. For both catalysts, the developed methodology was further validated, proving adaptable and efficient in producing the targeted FF from the aforementioned lignocellulosic raw materials. More specifically, the employment of AlCl3·6H2O resulted in the highest selectivity (up to 89 % from GM) and FF yield (42 % and 39 % molar from OS and AH, respectively), maintaining notable selectivity for the latter (61 and 48 % from AH and OS). At this regard, and considering the environmental factor of sustainability, it is important to point out the role of AlCl3·6H2O in contrast to H2SO4, thus mitigating detrimental substances. This study provides an important management of agricultural waste through sustainable practises for the development of potential bio-based chemicals, aligning with Green Chemistry and process intensification principles.


Subject(s)
Furaldehyde , Microwaves , Prunus dulcis , Wine , Furaldehyde/analogs & derivatives , Wine/analysis , Prunus dulcis/chemistry , Biofuels/analysis , Vitis , Lignin/chemistry , Plant Oils/chemistry , Catalysis , Aluminum Chloride , Olea/chemistry
8.
Insect Sci ; 2024 Jul 11.
Article in English | MEDLINE | ID: mdl-38990171

ABSTRACT

The ubiquitous incorporation of plastics into daily life, coupled with inefficient recycling practices, has resulted in the accumulation of millions of metric tons of plastic waste, that poses a serious threat to the Earth's sustainability. Plastic pollution, a global problem, disrupts the ecological balance and endangers various life forms. Efforts to combat plastic pollution are underway, with a promising avenue being biological degradation facilitated by certain insects and their symbiotic gut microorganisms, particularly bacteria. This review consolidates existing knowledge on plastic degradation by insects and their influence on gut microbiota. Additionally, it delves into the potential mechanisms employed by insects in symbiosis with gut bacteria, exploring the bioconversion of waste plastics into value-added biodegradable polymers through mineralization. These insights hold significant promise for the bio-upcycling of plastic waste, opening new horizons for future biomanufacturing of high-value chemicals from plastic-derived compounds. Finally, we weigh the pros and cons of future research endeavors related to the bioprospection of plastic-degrading bacteria from underexplored insect species. We also underscore the importance of bioengineering depolymerases with novel characteristics, aiming for their application in the remediation and valorization of waste plastics.

9.
Article in English | MEDLINE | ID: mdl-38990261

ABSTRACT

Food waste is produced for intended human consumption and is normally lost, discharged, contaminated, or finally degraded. The rising problem of food waste is increasing rapidly, so every sector is involved in minimizing food waste generation as well as waste management from collection to disposal, and scientists are developing the best eco-friendly and sustainable solutions for all sectors in the food supply chain, from the agricultural sector to the industrial sector and even up to the retailer to human consumption. Sustainable management is needed for the food wastes in the agricultural and industrial sectors, which are a major burning headache for environmentalists, health departments, and the government all over the earth. Various strategies can be employed to effectively control food waste, and these strategies can be ranked in a manner similar to the waste management hierarchy. The most desirable options involve the act of avoiding and donating edible portions to social agencies. Food waste is utilized in industrial operations to produce biofuels or biopolymers. The next stages involve the retrieval of nutrients and the sequestration of carbon through composting. The government implements appropriate management practices, laws, and orders to minimize food waste generation. Different contemporary methods are utilized to produce biofuel utilizing various types of food waste. In order for composting techniques to recover nutrients and fix carbon, food waste must be processed. Both the management of food waste and the creation of outgrowths utilizing biomaterials require additional study. This review aims to present a comprehensive analysis of the ongoing discourse surrounding the definitions of food waste, the production and implementation of methods to reduce it, the emergence of conversion technologies, and the most recent trends.

