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1.
Environ Pollut ; 352: 124140, 2024 Jul 01.
Article in English | MEDLINE | ID: mdl-38740247

ABSTRACT

The average-speed emission model (Speed-based model), a widely used and simple method of calculating road vehicle emissions, offers easy accessibility by expressing emissions as a function of average speed. However, there are limitations in expressing emissions generated through complex mechanisms simply as a function of speed. Real-world driving tests using a portable emission measurement system can incorporate the impact of vehicle driving load on emissions. In this study, we analyzed real-world emissions data from 94 light-duty vehicles and developed time-based emission factors depending on vehicle speed and vehicle-specific power (VSP). We also propose a speed-VSP based model to estimate regional CO2 and NOx emissions by combining time-based emission factors and vehicle operating times. The speed-based model and Speed-VSP based model exhibit a 44% difference in NOx emissions and a 29% difference in CO2 emission. In a comparison of the two models against RDE test results, the speed-VSP based model achieved high accuracy in predicting NOx and CO2 emissions with a lower root mean square error (RMSE). Specifically, for NOx emissions predictions, the speed-VSP based model achieved an RMSE of 122-270 mg/km, while the speed-based model showed a much higher RMSE of 435-476 mg/km. For CO2 emissions predictions, the speed-VSP based model achieved an RMSE of 34-56 mg/km, while the speed-based model showed a much higher RMSE of 36-72 mg/km. The results of this study present an opportunity to reassess and improve conventional method of measuring and evaluating emissions from road transport.


Subject(s)
Air Pollutants , Carbon Dioxide , Environmental Monitoring , Nitrogen Oxides , Vehicle Emissions , Vehicle Emissions/analysis , Republic of Korea , Carbon Dioxide/analysis , Air Pollutants/analysis , Environmental Monitoring/methods , Nitrogen Oxides/analysis , Air Pollution/statistics & numerical data , Transportation , Models, Theoretical
2.
Environ Int ; 187: 108697, 2024 May.
Article in English | MEDLINE | ID: mdl-38696979

ABSTRACT

Road dust is a demonstrated source of urban air pollution. Given this, the implementation of street sweeping strategies that effectively limit road dust accumulation and resuspension should be a public health priority. Research examining the effectiveness of street sweeping for road dust removal in support of good air quality has been limited to date. To address this, the study aimed to assess the use of a regenerative-air street sweeper to efficiently remove road dust particles and metal(loid)s in size fractions relevant for respiratory exposure in Toronto, Canada. As part of this, the mass amounts, particle size distribution and elemental concentrations of bulk road dust before and after sweeping at five arterial sites were characterized. Sweeping reduced the total mass amount of thoracic-sized (<10 µm) road dust particles by 76 % on average. A shift in the size distribution of remaining particles toward finer fractions was observed in post-sweeping samples, together with an enrichment in many metal(loid)s such as Co, Ti and S. Overall, the mass amounts of metal(loid)s of respiratory health concern like Cu and Zn were greatly reduced with sweeping. Traffic volume and road surface quality were predictors of dust loadings and elemental concentrations. Road surface quality was also found to impact street sweeping efficiencies, with larger mass amounts per unit area collected post-sweeping where street surfaces were distressed. This study demonstrates that street sweeping using advanced technology can be highly effective for road dust removal, highlighting its potential to support air quality improvement efforts. The importance of tailoring sweeping service levels and technologies locally as per the quality of road surface and traffic patterns is emphasized. Continued efforts to mitigate non-exhaust emissions that pose a respiratory health risk at their source is essential.


