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1.
Int J Biol Macromol ; 276(Pt 2): 133906, 2024 Sep.
Article in English | MEDLINE | ID: mdl-39019364

ABSTRACT

This novel research addresses the critical need for sustainable and efficient materials, aiming to enhance the optical and thermoelectric properties of Aluminum doped Zinc Oxide (Al-doped ZnO) on cellulose fabric for diverse applications. At first stage, Cellulosic fabric of Al-doped ZnO were experimentally studied in detail with respect to varying levels of annealing temperature. Structural analysis unveiled structural evolution in hexagonal crystal formations with a reduction in particle size up to 27.5 % on average, with increased temperature. Further, Raman spectroscopy revealed the doping effects on the vibrational modes of ZnO, potentially due to alterations in lattice structure. The ZnO optical modes are found as E2 (low) = 110 cm-1 with observed phonon frequency in the Raman spectra of ZnO at A1 (TO) = 364 cm-1. Fourier transform infrared spectroscopy (FTIR) revealed the presence of characteristic stretching of developed material. Furthermore, the optical characters revealed a decrement of 43.22 % in bandgap values with increasing annealing temperature. The analysis of thermoelectric attributes documented that the prominent sample annealed at 300°C exhibited the maximum Seebeck coefficient and power factor of 2.1 × 10-3 µV/oC and 5.8 × 10-21 Wm-1 K-2, respectively. At second stage the optical characteristics of experimentally optimized sample were rigorously studied through the application of Material Studio software, while varying the doping ratio.


Subject(s)
Cellulose , Textiles , Zinc Oxide , Cellulose/chemistry , Zinc Oxide/chemistry , Temperature , Spectroscopy, Fourier Transform Infrared , Spectrum Analysis, Raman , Aluminum/chemistry
2.
Sensors (Basel) ; 24(6)2024 Mar 21.
Article in English | MEDLINE | ID: mdl-38544279

ABSTRACT

Respiratory rate (fR) monitoring through wearable devices is crucial in several scenarios, providing insights into well-being and sports performance while minimizing interference with daily activities. Strain sensors embedded into garments stand out but require thorough investigation for optimal deployment. Optimal sensor positioning is often overlooked, and when addressed, the quality of the respiratory signal is neglected. Additionally, sensor metrological characterization after sensor integration is often omitted. In this study, we present the design, development, and feasibility assessment of a smart t-shirt embedded with two flexible sensors for fR monitoring. Guided by a motion capture system, optimal sensor design and position on the chest wall were defined, considering both signal magnitude and quality. The sensors were developed, embedded into the wearable system, and metrologically characterized, demonstrating a remarkable response to both static (sensitivity 9.4 Ω⋅%-1 and 9.1 Ω⋅%-1 for sensor A and sensor B, respectively) and cyclic loads (min. hysteresis span 20.4% at 36 bpm obtained for sensor A). The feasibility of the wearable system was assessed on healthy volunteers both under static and dynamic conditions (such as running, walking, and climbing stairs). A mean absolute error of 0.32 bpm was obtained by averaging all subjects and tests using the combination of the two sensors. This value was lower than that obtained using both sensor A (0.53 bpm) and sensor B (0.78 bpm) individually. Our study highlights the importance of signal amplitude and quality in optimal sensor placement evaluation, as well as the characterization of the embedded sensors for metrological assessment.


Subject(s)
Running , Wearable Electronic Devices , Humans , Monitoring, Physiologic , Respiratory Rate , Textiles
3.
Polymers (Basel) ; 15(21)2023 Oct 25.
Article in English | MEDLINE | ID: mdl-37959904