10.
Heliyon ; 10(12): e32878, 2024 Jun 30.
Article in English | MEDLINE | ID: mdl-38975073

ABSTRACT

Household single-use packaging has poor rates of recycling, and presents a challenge in transitioning to a circular packaging economy. This study characterises the flows of household single-use packaging in the municipal waste system for 2020-21 in New South Wales, Australia. Households are an important source of packaging usage in Australia, accounting for over 40 % of all packaging used in 2020-21. Our focus spans 17 single-use packaging materials and 11 formats. We estimate the composition of single-use consumer packaging in the kerbside collection stream, and the ultimate fate of used packaging. Results show 1000 ± 8 % kt of packaging was used by households in NSW in 2020-21 (∼123 kg/cap). Composition of the used packaging stream was dominated by glass (36 %), paper (29 %) and plastic (28 %) packaging. HDPE (26 % of plastic packaging), LDPE (24 %) and PET (19 %) were the main polymers in use. 63 % ± 5 % of used packaging was collected for recycling, and 34 % ± 7 % was recovered via recyclate generation and overseas exports. Glass packaging had the highest recycling rates at 52 % ± 3 %, while plastic packaging had the poorest at 11 % ± 10 %. Findings indicate incorrect disposal of recyclables at the household to mixed-waste systems as a major limitation of the system to improve recycling rates. Expansion in recovery capacity is also essential for improving recycling rates, and the potential for generating the packaging-grade recyclate essential for meeting recycled content targets. The study offers contributions to the understanding of consumer packaging managed within the municipal waste system. Insights gained have application in informing sustainable packaging and waste management strategies.

11.
Heliyon ; 10(12): e32725, 2024 Jun 30.
Article in English | MEDLINE | ID: mdl-38975142

ABSTRACT

The significance of accurate energy production prediction cannot be overstated, especially in the context of achieving carbon neutrality and balancing traditional and clean energy sources. Unlike conventional models with simplified assumptions or limited data inputs hindering energy usage optimization, waste reduction and efficient resource allocation, we introduced a novel structural equation modelling approach to eight manufacturing industries' sustainable waste management practices (SWMPs) in Iraq. This comprehensive analysis, conducted with Smart PLS software on 375 responses aims to enhance energy production predictions' accuracy and support sustainability goals contribute to achieving carbon neutrality goals and promote a balanced energy mix that supports sustainability and environmental stewardship. The findings reveal noteworthy insights: notably, chemical manufacturing companies exhibit a substantial advantage from green accounting practices, witnessing a 78.1 % and 45.8 % improvement in environmental auditing oversight and SWMPs, respectively, compared to other manufacturing sectors. Compared to conventional grey models, our model demonstrates that a 1-unit improvement in CSR enhances environmental auditing oversight effectiveness by 33.4 % and sustainable waste management by 56.9 % across industries. By leveraging these data-driven insights and innovative approaches, we can drive positive change towards a more sustainable and resilient energy future, collectively contributing to a more resilient, efficient, and sustainable energy ecosystem that benefits societies, economies, and the environment. The heightened accuracy of energy production prediction facilitated by our novel model empowers stakeholders at regional and global levels to make informed decisions, mitigate risks, support policy development, achieve sustainability goals, formulate effective policies and foster collaboration.

12.
Waste Manag ; 186: 226-235, 2024 Sep 15.
Article in English | MEDLINE | ID: mdl-38936306

ABSTRACT

Plastic mismanagement and its subsequent pollution by rapid economic development and urbanisation pose significant challenges for modern world society. Notwithstanding one of the main sources for macro plastic leakage into the ocean from land, precise assessment of plastic pollution origins from Southeast Asia is yet to be clearly examined. In order to make informed decisions and prioritise areas of improvement it is required to better understand the waste leakage dynamics at the local level. In this work, the Waste Flow Diagram (WFD) was applied to understand the sources and fates of plastics leaking from the solid waste management system for the case of Tuy Hoa City, Phu Yen, Vietnam. The study shows scenarios of leakage into the aquatic environment ranging from 0.8 to 2.7 kg/cap/year, which originates mainly from the collection system. Targeted improvements to this stage of the service could reduce leakages and the overall environmental impacts of mismanaged plastic waste. The results of this study show the necessity and importance of having up to date and reliable data to better inform stakeholders and service planning, facilitating efficient action against plastic pollution. As the first peer-reviewed scientific article critically applying the WFD, this work highlights the steps and challenges of the methodology and critically analyses different methodological pathways.