Subject(s)
Air Pollutants , Dust , Metals , Particle Size , Dust/analysis , Air Pollutants/analysis , Metals/analysis , Air Pollution/prevention & control , Cities , Environmental Monitoring/methods , Humans , Particulate Matter/analysis , Vehicle Emissions/analysis
3.
Bull Environ Contam Toxicol ; 112(5): 76, 2024 May 11.
Article in English | MEDLINE | ID: mdl-38733550

ABSTRACT

Traffic-related particulate matter emissions have been considerably reduced due to stringent regulations in Europe. However, emission of diesel-powered vehicles still poses a significant environmental threat, affecting rural ecosystems and agriculture. Several studies have reported that polycyclic aromatic hydrocarbons (PAHs), a group of potentially toxic organic compounds, can accumulate in crops and vegetables. In our study, white mustard (Sinapis alba L.) plants were experimentally treated with an extract of diesel exhaust. PAH concentrations were measured in the different plant compartments (stems, leaves and seeds), bioconcentration factors (BCFs) were also calculated. Significant accumulation was measured in the leaves and seeds, stems showed lower accumulation potential. All plant matrices showed high tendency to accumulate higher molecular weight PAHs, BCF was the highest in the 6-ring group. The fact that considerable accumulation was experienced in the seeds might show the risk of cultivating crops nearby roads highly impacted by traffic-related emissions.


Subject(s)
Air Pollutants , Environmental Monitoring , Polycyclic Aromatic Hydrocarbons , Seeds , Seeds/chemistry , Polycyclic Aromatic Hydrocarbons/analysis , Polycyclic Aromatic Hydrocarbons/metabolism , Air Pollutants/analysis , Sinapis , Vehicle Emissions/analysis , Particulate Matter/analysis
4.
Environ Monit Assess ; 196(6): 591, 2024 May 31.
Article in English | MEDLINE | ID: mdl-38819539

ABSTRACT

The increasing number of vehicles are emitting a large amount of particles into the atmosphere, causing serious harm to the ecological environment and human health. This study conducted the Worldwide Harmonized Light Vehicles Test Cycle (WLTC) to investigate the emission characteristics of particle number (PN) of China-VI gasoline vehicles with different gasoline. The gasoline with lower aromatic hydrocarbons and olefins reduced particulate matter (PM) and PN emissions by 24% and 52% respectively. The average PN emission rate of the four vehicles during the first 300 s (the cold start period) was 7.2 times that of the 300 s-1800s. Additionally, because the particle transmission time and instrument response time, the test results of instantaneous emissions of PN were not synchronized with vehicle specific power (VSP). By calculating the Spearman correlation coefficient between pre-average vehicle specific power (PAVSP) and the test results of PN instantaneous emissions, the delay time was determined as 10s. After the PN emissions results were corrected, the PN emissions were found to be more related to VSP. By analyzing the influence of driving status on emission, this study found that vehicles in acceleration mode increased PN emissions by 76% compared to those in constant speed mode.


Subject(s)
Air Pollutants , Environmental Monitoring , Gasoline , Particulate Matter , Vehicle Emissions , Vehicle Emissions/analysis , Gasoline/analysis , China , Air Pollutants/analysis , Environmental Monitoring/methods , Particulate Matter/analysis , Automobile Driving , Air Pollution/statistics & numerical data
5.
Environ Monit Assess ; 196(6): 521, 2024 May 07.
Article in English | MEDLINE | ID: mdl-38714584

ABSTRACT

The transport sector is considered the largest contributor of air pollutants in urban areas, mainly on-road vehicles, affecting the environment and human health. Bahía Blanca is a medium-sized Latin American city, with high levels of traffic in the downtown area during peak hours. In this regard, it is necessary to analyze air pollution using an air quality model considering that there are no air pollutant measurements in the central area. Furthermore, this type of study has not been carried out in the region and since the city is expected to grow, it is necessary to evaluate the current situation in order to make effective future decisions. In this sense, the AERMOD model (US-EPA version) and the RLINE source type were used in this work. This study analyzes the variations of pollutant concentrations coming from mobile sources in Bahía Blanca's downtown area, particularly carbon monoxide (CO) and nitrogen oxides (NOx) during the period Jul-2020 to Jun-2022. It is interesting to note the results show the maximum concentration values detected are not directly associated with maximum levels of vehicle flow or emission rates, which highlights the importance of meteorological parameters in the modeling. In addition, alternative scenarios are proposed and analyzed from a sustainable approach. Regarding the scenario analysis, it can be concluded that diesel vehicles have a large influence on NOx emissions. Moreover, restrictions as strict as those proposed for a Low Emission Zone would be less applicable in the city than alternative temporary measures that modify traffic at peak hours.