ABSTRACT

Minimizing the impact of electromagnetic radiation (EMR) holds paramount importance in safeguarding individuals who frequently utilize electrical and electronic devices. Electrically conductive textiles, which possess specialized EMR shielding features, present a promising solution to mitigate the risks related to EMR. Furthermore, these textile-based shielding materials could find application as radar-absorbing materials in stealth technology, emphasizing the need for substantial absorption capabilities in shielding mechanisms. In this study, various textile-based materials with an electrically conductive coating that contain the conjugated polymer system poly(3,4-ethylene-dioxythiophene)-polystyrene sulfonate (PEDOT:PSS) were prepared and investigated. The influence of the textile substrate structural parameters, coating deposit, and coating method on their microwave properties-transmission, reflection, and absorption-was investigated. Reflection and transmission measurements were conducted within a frequency range of 2 to 18 GHz. These measurements revealed that, for the tested samples, the shielding properties are determined by the combined effect of reflection and absorption. However, the role of these two parameters varies across the tested frequency range. It was defined that for fabrics coated on one side, better reflection reduction is obtained when the shielding effectiveness (SE) is below |20| dB. It was found that by controlling the coating deposition on the fabric, it is possible to fine-tune the electrical properties to a certain extent, thereby influencing the microwave properties of the coated fabrics. The studies of prepared samples have shown that reflection and transmission parameters depend not only on the type and quantity of conductive paste applied to the fabric but also on the fabric's construction parameters and the coating technique used. It was found that the denser the substrate used for coating, the more conductive paste solidifies on the surface, forming a thicker coat on the top. For conductive fabrics with the same substrate to achieve a particular SE value using the knife-over-roll coating technology, the required coating deposit amount is considerably lower as compared with the deposit necessary in the case of screen printing: for the knife-over-roll-coated sample to reach SE 15 dB, the required deposit is approximately 14 g/m2; meanwhile, for a sample coated via screen printing, this amount rises to 23 g/m2.

4.
ACS Appl Mater Interfaces ; 15(37): 44521-44532, 2023 Sep 20.
Article in English | MEDLINE | ID: mdl-37695080

ABSTRACT

Pandemics stress supply lines and generate shortages of personal protective equipment (PPE), in part because most PPE is single-use and disposable, resulting in a need for constant replenishment to cope with high-volume usage. To better prepare for the next pandemic and to reduce waste associated with disposable PPE, we present a composite textile material capable of thermally decontaminating its surface via Joule heating. This material can achieve high surface temperatures (>100 °C) and inactivate viruses quickly (<5 s of heating), as evidenced experimentally with the surrogate virus HCoV-OC43 and in agreement with analytical modeling for both HCoV-OC43 and SARS-CoV-2. Furthermore, it does not require doffing because it remains relatively cool near the skin (<40 °C). The material can be easily integrated into clothing and provides a rapid, reusable, in situ decontamination method capable of reducing PPE waste and mitigating the risk of supply line disruptions in times of need.


Subject(s)
COVID-19 , Wearable Electronic Devices , Humans , COVID-19/prevention & control , Decontamination , SARS-CoV-2 , Textiles
5.
Materials (Basel) ; 16(12)2023 Jun 12.
Article in English | MEDLINE | ID: mdl-37374519

ABSTRACT

The transport properties of commercial carbon nanofibers (CNFs) produced by chemical vapor deposition (CVD) depend on the various conditions used during their growth and post-growth synthesis, which also affect their derivate CNF-based textile fabrics. Here, the production and thermoelectric (TE) properties of cotton woven fabrics (CWFs) functionalized with aqueous inks made from different amounts of pyrolytically stripped (PS) Pyrograf® III PR 25 PS XT CNFs via dip-coating method are presented. At 30 °C and depending on the CNF content used in the dispersions, the modified textiles show electrical conductivities (σ) varying between ~5 and 23 S m-1 with a constant negative Seebeck coefficient (S) of -1.1 µVK-1. Moreover, unlike the as-received CNFs, the functionalized textiles present an increase in their σ from 30 °C to 100 °C (dσ/dT > 0), explained by the 3D variable range hopping (VRH) model as the charge carriers going beyond an aleatory network of potential wells by thermally activated hopping. However, as it happens with the CNFs, the dip-coated textiles show an increment in their S with temperature (dS/dT > 0) successfully fitted with the model proposed for some doped multiwall carbon nanotube (MWCNT) mats. All these results are presented with the aim of discerning the authentic function of this type of pyrolytically stripped Pyrograf® III CNFs on the thermoelectric properties of their derived textiles.

