ABSTRACT
RESUMO Neste artigo, apresenta-se uma abordagem conceitual sobre propostas de alternativas para a concepção de sistemas com reator anaeróbio de manta de lodo. Em essência, propõem-se: i) a eliminação dos separadores de gás, líquido e sólido que constam em reatores upflow anaerobic sludge blanket reactors e sua substituição por unidade de sedimentação de alta taxa em setor incluso ou externo ao volume do reator biológico; ii) a recirculação de parcela do lodo retido no sedimentador, transformando o conjunto em um sistema semelhante ao de lodo ativado, porém preservando a manta de lodo no reator anaeróbio (activated anaerobic sludge blanket system) e, assim, viabilizando melhor controle do tempo de retenção celular; e iii) a simplificação (menor número de entradas) do sistema de distribuição do afluente junto ao fundo da zona de reação, mediante duas alternativas: agitação mecânica ou agitação hidráulica com jatos — em ambos os casos, intermitentes. As propostas, conforme apresentadas, constituem resumo de pesquisa baseada em reatores de bancada sucedida pela operação e testes em duas unidades-piloto paralelas (volume total: 20,8 m3, incluindo volumes de reação e de sedimentação). Constatou-se que é possível remover sólidos suspensos do efluente da região de reação sem a necessidade do separador trifásico e, também, que é possível manter-se a manta de lodo mesmo com a agitação na região de reação. Foram obtidos bons resultados na remoção de sólidos suspensos totais, demanda bioquímica de oxigênio e demanda química de oxigênio nos sedimentadores com valores de taxa de aplicação superficial de 34,0 até 81,6 m3m-2dia. Constatou-se, também, que valores bastante baixos de gradiente de velocidade (G £ 20s-1) são suficientes para promover a manutenção da manta de lodo e que a intermitência na agitação é favorável ao processo biológico. Os resultados relacionados com a remoção de demanda química de oxigênio, demanda bioquímica de oxigênio e sólidos suspensos totais foram comparados com os de outros estudos sobre reatores upflow anaerobic sludge blanket reactors convencionais. Contudo, aqueles relacionados com o tempo de reação celulat foram os mais significativos para as conclusões desta pesquisa. Quando o reator foi operado com tempo de detenção hidráulica de 8,2 h e velocidade ascensional no reator biológico de 0,69 mh-1, o tempo de reação celular do sistema resultou em 175 dias. Com velocidade ascensional menores, os valores de tempo de reação nuclear foram ainda maiores (por exemplo: velocidade ascensional = 0,39 mh-1; tempo de reação celular = 363 dias). Os resultados deste trabalho abrem perspectivas para novas pesquisas e novos horizontes para projeto de sistemas com reatores anaeróbios de manta de lodo e decantadores de alta taxa.
ABSTRACT This paper presented a conceptual approach toward alternatives for the design of anaerobic sludge blanket reactors. In essence, it is proposed: i) the elimination of gas-liquid-solid separators that integrate the upflow anaerobic sludge blanket reactors and their replacement by a high rate settlers placed inside or outside the volume of biological reactor; ii) the recirculation of a fraction of the of the sludge retained in the settler, converting the process into a solution that resembles the activated sludge system, however, preserving the sludge blanket (Activated Anaerobic Sludge Blanket System), and thus ensuring better control of the cell retention time; and iii) the simplification (lower inlet points) of the influent distribution system placed over the bottom of the reaction zone, upon the implementation of two alternatives: mechanical mixing or hydraulic agitation with jet discharges, intermittent, in both cases. The proposals, as presented, are a summary of researches based on bench scale tests succeeded by the operation and tests in two parallel pilot units (total volume: 20.8 m3, including reaction zone and settler). It was found that it is possible to remove suspended solids from the effluent of the reaction zone without the need for a three-phase separator, and also, that it is possible to maintain the sludge blanket even with mixing in the reaction zone. Good results regarding total suspended solids, biochemical oxygen demand and chemical oxygen demand removal in the settlers were obtained, with applied hydraulic loading rate from 34.0 to 81.6 m3m-2 day. It was also found that very low velocity gradient values (G £ 20 s-1) are required to promote the maintenance of the sludge blanket, and the intermittency in the agitation is favorable to the biological process. The results concerning, , and TSS removal were compared with those of other studies on conventional upflow anaerobic sludge blanket reactors. However, those related to sludge age were the most significant to the conclusions of this research. When the reactor was operated with a hydraulic retention time of 8.2 h and a upflow velocity upflow velocity of 0.69 mh-1 in the biological reactor, the average sludge age reached 175 days. When applying smaller values of upflow velocity, the sludge age values reached greater values (Example: upflow velocity = 0.39 mh-1; sludge age = 363 days). The results and conclusions of this research open new perspectives for future research and new horizons for designing systems consisting of anaerobic sludge blanket and high-rate settlers.
ABSTRACT
Microbial fuel cells (MFCs) are electrochemical devices focused on bioenergy generation and organic matter removal carried out by microorganisms under anoxic environments. In these types of systems, the anodic oxidation reaction is catalyzed by anaerobic microorganisms, while the cathodic reduction reaction can be carried out biotically or abiotically. Membranes as separators in MFCs are the primary requirements for optimal electrochemical and microbiological performance. MFC configuration and operation are similar to those of proton-exchange membrane fuel cells (PEMFCs)-both having at least one anode and one cathode split by a membrane or separator. The Nafion® 117 (NF-117) membrane, made from perfluorosulfonic acid, is a membrane used as a separator in PEMFCs. By analogy of the operation between electrochemical systems and MFCs, NF-117 membranes have been widely used as separators in MFCs. The main disadvantage of this type of membrane is its high cost; membranes in MFCs can represent up to 60% of the MFC's total cost. This is one of the challenges in scaling up MFCs: finding alternative membranes or separators with low cost and good electrochemical characteristics. The aim of this work is to critically review state-of-the-art membranes and separators used in MFCs. The scope of this review includes: (i) membrane functions in MFCs, (ii) most-used membranes, (iii) membrane cost and efficiency, and (iv) membrane-less MFCs. Currently, there are at least 20 different membranes or separators proposed and evaluated for MFCs, from basic salt bridges to advanced synthetic polymer-based membranes, including ceramic and unconventional separator materials. Studies focusing on either low cost or the use of natural polymers for proton-exchange membranes (PEM) are still scarce. Alternatively, in some works, MFCs have been operated without membranes; however, significant decrements in Coulombic efficiency were found. As the type of membrane affects the performance and total cost of MFCs, it is recommended that research efforts are increased in order to develop new, more economic membranes that exhibit favorable properties and allow for satisfactory cell performance at the same time. The current state of the art of membranes for MFCs addressed in this review will undoubtedly serve as a key insight for future research related to this topic.
ABSTRACT
Se detalla y fundamenta la técnica de extracción atraumática de dientestemporales unirradiculares en pacientes pediátricos con trastornos de lacoagulación utilizando separadores elastoméricos. Se expone el caso deun paciente pediátrico con diagnóstico de defi ciencia de factor X de lacoagulación, quien requirió de la extracción atraumática de los órganosdentarios centrales superiores temporales debido a la gingivorragiapropia de la exfoliación natural.
We describe the technique of atraumatic tooth extraction for single-rooted temporary and permanent teeth in pediatric patients with bleed-ing disorders using elastomeric separators and discuss its benefi ts. We present the case of a pediatric patient diagnosed with coagulation factor X defi ciency who required the atraumatic extraction of his temporary upper central teeth due to gingival bleeding caused by natural exfoliation.