Subject(s)
Air Pollutants , Air Pollution , Carbon Monoxide , Cities , Environmental Monitoring , Vehicle Emissions , Environmental Monitoring/methods , Air Pollutants/analysis , Air Pollution/statistics & numerical data , Vehicle Emissions/analysis , Carbon Monoxide/analysis , Nitrogen Oxides/analysis , Latin America , Models, Theoretical , Particulate Matter/analysis
6.
Part Fibre Toxicol ; 21(1): 26, 2024 May 22.
Article in English | MEDLINE | ID: mdl-38778339

ABSTRACT

BACKGROUND: During inhalation, airborne particles such as particulate matter ≤ 2.5 µm (PM2.5), can deposit and accumulate on the alveolar epithelial tissue. In vivo studies have shown that fractions of PM2.5 can cross the alveolar epithelium to blood circulation, reaching secondary organs beyond the lungs. However, approaches to quantify the translocation of particles across the alveolar epithelium in vivo and in vitro are still not well established. In this study, methods to assess the translocation of standard diesel exhaust particles (DEPs) across permeable polyethylene terephthalate (PET) inserts at 0.4, 1, and 3 µm pore sizes were first optimized with transmission electron microscopy (TEM), ultraviolet-visible spectroscopy (UV-VIS), and lock-in thermography (LIT), which were then applied to study the translocation of DEPs across human alveolar epithelial type II (A549) cells. A549 cells that grew on the membrane (pore size: 3 µm) in inserts were exposed to DEPs at different concentrations from 0 to 80 µg.mL- 1 ( 0 to 44 µg.cm- 2) for 24 h. After exposure, the basal fraction was collected and then analyzed by combining qualitative (TEM) and quantitative (UV-VIS and LIT) techniques to assess the translocated fraction of the DEPs across the alveolar epithelium in vitro. RESULTS: We could detect the translocated fraction of DEPs across the PET membranes with 3 µm pore sizes and without cells by TEM analysis, and determine the percentage of translocation at approximatively 37% by UV-VIS (LOD: 1.92 µg.mL- 1) and 75% by LIT (LOD: 0.20 µg.cm- 2). In the presence of cells, the percentage of DEPs translocation across the alveolar tissue was determined around 1% at 20 and 40 µg.mL- 1 (11 and 22 µg.cm- 2), and no particles were detected at higher and lower concentrations. Interestingly, simultaneous exposure of A549 cells to DEPs and EDTA can increase the translocation of DEPs in the basal fraction. CONCLUSION: We propose a combination of analytical techniques to assess the translocation of DEPs across lung tissues. Our results reveal a low percentage of translocation of DEPs across alveolar epithelial tissue in vitro and they correspond to in vivo findings. The combination approach can be applied to any traffic-generated particles, thus enabling us to understand their involvement in public health.


Subject(s)
Particulate Matter , Pulmonary Alveoli , Vehicle Emissions , Humans , Vehicle Emissions/toxicity , Vehicle Emissions/analysis , A549 Cells , Particulate Matter/toxicity , Particulate Matter/analysis , Pulmonary Alveoli/drug effects , Pulmonary Alveoli/metabolism , Particle Size , Microscopy, Electron, Transmission , Polyethylene Terephthalates/chemistry , Polyethylene Terephthalates/toxicity , Alveolar Epithelial Cells/drug effects , Alveolar Epithelial Cells/metabolism , Air Pollutants/toxicity , Air Pollutants/analysis
7.
Ecotoxicol Environ Saf ; 278: 116354, 2024 Jun 15.
Article in English | MEDLINE | ID: mdl-38691882