6.
Polymers (Basel) ; 15(11)2023 May 31.
Article in English | MEDLINE | ID: mdl-37299337

ABSTRACT

The way to improve the properties (resistance to washing, delamination, and rubbing off) of the PEDOT:PSS coating applied on wool fabric without reduction of its electrical conductivity by introducing a commercially available combination of low formaldehyde content melamine resins into the printing paste is presented in this paper. Primarily, to improve the hydrophilicity and dyeability of wool fabric, the samples were modified using low-pressure nitrogen (N2) gas plasma. Two commercially available PEDOT:PSS dispersions were used to treat wool fabric by the exhaust dyeing and screen printing methods, respectively. Spectrophotometric measurements of the color difference (ΔE*ab) and visual evaluation of woolen fabric dyed and printed with PEDOT:PSS in different shades of the blue color showed that the sample modified with N2 plasma obtained a more intense color compared to the unmodified one. SEM was used to examine the surface morphology and a cross-sectional view of wool fabric that had undergone various modifications. SEM image shows that the dye penetrates deeper into the wool fabric after plasma modification using dyeing and coating methods with a PEDOT:PSS polymer. In addition, with a Tubicoat fixing agent, HT coating looks more homogeneous and uniform. The chemical structure spectra of wool fabrics coated with PEDOT:PSS were investigated using FTIR-ATR characterization. The influence of melamine formaldehyde resins on the electrical properties, resistance to washing, and mechanical effects of PEDOT:PSS treated wool fabric was also evaluated. The resistivity measurement of the samples containing melamine-formaldehyde resins as an additive did not show a significant decrease in electrical conductivity, while the electrical conductivity was maintained after the washing and rubbing test as well. The best results of electrical conductivity for investigated wool fabrics before and after washing and mechanical action were determined for samples subjected to the combined processing-surface modification by low-pressure N2 plasma, dyeing by exhaust with PEDOT:PSS, and coating by the screen-printing method of PEDOT:PSS and a 3 wt.% melamine formaldehyde resins mixture.

7.
Materials (Basel) ; 16(3)2023 Jan 18.
Article in English | MEDLINE | ID: mdl-36769918

ABSTRACT

Conductive textiles play an important role in recent electronics development; however, one of the major challenges remains their machine-washing durability. For the investigation of the basic wash ageing mechanisms, we used copper-plated polyamide 66 and cellulose fabrics and developed a wet and dry operable flex tester with online resistance recording. The evaluation was supported by abrasion tests, cyclic elongation tests and tribological investigation of dry and wet textile-textile friction. It was found that the contribution of mechanical and chemical ageing to wash ageing strongly depends on the substrate material. A bad adhesion of copper on polyamide 66 leads to early fatigue while better stability of the copper on cellulose leads to a stronger resistance against ageing. For both substrates, the delamination of the copper layer was the root cause of the fatigue, which is facilitated by the washing solution. Finally, a cumulative fatigue model was developed and the determination of the end of lifetime by the intended use is discussed.

8.
Sensors (Basel) ; 23(2)2023 Jan 05.
Article in English | MEDLINE | ID: mdl-36679418

ABSTRACT

Wearable devices have been shown to play an important role in disease prevention and health management, through the multimodal acquisition of peripheral biosignals. However, many of these wearables are exposed, limiting their long-term acceptability by some user groups. To overcome this, a wearable smart sock integrating a PPG sensor and an EDA sensor with textile electrodes was developed. Using the smart sock, EDA and PPG measurements at the foot/ankle were performed in test populations of 19 and 15 subjects, respectively. Both measurements were validated by simultaneously recording the same signals with a standard device at the hand. For the EDA measurements, Pearson correlations of up to 0.95 were obtained for the SCL component, and a mean consensus of 69% for peaks detected in the two locations was obtained. As for the PPG measurements, after fine-tuning the automatic detection of systolic peaks, the index finger and ankle, accuracies of 99.46% and 87.85% were obtained, respectively. Moreover, an HR estimation error of 17.40±14.80 Beats-Per-Minute (BPM) was obtained. Overall, the results support the feasibility of this wearable form factor for unobtrusive EDA and PPG monitoring.