Subject(s)
Plastics , Refuse Disposal , Solid Waste , Vietnam , Solid Waste/analysis , Refuse Disposal/methods , Cities , Waste Management/methods , Environmental Monitoring/methods
13.
Sci Total Environ ; 941: 173553, 2024 Sep 01.
Article in English | MEDLINE | ID: mdl-38823691

ABSTRACT

Red mud and phosphogypsum have long been a focus and challenge in global industrial waste management, and their low-cost and large-scale utilization technology has always been an urgent need. This study is based on the strong acid-base neutralization reaction between red mud and phosphogypsum, which contain an elemental composition similar to that of natural soil, red mud itself has characteristic of clay minerals, and other auxiliary materials (i.e. rice husk powder, bentonite, fly ash, polyacrylamide flocculant and microbial suspension) were added, so as to explore the potential of synergistically prepared artificial soil for vegetation restoration. The results showed that the artificial soils exhibited physicochemical characteristics (e.g., pH, moisture content, cation exchange capacity) similar to those of natural soil, along with abundant organic matter, nitrogen, phosphorus, and potassium contents, meeting the growth requirements of plants. The artificial soils were able to support favorable growth of suitable plants (e.g., sunflower, wheat, rye grass), accumulating high levels of diverse enzymatic activities, comparable to those in natural soils (e.g., catalase, urease, phosphatase), or even surpassing natural soils (e.g., sucrase), and rich microorganism communities, such as Cyanobacteria, Proteobacteria, Actinobacteria in the bacteria domain, and Ascomycota in the fungi domain, were initially developed. It's suggested that preparing 1 ton of artificial soil entails synergistic consumption of 613.7 kg of red mud and 244.6 kg of phosphogypsum, accounting for mass proportions of 61.4 % and 24.5 %, respectively. In future, more evaluations on the leaching loss of nutrients and alkalinity and the environmental risks of heavy metals should be conducted to more references for the artificial soil application. In summary, the preparation of artificial soil is a very simple, efficient, scalable and low-cost collaborative resource utilization scheme of red mud and phosphogypsum, which has great potential for vegetation restoration in some places such as tailings field and soil-deficient depression.


Subject(s)
Calcium Sulfate , Environmental Restoration and Remediation , Phosphorus , Soil , Phosphorus/analysis , Soil/chemistry , Environmental Restoration and Remediation/methods , Soil Microbiology , Plants , Waste Management/methods
14.
Sci Rep ; 14(1): 14617, 2024 Jun 25.
Article in English | MEDLINE | ID: mdl-38918460

ABSTRACT

The use of waste foundry sand (WFS) in concrete production has gained attention as an eco-friendly approach to waste reduction and enhancing cementitious materials. However, testing the impact of WFS in concrete through experiments is costly and time-consuming. Therefore, this study employs machine learning (ML) models, including support vector regression (SVR), decision tree (DT), and AdaBoost regressor (AR) ensemble model to predict concrete properties accurately. Moreover, SVR was employed in conjunction with three robust optimization algorithms: the firefly algorithm (FFA), particle swarm optimization (PSO), and grey wolf optimization (GWO), to construct hybrid models. Using 397 experimental data points for compressive strength (CS), 146 for elastic modulus (E), and 242 for split tensile strength (STS), the models were evaluated with statistical metrics and interpreted using the SHapley Additive exPlanation (SHAP) technique. The SVR-GWO hybrid model demonstrated exceptional accuracy in predicting waste foundry sand concrete (WFSC) strength characteristics. The SVR-GWO hybrid model exhibited correlation coefficient values (R) of 0.999 for CS and E, and 0.998 for STS. Age was found to be a significant factor influencing WFSC properties. The ensemble model (AR) also exhibited comparable prediction accuracy to the SVR-GWO model. In addition, SHAP analysis revealed an optimal content of input variables in the concrete mix. Overall, the hybrid and ensemble models showed exceptional prediction accuracy compared to individual models. The application of these sophisticated soft computing prediction techniques holds the potential to stimulate the widespread adoption of WFS in sustainable concrete production, thereby fostering waste reduction and bolstering the adoption of environmentally conscious construction practices.