ABSTRACT

After the resumption of work and production following the COVID-19 pandemic, many cities entered a "transition phase", characterized by the gradual recovery of emission levels from various sources. Although the overall PM2.5 emission trends have recovered, the specific changes in different sources of PM2.5 remain unclear. Here, we investigated the changes in source contributions and the evolution pattern of pollution episodes (PE) in Wuhan during the "transition period" and compared them with the same period during the COVID-19 lockdown. We found that vehicle emissions, industrial processes, and road dust exhibited significant recoveries during the transition period, increasing by 5.4%, 4.8%, and 3.9%, respectively, during the PE. As primary emissions increased, secondary formation slightly declined, but it still played a predominant role (accounting for 39.1∼ 43.0% of secondary nitrate). The reduction in industrial activities was partially offset by residential burning. The evolution characteristics of PE exhibited significant differences between the two periods, with PM2.5 concentration persisting at a high level during the transition period. The differences in the evolution patterns of the two periods were also reflected in their change rates at each stage, which mostly depend on the pre-PE concentration level. The transition period shows a significantly higher value (8.4 µg m-3 h-1) compared with the lockdown period, almost double the amount. In addition to local emissions, regional transport should be a key consideration in pollution mitigation strategies, especially in areas adjacent to Wuhan. Our study quantifies the variations in sources between the two periods, providing valuable insights for optimizing environmental planning to achieve established goals.


Subject(s)
Air Pollutants , Air Pollution , COVID-19 , Cities , Environmental Monitoring , Particulate Matter , China/epidemiology , COVID-19/epidemiology , Environmental Monitoring/methods , Air Pollutants/analysis , Air Pollution/statistics & numerical data , Particulate Matter/analysis , Humans , Vehicle Emissions/analysis , SARS-CoV-2 , Industry , Pandemics
8.
Sci Total Environ ; 933: 173148, 2024 Jul 10.
Article in English | MEDLINE | ID: mdl-38735334

ABSTRACT

The concentration of 56 volatile organic compounds (VOCs) in the ambient air of Shenyang was continuously monitored at four sites in 2021. The characteristics, sources, secondary pollution potential and health risks of VOCs in different functional regions of Shenyang were discussed. The results indicate that the concentration of VOCs in industrial regions was significantly higher than that in non-industrial regions, with a mean of 41.09 ± 69.82 parts per billion volumes (ppbv) compared to 19.99 ± 17.86 ppbv (commercial & residential region in urban fringe), 27.51 ± 28.81 ppbv (educational & scenic region) and 29.71 ± 23.97 ppbv (commercial & residential region in urban center). The positive matrix factorization (PMF) model was utilized to assign the sources of VOCs in Shenyang, and six factors were recognized: gasoline vehicles (34.8 %), diesel vehicles (28.3 %), combustion (11.4 %), biogenic emissions (9.7 %), industrial processes (8.2 %), and fuel evaporation (7.7 %). The results of the reactivity evaluation indicated that the ozone (O3) formation potential (OFP) was primarily influenced by industrial processes (29.2 %), diesel vehicles (25.7 %), biogenic emissions (17.0 %). These three factors were also the top three contributors to secondary organic aerosol formation potential (SOAP), accounting for 44.2 %, 9.4 % and 30.3 %, respectively. At the all four sites, the non-carcinogenic and carcinogenic risks of VOCs ranged from 1.6 × 10-2 to 3.8 × 10-2 and from 2.3 × 10-6 to 3.3 × 10-6, respectively. And the main risks can be attributed to emissions from industrial processes and gasoline vehicles. These findings suggested to strengthen the control of vehicle emissions throughout all regions in Shenyang and industrial processes emissions in industrial regions.


Subject(s)
Air Pollutants , Environmental Monitoring , Volatile Organic Compounds , Volatile Organic Compounds/analysis , Air Pollutants/analysis , China , Vehicle Emissions/analysis , Risk Assessment , Air Pollution/statistics & numerical data , Humans , Cities , Ozone/analysis
9.
J Environ Manage ; 359: 121017, 2024 May.
Article in English | MEDLINE | ID: mdl-38718602