Subject(s)
Galvanic Skin Response , Wearable Electronic Devices , Humans , Photoplethysmography/methods , Feasibility Studies , Foot , Heart Rate
9.
Polymers (Basel) ; 14(21)2022 Nov 03.
Article in English | MEDLINE | ID: mdl-36365707

ABSTRACT

The presented review summarizes recent studies in the field of electro conductive textiles as an essential part of lightweight and flexible textile-based electronics (so called e-textiles), with the main focus on a relatively simple and low-cost dip-coating technique that can easily be integrated into an existing textile finishing plant. Herein, numerous electro conductive compounds are discussed, including intrinsically conductive polymers, carbon-based materials, metal, and metal-based nanomaterials, as well as their combinations, with their advantages and drawbacks in contributing to the sectors of healthcare, military, security, fitness, entertainment, environmental, and fashion, for applications such as energy harvesting, energy storage, real-time health and human motion monitoring, personal thermal management, Electromagnetic Interference (EMI) shielding, wireless communication, light emitting, tracking, etc. The greatest challenge is related to the wash and wear durability of the conductive compounds and their unreduced performance during the textiles' lifetimes, which includes the action of water, high temperature, detergents, mechanical forces, repeated bending, rubbing, sweat, etc. Besides electrical conductivity, the applied compounds also influence the physical-mechanical, optical, morphological, and comfort properties of textiles, depending on the type and concentration of the compound, the number of applied layers, the process parameters, as well as additional protective coatings. Finally, the sustainability and end-of-life of e-textiles are critically discussed in terms of the circular economy and eco-design, since these aspects are mainly neglected, although e-textile' waste could become a huge problem in the future when their mass production starts.

10.
ACS Nano ; 16(9): 14490-14502, 2022 Sep 27.
Article in English | MEDLINE | ID: mdl-36094895

ABSTRACT

Stretchable conductive fibers are an important component of wearable electronic textiles, but often suffer from a decrease in conductivity upon stretching. The use of liquid metal (LM) droplets as conductive fillers in elastic fibers is a promising solution. However, there is an urgent need to develop effective strategies to achieve high adhesion of LM droplets to substrates and establish efficient electron transport paths between droplets. Here, we use large-sized MXene two-dimensional conductive materials to modify magnetic LM droplets and prepare MXene/magnetic LM/poly(styrene-butadiene-styrene) composite fibers (MLMS fibers). The MXene sheets decorated on the surface of magnetic LM droplets not only enhance the droplet adhesion to substrate but also bridge adjacent droplets to establish efficient conductive paths. MLMS fibers show several-fold improvements in tensile strength and elongation and a 30-fold increase in conductivity compared with pure LM-filled fibers. These conductive fibers can be easily woven into multifunctional textiles, which exhibit strong electromagnetic interference shielding and stable Joule heating performances even under large tensile deformation. In addition, other advantages of MLMS textiles, such as high gas/liquid permeability, strong chemical resistance (acid and alkaline conditions), high/low-temperature tolerance (-40-150 °C) and water washability, make them particularly suitable for wearable applications.

11.
Materials (Basel) ; 15(14)2022 Jul 08.
Article in English | MEDLINE | ID: mdl-35888265

ABSTRACT

This study presents the effect of non-thermal plasma modification on the changes of surface morphology, color characteristics and electrical conductivity of wool fabric dyed with intrinsically conductive polymer (ICP) poly (3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT: PSS). The wool fabric was treated with an aqueous dispersion of PEDOT: PSS, Clevios F ET, providing electrically conductive properties to textiles. The wool fabric, containing basic groups of amines (NH2), was pre-activated with low-pressure plasma of non-polymer forming nitrogen (N2) gas before exhaust dyeing with PEDOT: PSS at 90 °C was applied. This treatment imparted hydrophilicity, reduced felting, increased adhesion, improved dye ability and ensured that more PEDOT: PSS negatively charged sulfonate (-SO3-) counter ions would be electrostatically bounded with the cationic protonated amine groups of the wool fiber. Initially, before (N2) plasma treatment and after fabrics were evaluated according to the test method for aqueous liquid repellency, the surface morphology of the plasma-modified and -unmodified wool dyed fabric was observed with scanning electron microscopy (SEM). The functional groups introduced onto the surface after N2 gas plasma treatment of wool fabric were characterized by X-ray photoelectron and FTIR-ATR spectroscopy. The results of color difference measurements show that N2 gas plasma treatments provide more intense color on Clevios F ET dyed wool fabric and retain its electrical conductivity.