15.
J Imaging ; 10(6)2024 May 22.
Article in English | MEDLINE | ID: mdl-38921603

ABSTRACT

Addressing the pressing issue of food waste is vital for environmental sustainability and resource conservation. While computer vision has been widely used in food waste reduction research, existing food image datasets are typically aggregated into broad categories (e.g., fruits, meat, dairy, etc.) rather than the fine-grained singular food items required for this research. The aim of this study is to develop a model capable of identifying individual food items to be integrated into a mobile application that allows users to photograph their food items, identify them, and offer suggestions for recipes. This research bridges the gap in available datasets and contributes to a more fine-grained approach to utilising existing technology for food waste reduction, emphasising both environmental and research significance. This study evaluates various (n = 7) convolutional neural network architectures for multi-class food image classification, emphasising the nuanced impact of parameter tuning to identify the most effective configurations. The experiments were conducted with a custom dataset comprising 41,949 food images categorised into 20 food item classes. Performance evaluation was based on accuracy and loss. DenseNet architecture emerged as the top-performing out of the seven examined, establishing a baseline performance (training accuracy = 0.74, training loss = 1.25, validation accuracy = 0.68, and validation loss = 2.89) on a predetermined set of parameters, including the RMSProp optimiser, ReLU activation function, '0.5' dropout rate, and a 160×160 image size. Subsequent parameter tuning involved a comprehensive exploration, considering six optimisers, four image sizes, two dropout rates, and five activation functions. The results show the superior generalisation capabilities of the optimised DenseNet, showcasing performance improvements over the established baseline across key metrics. Specifically, the optimised model demonstrated a training accuracy of 0.99, a training loss of 0.01, a validation accuracy of 0.79, and a validation loss of 0.92, highlighting its improved performance compared to the baseline configuration. The optimal DenseNet has been integrated into a mobile application called FridgeSnap, designed to recognise food items and suggest possible recipes to users, thus contributing to the broader mission of minimising food waste.

16.
Environ Sci Technol ; 58(25): 11175-11184, 2024 Jun 25.
Article in English | MEDLINE | ID: mdl-38857431

ABSTRACT

Arsenic (As)-bearing Fe(III) precipitate groundwater treatment sludge has traditionally been viewed by the water sector as a disposal issue rather than a resource opportunity, partly due to assumptions of the low value of As. However, As has now been classified as a Critical Raw Material (CRM) in many regions, providing new incentives to recover As and other useful components of the sludge, such as phosphate (P) and the reactive hydrous ferric oxide (HFO) sorbent. Here, we investigate alkali extraction to separate As from a variety of field and synthetic As-bearing HFO sludges, which is a critical first step to enable sludge upcycling. We found that As extraction was most effective using NaOH, with the As extraction efficiency increasing up to >99% with increasing NaOH concentrations (0.01, 0.1, and 1 M). Extraction with Na2CO3 and Ca(OH)2 was ineffective (<5%). Extraction time (hour, day, week) played a secondary role in As release but tended to be important at lower NaOH concentrations. Little difference in As extraction efficiency was observed for several key variables, including sludge aging time (50 days) and cosorbed oxyanions (e.g., Si, P). However, the presence of ∼10 mass% calcite decreased As release from field and synthetic sludges considerably (<70% As extracted). Concomitant with As release, alkali extraction promoted crystallization of poorly ordered HFO and decreased particle specific surface area, with structural modifications increasing with NaOH concentration and extraction time. Taken together, these results provide essential information to inform and optimize the design of resource recovery methods for As-bearing treatment sludge.