ABSTRACT

Energy transition currently brings focus on fuel cell micro-combined heat and power (mCHP) systems for residential uses. The two main technologies already commercialized are the Proton Exchange Membrane Fuel Cells (PEMFCs) and Solid Oxide Fuel Cells (SOFCs). The pollutant emissions of one system of each technology have been tested with a portable probe both in laboratory and field-test configurations. In this paper, the nitrogen oxides (NOx), sulphur dioxide (SO2), and carbon monoxide (CO) emission levels are compared to other combustion technologies such as a recent Euro 6 diesel automotive vehicle, a classical gas condensing boiler, and a gas absorption heat pump. At last, a method of converting the concentration of pollutants (in ppm) measured by the sensors into pollutant intensity per unit of energy (in mg/kWh) is documented and reported. This allows for comparing the pollutant emissions levels with relevant literature, especially other studies conducted with other measuring sensors. Both tested residential fuel cell technologies fed by natural gas can be considered clean regarding SO2 and NOx emissions. The CO emissions can be considered quite low for the tested SOFC and even nil for the tested PEMFC. The biggest issue of natural gas fuel cell technologies still lies in the carbon dioxide (CO2) emissions associated with the fossil fuel they consume. The gas absorption heat pump however shows worse NOx and CO levels than the classical gas condensing boiler. At last, this study illustrates that the high level of hybridization between a fuel cell and a gas boiler may be responsible for unexpected ON/OFF cycling behaviours and therefore prevent both sub-systems from operating as optimally and reliably as they would have as standalone units.


Subject(s)
Air Pollutants , Nitrogen Oxides , Air Pollutants/analysis , Nitrogen Oxides/analysis , Carbon Monoxide/analysis , Sulfur Dioxide/analysis , Benchmarking , Vehicle Emissions/analysis , Environmental Monitoring/methods
11.
Occup Environ Med ; 81(5): 238-243, 2024 Jun 03.
Article in English | MEDLINE | ID: mdl-38811167

ABSTRACT

OBJECTIVES: Increasing epidemiological and experimental evidence suggests that particle exposure is an environmental risk factor for chronic kidney disease (CKD). However, only a few case-control studies have investigated this association in an occupational setting. Hence, our objective was to investigate associations between particle exposure and CKD in a large cohort of Swedish construction workers. METHODS: We performed a retrospective cohort study in the Swedish Construction Workers' Cohort, recruited 1971-1993 (n=286 089). A job-exposure matrix was used to identify workers exposed to nine different particulate exposures, which were combined into three main categories (inorganic dust and fumes, wood dust and fibres). Incident CKD and start of renal replacement therapy (RRT) were obtained from validated national registries until 2021 and analysed using adjusted Cox proportional hazards models. RESULTS: Exposure to inorganic dust and fumes was associated with an increased risk of CKD and RRT during working age (adjusted HR for CKD at age <65 years 1.15, 95% CI 1.05 to 1.26). The elevated risk did not persist after retirement age. Exposure to cement dust, concrete dust and diesel exhaust was associated with CKD. Elevated HRs were also found for quartz dust and welding fumes. CONCLUSIONS: Workers exposed to inorganic particles seem to be at elevated risk of CKD and RRT. Our results are in line with previous evidence of renal effects of ambient air pollution and warrant further efforts to reduce occupational and ambient particle exposure.


Subject(s)
Construction Industry , Dust , Occupational Diseases , Occupational Exposure , Renal Insufficiency, Chronic , Humans , Occupational Exposure/adverse effects , Sweden/epidemiology , Renal Insufficiency, Chronic/epidemiology , Renal Insufficiency, Chronic/etiology , Middle Aged , Male , Adult , Construction Industry/statistics & numerical data , Retrospective Studies , Occupational Diseases/epidemiology , Occupational Diseases/etiology , Particulate Matter/adverse effects , Particulate Matter/analysis , Female , Aged , Risk Factors , Air Pollutants, Occupational/adverse effects , Proportional Hazards Models , Cohort Studies , Vehicle Emissions/analysis , Construction Materials/adverse effects , Wood
12.
Int J Circumpolar Health ; 83(1): 2343125, 2024 Dec.
Article in English | MEDLINE | ID: mdl-38626426

