ABSTRACT
Maya Blue-type specimens prepared from indigo (1 wt %) plus kaolinite, montmorillonite, palygorskite, sepiolite, and silicalite are studied. Liquid chromatography with diode array detection, ultra-performance liquid chromatography coupled with mass spectrometry, and pyrolysis-silylation gas chromatography-mass spectrometry analyses of the extracts from these specimens combined with spectral and solid-state voltammetry, electrochemical impedance spectroscopy, and scanning electrochemical microscopy techniques provide evidence for the presence of a significant amount of dehydroindigo and isatin accompanying indigo and other minority organic compounds in all samples. Solid-state electrochemistry data permits the estimatation of indigo loading in archeological Maya Blue, which is in the range of 0.2 to 1.5 wt %. These results support a view of 'genuine' Maya Blue-type materials as complex polyfunctional organic-inorganic hybrids.
Subject(s)
Indigo Carmine/chemistry , Isatin/chemistry , Magnesium Compounds/chemistry , Magnesium Silicates/chemistry , Silicon Compounds/chemistry , Bentonite/chemistry , Bentonite/isolation & purification , Chromatography, High Pressure Liquid , Chromatography, Liquid , Electrochemistry , Humans , Indigo Carmine/isolation & purification , Isatin/isolation & purification , Kaolin/chemistry , Kaolin/isolation & purification , Magnesium Compounds/isolation & purification , Magnesium Silicates/isolation & purification , Mass Spectrometry , Oxidation-Reduction , Silicon Compounds/isolation & purificationABSTRACT
In this study, an ultrasonic irradiation technique was utilized to mitigate the fouling of polyethersulfone (PES) and polyvinylidene fluoride (PVDF) membranes. The use of ultrasound at 20 kHz was applied to a dead-end microfiltration cell in order to mitigate fouling caused by the presence of colloidal bentonite particles. The effect of ultrasonic power and pulse duration on the permeate flux recovery was examined. Measurements indicate that an increase in ultrasonic power and longer pulse duration results to a higher permeate flux recovery. In order to reduce power consumption, a low to high power shift (LHPS) and pulsation method, were investigated. Methods of cleaning such as ultrasonic irradiation, ultrasonic cleaning with forward flushing and ultrasonic cleaning with backwashing were utilized and their cleaning efficiencies were examined. The cleaning performance was assessed using the clean water flux method and scanning electron microscope analysis of the cleaned membranes. Results showed that LHPS and pulsation method both improve the permeate flux recovery but were not able to attain the 93.97 and 74.88% flux recovery for PES and PVDF that was achieved by constant-15 W ultrasonic cleaning. In addition, forward flushing and backwashing may enhance the performance of ultrasonic cleaning at 9 W but could become disadvantageous at 15 W.
Subject(s)
Bentonite/chemistry , Equipment Contamination/prevention & control , Membranes, Artificial , Polymers/chemistry , Polyvinyls/chemistry , Sonication/methods , Sulfones/chemistry , Water/chemistry , Bentonite/isolation & purification , Bentonite/radiation effects , High-Energy Shock Waves , Polymers/radiation effects , Polyvinyls/radiation effects , Pressure , Radiation Dosage , Sulfones/radiation effects , Ultrafiltration/instrumentation , Water Purification/instrumentationABSTRACT
The effects of four clarification agents (bentonite, charcoal, PVPP and potassium caseinate) on the removal of residues of three fungicides (famoxadone, fluquinconazole and trifloxystrobin) applied directly to a racked white wine, elaborated from Airen variety grapes from the D.O. Region of Jumilla (Murcia, Spain) are studied. The clarified wines were filtered with 0.45 microm nylon filters to determine the influence of this winemaking process in the disappearance of fungicide residues. Hydro-alcoholic solutions with the three fungicides at concentrations of 1 and 2 ppm were then added through intense stirring to each of the containers. Two hours later, the corresponding clarifying agent was added with intense stirring for some minutes. The containers were then sealed and left to settle for five days. Once the clean wines had been racked, they were filtered through nylon 0.45 microm pore filters. All assays were performed three times. Analytical determination of fluquinconazole and trifloxystrobin was performed by gas chromatography with an electron captor detector (ECD), while that of famoxadone was made using an HPLC-DAD. For the three fungicides, the highest elimination is produced with the clarification by charcoal, reaching Levels of removal of 100% in all cases. For the four clarifying agents, the highest elimination is produced for the fluquinconazole residues. The fungicide which is retained most in the lees is famoxadone, since it has the lowest solubility of the three pesticides studied. The highest percentage of residues in the lees is obtained for the assay with charcoal. The filtration process of the clarified wines using the four agents studied is not effective, since the elimination percentage is generally lower than 10% of the initial residues in the non-clarified wines.
