ABSTRACT
After the Fukushima Daiichi Nuclear Power Plant accident in March 2011, concentrations of cesium isotopes (133Cs, 134Cs, and 137Cs) were measured in zooplankton collected in the Pacific off the east coast of Japan from May 2012 to February 2015. The time series of the data exhibited sporadic 137Cs concentration peaks in zooplankton. In addition, the atom ratio of 137Cs/133Cs in zooplankton was consistently high compared to that in ambient seawater throughout the sampling period. These phenomena cannot be explained fully by the bioaccumulation of 137Cs in zooplankton via ambient seawater intake, the inclusion of resuspended sediment in the plankton sample, or the taxonomic composition of the plankton. Autoradiography revealed highly radioactive particles within zooplankton samples, which could be the main factor underlying the sporadic appearance of high 137Cs concentrations in zooplankton as well as the higher ratio of 137Cs/133Cs in zooplankton than in seawater.
Subject(s)
Water Pollutants, Radioactive/analysis , Zooplankton/chemistry , Animals , Cesium Isotopes/chemistry , Cesium Radioisotopes/chemistry , Fukushima Nuclear Accident , Geologic Sediments/chemistry , Japan , Pacific Ocean , Seawater/analysis , Zooplankton/metabolismABSTRACT
In this work, the capability of nanometallic Ca/CaO methanol suspension in removing and/or immobilizing stable ((133)Cs) and radioactive cesium species ((134)Cs and (137)Cs) in contaminated fly ash was investigated. After a first methanol and second water washing yielded only 45% of (133)Cs removal. While, after a first methanol washing, the second solvent with nanometallic Ca/CaO methanol suspension yielded simultaneous enhanced removal and immobilization about 99% of (133)Cs. SEM-EDS analysis revealed that the mass percent of detectable (133)Cs on the fly ash surface recorded a 100% decrease. When real radioactive cesium contaminated fly ash (containing an initial 14,040Bqkg(-1)(134)Cs and (137)Cs cumulated concentration) obtained from burning wastes from Fukushima were reduced to 3583Bqkg(-1) after treatment with nanometallic Ca/CaO methanol suspension. Elution test conducted on the treated fly ash gave 100BqL(-1) total (134)Cs and (137)Cs concentrations in eluted solution. Furthermore, both ash content and eluted solution concentrations of (134)Cs and (137)Cs were much lower than the Japanese Ministry of the Environment regulatory limit of 8000Bqkg(-1) and 150BqL(-1) respectively. The results of this study suggest that the nanometallic Ca/CaO methanol suspension is a highly potential amendment for the remediation of radioactive cesium-contaminated fly ash.
Subject(s)
Calcium Compounds/chemistry , Calcium/chemistry , Cesium Radioisotopes/chemistry , Cesium/chemistry , Coal Ash/analysis , Methanol/chemistry , Oxides/chemistry , Cesium/isolation & purification , Cesium Isotopes/chemistry , Cesium Isotopes/isolation & purification , Cesium Radioisotopes/isolation & purification , Incineration , Microscopy, Electron, Scanning , Refuse Disposal , SuspensionsABSTRACT
Twenty-one years after the Chernobyl accident, lichen and moss samples were collected from the Ordu province, which was already chosen for a related study some years ago. It was observed that 137Cs activity concentration ranged from 31 to 469 Bq kg(-1) in the moss and from 132 to 1508 Bq kg(-1) in the lichen samples. The decrease of the activity concentrations in the present measurements (2007) relative to those in 1997 (over a period of 10 y) indicated ecological half-lives between 1.8 and 10.4 y for the moss and between 2.1 and 13.7 y for the lichen samples. It was observed that 137Cs was still eminent in the area studied. Moreover, 40K activity concentrations and K element concentrations were measured and their relationships were discussed.
Subject(s)
Bryophyta/metabolism , Cesium/chemistry , Cesium/metabolism , Lichens/metabolism , Soil Pollutants, Radioactive/chemistry , Bryophyta/chemistry , Cesium Isotopes/chemistry , Cesium Isotopes/metabolism , Half-Life , Lichens/chemistry , Soil Pollutants, Radioactive/metabolism , TurkeyABSTRACT
To document the short-term dynamics of Cs, 4 kg of (133)Cs were introduced into an 11.4-ha, 157 000 m(3) reservoir previously contaminated with (137)Cs from past reactor operations at the US Department of Energy's Savannah River Site near Aiken, South Carolina, USA. The (133)Cs addition resulted in an increase of 6.1 MBq of (137)Cs (1.9 mug (137)Cs) in the water column over the following 260 days. Possible sources for the increased (137)Cs included (1) release from the sediments, (2) release from the approximately 26 000 kg of aquatic macrophytes that occupied 80% of the reservoir, and (3) wash-in from the pond's watershed. Data are presented to indicate that release from the sediments was the principal source of the (137)Cs increase. The fraction of (137)Cs released from the sediments (0.7%) is consistent with laboratory measurements of (137)Cs desorption from neighboring ponds on the Savannah River Site.