ABSTRACT

Arctic miners face significant risks from diesel exhaust and dust exposure, potentially leading to adverse respiratory health. Employers must limit harmful exposures, using personal protective equipment (PPE) as a last line of defense. This study explored the association between reported respiratory exposure and symptoms, and PPE training and usage. Data from the MineHealth study (2012-2014) included a total of 453 Arctic open pit miners in Norway, Sweden, and Finland. Participants answered questions on exposure to dust and diesel exhaust, respiratory symptoms, and PPE use, in addition to age, gender, BMI, smoking, and self-rated health. Estimated exposure to dust was common, reported by 91%, 80%, and 82% and that of diesel exhaust by 84%, 43%, and 47% of workers in Sweden, Finland, and Norway, respectively. Reported dust exposure was significantly related to respiratory symptoms (OR 2.2, 95% CI 1.3-3.7), diesel exposure increased the occurrence of wheezing (OR 2.6, 95% CI 1.3-5.4). PPE use varied between the studied mines. Non-use was common and related to reduced visibility, wetness, skin irritation and fogging of the respiratory PPE. Future research should employ more precise exposure assessment, respiratory function as well as explore the reasons behind the non-compliance of PPE use.


Subject(s)
Air Pollutants, Occupational , Lung Diseases , Occupational Exposure , Humans , Dust/analysis , Vehicle Emissions/analysis , Occupational Exposure/adverse effects , Air Pollutants, Occupational/analysis , Self Report , Protective Devices
13.
Toxicol Ind Health ; 40(6): 337-351, 2024 Jun.
Article in English | MEDLINE | ID: mdl-38597775

ABSTRACT

Gasoline station attendants are exposed to numerous chemicals that might have genotoxic and carcinogenic potential, such as benzene in fuel vapor and particulate matter and polycyclic aromatic hydrocarbons in vehicle exhaust emission. According to IARC, benzene and diesel particulates are Group 1 human carcinogens, and gasoline has been classified as Group 2A "possibly carcinogenic to humans." At gas stations, self-service is not implemented in Turkey; fuel-filling service is provided entirely by employees, and therefore they are exposed to those chemicals in the workplace during all working hours. Genetic monitoring of workers with occupational exposure to possible genotoxic agents allows early detection of cancer. We aimed to investigate the genotoxic damage due to exposures in gasoline station attendants in Turkey. Genotoxicity was evaluated by the Comet, chromosomal aberration, and cytokinesis-block micronucleus assays in peripheral blood lymphocytes. Gasoline station attendants (n = 53) had higher tail length, tail intensity, and tail moment values than controls (n = 61). In gasoline station attendants (n = 46), the frequencies of chromatid gaps, chromosome gaps, and total aberrations were higher compared with controls (n = 59). Increased frequencies of micronuclei and nucleoplasmic bridges were determined in gasoline station attendants (n = 47) compared with controls (n = 40). Factors such as age, duration of working, and smoking did not have any significant impact on genotoxic endpoints. Only exposure increased genotoxic damage in gasoline station attendants independently from demographic and clinical characteristics. Occupational exposure-related genotoxicity risk may increase in gasoline station attendants who are chronically exposed to gasoline and various chemicals in vehicle exhaust emissions.


Subject(s)
Chromosome Aberrations , DNA Damage , Gasoline , Micronucleus Tests , Occupational Exposure , Humans , Occupational Exposure/adverse effects , Occupational Exposure/analysis , Gasoline/toxicity , Adult , Male , Turkey , Chromosome Aberrations/chemically induced , DNA Damage/drug effects , Middle Aged , Air Pollutants, Occupational/analysis , Air Pollutants, Occupational/toxicity , Comet Assay , Biomarkers , Vehicle Emissions/toxicity , Vehicle Emissions/analysis , Lymphocytes/drug effects , Female , Mutagens/toxicity , Benzene/toxicity , Benzene/analysis
14.
Sci Total Environ ; 927: 172202, 2024 Jun 01.
Article in English | MEDLINE | ID: mdl-38599399

