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1.
Materials (Basel) ; 17(6)2024 Mar 13.
Article in English | MEDLINE | ID: mdl-38541480

ABSTRACT

Aftermarket additives are used to enhance the performance of internal combustion engines in specific aspects such as reducing wear, increasing power, and improving fuel economy. Despite their advantages, they can sometimes cause corrosion-related problems. This research evaluated the corrosiveness of four aftermarket additives on the corrosion of a high-leaded tin bronze alloy over 28 days at 80 °C in immersion tests. Among the evaluated products, three showed corrosive effects ranging from intermediate to severe. Notably, the visual appearance of the surfaces often did not indicate the underlying corrosive damage. Therefore, the assessment of corrosiveness was based on chemical characterizations conducted on both the drained oils and the bronze surfaces. The study found minimal oil degradation under the testing conditions, indicating that the primary cause of corrosion was the interaction between the specific additives and the metal elements of the alloy, rather than oil degradation itself. A direct correlation was observed between the dissolution of lead and copper and the adsorption of S and Cl-containing additives on the surfaces, respectively. The corrosive impact of Cl-containing additives in aftermarket formulations was significantly reduced when mixed with engine oil SAE 10W-30 (at a 25:1 ratio), suggesting a mitigated effect in combined formulations, which is the recommended usage for engines.

2.
ACS Appl Mater Interfaces ; 12(15): 17492-17501, 2020 Apr 15.
Article in English | MEDLINE | ID: mdl-32216323

ABSTRACT

In this work, the effect of copper addition on NiMo coating is evaluated in regard to the hydrogen evolution reaction (HER). NiMo and NiMo-NiCu composites are prepared by a simple coelectrodeposition process. The effect of Cu on deposit characters were tested by varying it in the range of 0.06-0.20 molar ratio. Copper addition promotes the growth of a new crystalline phase: NiCu. Also, the copper addition changed the composite surface. NiMo-NiCu0.12 shows a surface roughness 30 times higher than the NiMo material. NiMo-NiCu materials present higher activity toward HER, larger electroactive area, and higher stability in continuous water electrolysis than NiMo catalysts, as demonstrated by Tafel curves, electrochemical impedance spectroscopy measurements, and polarization tests. The combination of the large electroactive area due to the copper addition, the synergism between Ni-Mo, and the presence of Ni and Mo oxides on the surface results in catalyst with excellent features for HER application.

3.
Braz J Microbiol ; 49 Suppl 1: 113-118, 2018 Nov.
Article in English | MEDLINE | ID: mdl-30181050

ABSTRACT

Poultry meat is a food product that usually carries high rates of microbial contamination, including foodborne pathogens. The poultry industry has established different systems to minimize these hazards. In recent years, extensive literature has demonstrated the antimicrobial activity of different contact surfaces made of copper to effectively reduce microbial loads. The aim of the present study was to evaluate the antibacterial effect of copper surfaces on the transmission of two foodborne pathogens - Salmonella enterica and Listeria monocytogenes - and a poultry native microbiota bacterial species - Enterobacter cloacae. We also evaluated the impact of the poultry meat matrix on the antimicrobial activity of a copper surface. Our results indicated that copper surfaces reduced the bacterial load quickly (

Subject(s)
Anti-Bacterial Agents/pharmacology , Copper/pharmacology , Meat/microbiology , Poultry/microbiology , Animals , Cadaver , Food Contamination/analysis , Listeria monocytogenes/drug effects , Microbiota/drug effects , Salmonella enterica/drug effects
4.
Braz. j. microbiol ; Braz. j. microbiol;492018.
Article in English | LILACS-Express | LILACS, VETINDEX | ID: biblio-1469649

ABSTRACT

Abstract Poultry meat is a food product that usually carries high rates of microbial contamination, including foodborne pathogens. The poultry industry has established different systems to minimize these hazards. In recent years, extensive literature has demonstrated the antimicrobial activity of different contact surfaces made of copper to effectively reduce microbial loads. The aim of the present study was to evaluate the antibacterial effect of copper surfaces on the transmission of two foodborne pathogens Salmonella enterica and Listeria monocytogenes and a poultry native microbiota bacterial species Enterobacter cloacae. We also evaluated the impact of the poultry meat matrix on the antimicrobial activity of a copper surface. Our results indicated that copper surfaces reduced the bacterial load quickly ( than 4 min) when the microorganisms were exposed to polished copper surfaces. Even when bacteria were inoculated on copper surfaces soiled with the organic matrix (washing water from poultry carcasses) and survival rates were significantly higher, an antimicrobial effect was still observed. Survival rates of two microorganisms simultaneously exposed to copper did not show significant differences. We found an antimicrobial effect over pathogenic and non-pathogenic microorganisms. Results suggest a potential role for copper surfaces in the control of microbiological hazards in the poultry industry.

5.
Braz. j. microbiol ; Braz. j. microbiol;49(supl.1): 113-118, 2018. tab, graf
Article in English | LILACS | ID: biblio-974319

ABSTRACT

Abstract Poultry meat is a food product that usually carries high rates of microbial contamination, including foodborne pathogens. The poultry industry has established different systems to minimize these hazards. In recent years, extensive literature has demonstrated the antimicrobial activity of different contact surfaces made of copper to effectively reduce microbial loads. The aim of the present study was to evaluate the antibacterial effect of copper surfaces on the transmission of two foodborne pathogens - Salmonella enterica and Listeria monocytogenes - and a poultry native microbiota bacterial species - Enterobacter cloacae. We also evaluated the impact of the poultry meat matrix on the antimicrobial activity of a copper surface. Our results indicated that copper surfaces reduced the bacterial load quickly (<than 4 min) when the microorganisms were exposed to polished copper surfaces. Even when bacteria were inoculated on copper surfaces soiled with the organic matrix (washing water from poultry carcasses) and survival rates were significantly higher, an antimicrobial effect was still observed. Survival rates of two microorganisms simultaneously exposed to copper did not show significant differences. We found an antimicrobial effect over pathogenic and non-pathogenic microorganisms. Results suggest a potential role for copper surfaces in the control of microbiological hazards in the poultry industry.


Subject(s)
Animals , Poultry/microbiology , Copper/pharmacology , Meat/microbiology , Anti-Bacterial Agents/pharmacology , Cadaver , Food Contamination/analysis , Salmonella enterica/drug effects , Microbiota/drug effects , Listeria monocytogenes/drug effects
6.
Braz. J. Microbiol. ; 49(supl 1): 113-118, 2018. tab, graf
Article in English | VETINDEX | ID: vti-19075

ABSTRACT

Poultry meat is a food product that usually carries high rates of microbial contamination, including foodborne pathogens. The poultry industry has established different systems to minimize these hazards. In recent years, extensive literature has demonstrated the antimicrobial activity of different contact surfaces made of copper to effectively reduce microbial loads. The aim of the present study was to evaluate the antibacterial effect of copper surfaces on the transmission of two foodborne pathogens Salmonella enterica and Listeria monocytogenes and a poultry native microbiota bacterial species Enterobacter cloacae. We also evaluated the impact of the poultry meat matrix on the antimicrobial activity of a copper surface. Our results indicated that copper surfaces reduced the bacterial load quickly (

Subject(s)
Meat/microbiology , Copper , Anti-Infective Agents/analysis , Alloys , Salmonella , Listeria monocytogenes , Chickens
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