12.
Polymers (Basel) ; 14(2)2022 Jan 08.
Article in English | MEDLINE | ID: mdl-35054656

ABSTRACT

This experiment presents a study carried out on the electric charge passing textiles for heat production in compression weft-knitted composite fabrics used for medical purposes. The aim was to flourish compression support of knitted structure with integrated highly sensitive metal (silver) coated polyamide multifilament yarns and to evaluate its heat origination attributes after stretching in different levels as well as changes of the temperature during the time. A flat double needle-bed knitting machine was utilized to fabricate the selected specimens together with elastomeric inlay-yarn incorporated into the structure for compression generation and silver coated polyamide yarn laid as ground yarn in a plated structure for heat generation. Six different variants depending on the metal coated yarn amount used and the fabric structure along with two types of the conductive yarn linear density were fabricated for this research work. Scanning electron microscope (SEM) images were preoccupied to show the morphology of conductive yarn and thermal pictures were captured to study the evenness of the heat over the surface of composite fabrics depending on conductive yarn distribution in the pattern repeat. The temperature profile of fabricated composite fabrics and comparison of the heat generation by specimens after stretching in different levels was studied.

13.
Materials (Basel) ; 14(22)2021 Nov 10.
Article in English | MEDLINE | ID: mdl-34832180

ABSTRACT

Textile-based heaters have opened new opportunities for next-generation smart heating devices. This experiment presents electrically conductive textiles for heat generation in orthopaedic compression supports. The main goal was to investigate the influence of frequent washing and stretching on heat generation durability of constructed compression knitted structures. The silver coated polyamide yarns were used to knit a half-Milano rib structure containing elastomeric inlay-yarn. Dimensional stability of the knitted fabric and morphological changes of the silver coated electro-conductive yarns were investigated during every wash cycle. The results revealed that temperature becomes stable within two minutes for all investigated fabrics. The heat generation was found to be dependent on the stretching, mostly due to the changing surface area; and it should be considered during the development of heated compression knits. Washing negatively influences the heat-generating capacity on the fabric due to the surface damage caused by the mechanical and chemical interaction during washing. The higher number of silver-coated filaments in the electro-conductive yarn and the knitted structure, protecting the electro-conductive yarn from mechanical abrasion, may ensure higher durability of heating characteristics.

14.
ACS Appl Mater Interfaces ; 13(48): 57930-57942, 2021 Dec 08.
Article in English | MEDLINE | ID: mdl-34797629

ABSTRACT

Conductive composite inks are widely used in various applications such as flexible electronics. However, grand challenges still remain associated with their relatively low electrical conductivity and require heavy use of organic solvents, which may limit their high performance in broad applications and cause environmental concerns. Here, we report a generalized and eco-friendly strategy to fabricate highly conductive aqueous inks using silver nanowires (AgNWs) and biomass-derived organic salts, including succinic acid-chitosan (SA-chitosan) and sebacic acid-chitosan. SA-chitosan/AgNW composite coatings can be prepared by directly casting conductive aqueous inks on various substrates, followed by subsequently heating for cross-linking. The composite coatings exhibit an ultrahigh electrical conductivity up to 1.4 × 104 S/cm, which are stable after being treated with various organic solvents and/or kept at a high temperature of 150 °C, indicating their high chemical and thermal resistance. The flexibility and performance durability of these composite coatings were demonstrated by a suite of characterization methods, including bending, folding, and adhesion tests. Moreover, a high electromagnetic interference shielding (EMI) effectiveness of 73.3 dB is achieved for SA-chitosan/AgNW composite coatings at a thickness of only 10 µm due to the ultrahigh electrical conductivity. Additionally, we further demonstrated that such conductive composite inks can be used for fabricating functional textiles for a variety of applications with high performance, such as EMI shielding, Joule heating, and strain sensing. The robust and highly conductive inks prepared by this simple and environmental-friendly method hold great promise as important material candidates for the potential large-scale manufacturing of flexible and wearable electronics.