ABSTRACT

As an emerging atmospheric pollutant, airborne environmentally persistent free radicals (EPFRs) are formed during many combustion processes and pose various adverse health effects. In health-oriented air pollution control, it is vital to evaluate the health effects of atmospheric fine particulate matter (PM2.5) from different emission sources. In this study, various types of combustion-derived PM2.5 were collected on filters in a partial-flow dilution tunnel sampling system from three typical emission sources: coal combustion, biomass burning, and automobile exhaust. Substantial concentrations of EPFRs were determined in PM2.5 samples and associated with significant potential exposure risks. Results from in vitro cytotoxicity and oxidative potential assays suggest that EPFRs may cause substantial generation of reactive oxygen species (ROS) upon inhalation exposure to PM2.5 from anthropogenic combustion sources, especially from automobile exhaust. This study provides important evidence for the source- and concentration-dependent health effects of EPFRs in PM2.5 and motivates further assessments to advance public health-oriented PM2.5 emission control.


Subject(s)
Air Pollutants , Particulate Matter , Vehicle Emissions , Particulate Matter/analysis , Air Pollutants/analysis , Free Radicals , Vehicle Emissions/analysis , Environmental Monitoring , Humans , Air Pollution/statistics & numerical data , Reactive Oxygen Species , Environmental Exposure
16.
Chemosphere ; 356: 141850, 2024 May.
Article in English | MEDLINE | ID: mdl-38582160

ABSTRACT

Coastal urban areas impact atmospheric chemistry and air quality through various sources, interactions, and processes. This study examines the mass concentrations of fine mode (PM2.5) aerosol and its major and trace components (Al, As, Ba, Bi, Ca, Cd, Co, Cr, Cu, Fe, K, Mg, Mo, Mn, Na, Ni, Pb, Sb, Se, Sr, Te, Ti, Tl, V, Zn). The comprehensive field measurements were conducted in Poland between September 2019 and May 2020. Seasonal distribution and drivers of these pollutants showed considerable variability. In winter, higher concentrations were observed for Pb, Co, and As due to the higher contribution of pyrogenic emission. The Principal Component Analysis provided evidence of anthropogenic sources of trace species associated with coal combustion by industry/power plants, brake wear-related emissions, vehicle emissions, shipping activities, road-resuspended dust, and urban construction activities. These results showed that major chemical elements (Ca, Na, Fe, Mg, Al, and K) contributed to 4.07-34.0% of all components. Se, Zn, and Br contributed 1.29%, 1.25%, and 1.04%, respectively, while other tracers ranged between 0.07% and 0.95%. The diagnostic ratio of V/Ni remained stable between 0.45 and 0.46 during the cold season, then increased in spring, indicating that ship emissions were an important source of these metals during the warm season.


Subject(s)
Air Pollutants , Environmental Monitoring , Particulate Matter , Seasons , Poland , Air Pollutants/analysis , Particulate Matter/analysis , Air Pollution/statistics & numerical data , Vehicle Emissions/analysis , Aerosols/analysis , Cities , Principal Component Analysis
17.
Sci Total Environ ; 928: 172463, 2024 Jun 10.
Article in English | MEDLINE | ID: mdl-38615764

ABSTRACT

BACKGROUND: Mammographic density (MD) is the most important breast cancer biomarker. Ambient pollution is a carcinogen, and its relationship with MD is unclear. This study aims to explore the association between exposure to traffic pollution and MD in premenopausal women. METHODOLOGY: This Spanish cross-sectional study involved 769 women attending gynecological examinations in Madrid. Annual Average Daily Traffic (AADT), extracted from 1944 measurement road points provided by the City Council of Madrid, was weighted by distances (d) between road points and women's addresses to develop a Weighted Traffic Exposure Index (WTEI). Three methods were employed: method-1 (1dAADT), method-2 (1dAADT), and method-3 (e1dAADT). Multiple linear regression models, considering both log-transformed percentage of MD and untransformed MD, were used to estimate MD differences by WTEI quartiles, through two strategies: "exposed (exposure buffers between 50 and 200 m) vs. not exposed (>200 m)"; and "degree of traffic exposure". RESULTS: Results showed no association between MD and traffic pollution according to buffers of exposure to the WTEI (first strategy) for the three methods. The highest reductions in MD, although not statistically significant, were detected in the quartile with the highest traffic exposure. For instance, method-3 revealed a suggestive inverse trend (eßQ1 = 1.23, eßQ2 = 0.96, eßQ3 = 0.85, eßQ4 = 0.85, p-trend = 0.099) in the case of 75 m buffer. Similar non-statistically significant trends were observed with Methods-1 and -2. When we examined the effect of traffic exposure considering all the 1944 measurement road points in every participant (second strategy), results showed no association for any of the three methods. A slightly decreased MD, although not significant, was observed only in the quartile with the highest traffic exposure: eßQ4 = 0.98 (method-1), and eßQ4 = 0.95 (methods-2 and -3). CONCLUSIONS: Our results showed no association between exposure to traffic pollution and MD in premenopausal women. Further research is needed to validate these findings.