Subject(s)
Alkalies , Arsenic , Groundwater , Sewage , Sewage/chemistry , Groundwater/chemistry , Alkalies/chemistry , Water Pollutants, Chemical/chemistry , Water Purification/methods , Ferric Compounds/chemistry
17.
Sci Total Environ ; 946: 174110, 2024 Jun 21.
Article in English | MEDLINE | ID: mdl-38909789

ABSTRACT

Hydrothermal carbonization (HTC) of single plastic polymers such as polyethylene terephthalate (PET) and polystyrene (PS) has not yet been explored on a large scale, particularly their thermal behavior, chemical transformations under subcritical conditions, and the energy properties of the resultant hydrochar. This study investigated these aspects by employing techniques, such as thermogravimetric analysis (TGA), Fourier transformed infrared spectroscopy (FTIR), elemental and calorific analysis. The results show that PET hydrochar has a superior energy densification (1.37) and energy yield (89 %) compared to PS hydrochar (1.13, 54 %). Hydrothermal carbonization modifies the chemical structure of the polymers by increasing the number of carbonyl groups (CO) in PET and forming new ones in PS, and by enhancing hydroxyl groups (OH) in PET while retaining them in PS. Both materials preserve their aromatic and aliphatic structures, with the introduction of alkenes groups (CC) in the PET hydrochar. PET hydrochar begins to decompose at lower temperatures (150-270 °C) than PS hydrochar (242-283 °C) but reaches higher peak temperatures (420-585 °C vs. 390-470 °C), with both types achieving similar burnout temperatures (650-800 °C). PET hydrochar recorded a higher activation energy (121-126 kJ/mol) than PS hydrochar (67-74 kJ/mol) with the Mampel first-order reaction model as the best fit.

18.
Sci Total Environ ; 946: 174167, 2024 Jun 23.
Article in English | MEDLINE | ID: mdl-38917898

ABSTRACT

Globally, COVID-19 has not only caused tremendous negative health, social and economic impacts, but it has also led to environmental issues such as a massive increase in biomedical waste. The biomedical waste (BMW) was generated from centralized (hospitals, clinics, and research facilities) and extended (quarantine camps, COVID-19 test camps, and quarantined homes) healthcare facilities. Many effects, such as the possibility of infection spread, unlawful dumping/disposal, and an increase in toxic emissions by common BMW treatment facilities, are conjectured because of the rise in waste generation. However, it is also an opportunity to critically analyze the current BMW treatment scenario and implement changes to make the system more economical and environmentally sustainable. In this review, the waste disposal guidelines of the BMW management infrastructure are critically analyzed for many functional parameters to bring out possible applications and limitations of individual interventions. In addition, an investigation was made to select appropriate technology based on the environmental setting.

19.
Sci Rep ; 14(1): 13934, 2024 Jun 17.
Article in English | MEDLINE | ID: mdl-38886518

ABSTRACT

Cigarette filter is the most common hazardous litter that contains many pollutants including PAHs. The durability of this litter in the urban environment has an important effect on the rate of pollutant leakage. In this study, the leakage rate of PAHs from the littered cigarette filters was estimated by considering the affecting parameters on their durability in the urban environment. The results showed that the density of littered cigarette filters in the studied locations was 0.00048-0.13563 g/m2. The maximum spatial variation of the littered cigarette filter was 225 times. The average leakage of the total studied PAHs was estimated to be 2.048 µg/10 m2. The impact of structural factors and efficiency of urban cleaning in the estimated leakage was at most 2.4 times. It is necessary to change the behavior of citizens in littering the cigarette filter, considering its durability in the urban environment, to reduce the environmental and health consequences caused by the leakage of PAHs.

20.
Clin Kidney J ; 17(6): sfae144, 2024 Jun.
Article in English | MEDLINE | ID: mdl-38887470

ABSTRACT

The health-care system and particularly renal replacement therapy has a significant carbon footprint adding to global warming and extreme weather conditions. Improving sustainability has become the focus of national and international working groups. Many reviews underline the need for improvement of sustainability in nephrology, in particular dialysis, and provide recommendations on how to reduce waste, energy, and water consumption. However, how to implement these recommendations, and where to start, is not always clear. This paper summarizes discussions within the 'working group on sustainable nephrology' of the Swiss Society of Nephrology. We do not provide a detailed review of the topic but instead present a practical 10-point action plan to help health-care workers in nephrology make a start and improve the carbon footprint of their dialysis centres. We emphasize the importance of ongoing research, cooperation, and dialogue, and welcome additional ideas from the wider renal community.

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