15.
Sensors (Basel) ; 21(17)2021 Sep 04.
Article in English | MEDLINE | ID: mdl-34502835

ABSTRACT

Electronic textiles (e-textiles) have become more and more important in daily life and attracted increased attention of the scientific community over the last decade. This interdisciplinary field of interest ranges from material science, over chemistry, physics, electrical engineering, information technology to textile design. Numerous applications can already be found in sports, safety, healthcare, etc. Throughout the life of service, e-textiles undergo several exposures, e.g., mechanical stress, chemical corrosion, etc., that cause aging and functional losses in the materials. The review provides a broad and critical overview on the functional ageing of electronic textiles on different levels from fibres to fabrics. The main objective is to review possible aging mechanisms and elaborate the effect of aging on (electrical) performances of e-textiles. The review also provides an overview on different laboratory methods for the investigation on accelerated functional ageing. Finally, we try to build a model of cumulative fatigue damage theory for modelling the change of e-textile properties in their lifetime.


Subject(s)
Electronics , Textiles , Electric Conductivity
16.
Sensors (Basel) ; 21(12)2021 Jun 11.
Article in English | MEDLINE | ID: mdl-34208280

ABSTRACT

Due to the appearance of smart textiles and wearable electronics, the need for electro-conductive textiles and electro-conductive paths on textiles has become clear. In this article the results of a test of developed textile electro-conductive paths obtained by applying the method of screen printing pastes containing silver nanoparticles and carbon (graphene, nanotubes, graphite) are presented. Conducted research included analysis of the adhesion test, as well as evaluation of the surface resistance before and after the washing and bending cycles. Obtained results indicated that the samples with the content of carbon nanotubes 3% by weight in PMMA on substrate made of aramid fibers (surface mass of 260 g/m2) were characterized by the best adhesion and the best resistance to washing and bending cycles. Such electro-conductive paths have potential to be used in smart clothing applications.


Subject(s)
Graphite , Metal Nanoparticles , Nanotubes, Carbon , Electrodes , Electronics , Silver , Textiles
17.
Polymers (Basel) ; 13(10)2021 May 17.
Article in English | MEDLINE | ID: mdl-34067901

ABSTRACT

Waterborne polyurethane-urea dispersions (WPUD), which are based on 100% bio-based semi-crystalline polyester polyol and isophorone diisocyanate, have been successfully synthesized and doped with single-walled carbon nanotubes (SWCNT) to obtain a finishing agent that provides textiles with multifunctional properties. The chemical structure of WPUD has been characterized by Fourier-transform infrared spectroscopy (FTIR) and nuclear magnetic resonance (NMR). The thermal properties have been evaluated by differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and dynamic mechanical thermal analysis (DMTA). Mechanical properties have been studied by tensile stress-strain analysis. Moreover, the particle size, particle size distribution (PSD), and stability of developed waterborne dispersions have been assessed by dynamic light scattering (DLS), Z-potential, and accelerated aging tests (analytical centrifugation). Subsequently, selected fabrics have been face-coated by the WPUD using knife coating method and their properties have been assessed by measuring water contact angle (WCA), water column, fabric stiffness, and air permeability. The electrical conductivity of textiles coated with SWCNT-doped WPUD has been evaluated by EN 1149 standard. Finally, the surface morphologies of uncoated and coated fabrics have been studied by scanning electron microscopy (SEM). All of the synthesized polyurethane-ureas provide the coated substrates with remarkable water-repellency and water column, being therefore a more sustainable alternative to waterproof coatings based on fluoropolymers, such as PTFE. The additivation of the polymeric matrices with SWCNT has led to textile coatings with excellent electrical conductivity, maintaining water column properties, giving rise to multifunctional coatings that are highly demanded in protective workwear and technical textiles.

