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Chem Commun (Camb) ; 55(37): 5367-5370, 2019 May 10.
Article in English | MEDLINE | ID: mdl-30994655

ABSTRACT

A library of 26 mixed ligand UiO-66 analogs was synthesized, characterized, and screened for catalytic degradation of the chemical warfare agent (CWA) simulant dimethyl 4-nitrophenylphosphate (DMNP). The MOFs were screened and compared to physical mixtures of the same single component MOFs. Several of the MOFs display higher catalytic activity than the parent UiO-66 and other single ligand UiO-66 analogues.


Subject(s)
Chemical Warfare Agents/chemistry , Metal-Organic Frameworks/analogs & derivatives , Catalysis , Ligands , Metal-Organic Frameworks/chemical synthesis , Microscopy, Electron, Scanning , Nitrophenols/chemistry , Organophosphorus Compounds/chemistry , Particle Size
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