18.
Sensors (Basel) ; 21(10)2021 May 18.
Article in English | MEDLINE | ID: mdl-34070032

ABSTRACT

The rapid growth in wearable technology has recently stimulated the development of conductive textiles for broad application purposes, i.e., wearable electronics, heat generators, sensors, electromagnetic interference (EMI) shielding, optoelectronic and photonics. Textile material, which was always considered just as the interface between the wearer and the environment, now plays a more active role in different sectors, such as sport, healthcare, security, entertainment, military, and technical sectors, etc. This expansion in applied development of e-textiles is governed by a vast amount of research work conducted by increasingly interdisciplinary teams and presented systematic review highlights and assesses, in a comprehensive manner, recent research in the field of conductive textiles and their potential application for wearable electronics (so called e-textiles), as well as development of advanced application techniques to obtain conductivity, with emphasis on metal-containing coatings. Furthermore, an overview of protective compounds was provided, which are suitable for the protection of metallized textile surfaces against corrosion, mechanical forces, abrasion, and other external factors, influencing negatively on the adhesion and durability of the conductive layers during textiles' lifetime (wear and care). The challenges, drawbacks and further opportunities in these fields are also discussed critically.

19.
Polymers (Basel) ; 13(8)2021 Apr 07.
Article in English | MEDLINE | ID: mdl-33917188

ABSTRACT

This study presents the investigation of the electromagnetic properties and resistance performance of electrically conductive fabrics coated with composition containing the conjugated polymer system poly(3,4-ethylenedioxythiophene)-polystyrene sulfonate (PEDOT:PSS). The developed fabrics were intended for electromagnetic radiation (EMR) shielding in microwave range and for absorbing microwaves in radar operating range, so as to act as radar absorbing materials (RAM). The measurements of reflection and transmission of the developed fabrics were performed in a frequency range of 2-18 GHz, which covers the defined frequencies relevant to the application. Four types of fabrics with different fiber composition (polyamide; polyamide/cotton; wool and para-aramid/viscose) were selected and coated with conductive paste using screen printing method. It was found that EMR shielding effectiveness (SE) as well as absorption properties depend not only the amount of conductive paste topped on the fabric, but also resides in the construction parameters of fabrics. Depending on such fabric structural parameters as density, mass per unit area, type of weave, a layer of shield (or coating) just sticks on the fabric surface or penetrates into fabric, changing the shield thickness and herewith turning SE results. Meanwhile, the fiber composition of fabrics influences mostly bonding between fibers and polymer coating. To improve the resistance performance of the developed samples, a conventional textile surface modification technique, atmospheric plasma treatment, was applied. Initially, before plasma treatment and after treatment the fabrics were evaluated regarding an aqueous liquid repellency test, measuring the contact angles for the water solvent. The influence of plasma treatment on resistance performance of coated fabrics was evaluated by subjecting the plasma treated samples and untreated samples to abrasion in the Martindale abrasion apparatus and to multiplex washing cycles. These investigations revealed that applied plasma treatment visibly improved abrasion resistance as a result of better adhesion of the coating. However, washing resistance increased not so considerably.

20.
Sensors (Basel) ; 20(21)2020 Oct 31.
Article in English | MEDLINE | ID: mdl-33142899

ABSTRACT

Long-term electrocardiography (ECG) monitoring is very essential for the early detection and treatment of cardiovascular disorders. However, commercially used silver/silver chloride (Ag/AgCl) electrodes have drawbacks, and these become more obvious during long-term signal monitoring, making them inconvenient for this use. In this study, we developed silver printed textile electrodes from knitted cotton and polyester fabric for ECG monitoring. The surface resistance of printed electrodes was 1.64 Ω/sq for cotton and 1.78 Ω/sq for polyester electrodes. The ECG detection performance of the electrodes was studied by placing three electrodes around the wrist where the electrodes were embedded on an elastic strap with Velcro. The ECG signals collected using textile electrodes had a comparable waveform to those acquired using standard Ag/AgCl electrodes with a signal to noise ratio (SNR) of 33.10, 30.17, and 33.52 dB for signals collected from cotton, polyester, and Ag/AgCl electrodes, respectively. The signal quality increased as the tightness of the elastic strap increased. Signals acquired at 15 mmHg pressure level with the textile electrodes provided a similar quality to those acquired using standard electrodes. Interestingly, the textile electrodes gave acceptable signal quality even after ten washing cycles.


Subject(s)
Electrocardiography , Electrodes , Silver , Textiles , Humans , Laundering , Signal-To-Noise Ratio
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