Subject(s)
Breast Density , Environmental Exposure , Premenopause , Humans , Female , Environmental Exposure/statistics & numerical data , Cross-Sectional Studies , Adult , Spain , Traffic-Related Pollution/adverse effects , Breast Neoplasms/epidemiology , Middle Aged , Vehicle Emissions/analysis , Mammography , Air Pollutants/analysis
18.
Environ Int ; 187: 108658, 2024 May.
Article in English | MEDLINE | ID: mdl-38640612

ABSTRACT

During the unprecedented COVID-19 city lockdown, a unique opportunity arose to dissect the intricate dynamics of urban air quality, focusing on ultrafine particles (UFPs) and volatile organic compounds (VOCs). This study delves into the nuanced interplay between traffic patterns and UFP emissions in a subtropical urban setting during the spring-summer transition of 2021. Leveraging meticulous roadside measurements near a traffic nexus, our investigation unravels the intricate relationship between particle number size distribution (PNSD), VOCs mixing ratios, and detailed vehicle activity metrics. The soft lockdown era, marked by a 20-27% dip in overall traffic yet a surprising surge in early morning motorcycle activity, presented a natural experiment. We observed a consequential shift in the urban aerosol regime: the decrease in primary emissions from traffic substantially amplified the role of aged particles and secondary aerosols. This shift was particularly pronounced under stagnant atmospheric conditions, where reduced dilution exacerbated the influence of alternative emission sources, notably solvent evaporation, and was further accentuated with the resumption of normal traffic flows. A distinct seasonal trend emerged as warmer months approached, with aromatic VOCs such as toluene, ethylbenzene, and xylene not only increasing but also significantly contributing to more frequent particle growth events. These findings spotlight the criticality of targeted strategies at traffic hotspots, especially during periods susceptible to weak atmospheric dilution, to curb UFP and precursor emissions effectively. As we stand at the cusp of widespread vehicle electrification, this study underscores the imperative of a holistic approach to urban air quality management, embracing the complexities of primary emission reductions and the resultant shifts in atmospheric chemistry.


Subject(s)
Air Pollutants , Air Pollution , COVID-19 , Cities , Environmental Monitoring , Particulate Matter , SARS-CoV-2 , Vehicle Emissions , Volatile Organic Compounds , COVID-19/epidemiology , Particulate Matter/analysis , Volatile Organic Compounds/analysis , Vehicle Emissions/analysis , Air Pollutants/analysis , Air Pollution/statistics & numerical data , Humans , Seasons , Pandemics , Particle Size , Aerosols/analysis , Betacoronavirus , Coronavirus Infections/epidemiology , Pneumonia, Viral/epidemiology
19.
Environ Int ; 187: 108682, 2024 May.
Article in English | MEDLINE | ID: mdl-38669721

ABSTRACT

Concentrations of particulate matter (PM10, PM2.5), ultrafine (UFP), particle number (PNC), black carbon (BC), nitrogen dioxide (NO2) and nitrogen oxides (NOX) were measured in train carriages on diesel and bi-mode trains on inter-city and long-distance journeys in the United Kingdom (UK) using a high-quality mobile measurement system. Air quality on 15 different routes was measured using highly-time resolved data on a total of 119 journeys during three campaigns in winter 2020 and summer 2021; this included 13 different train classes. Each journey was sampled 4-10 times with approximatively 11,000 min of in-train concentrations in total. Mean-journey concentrations were 7.552 µg m-3 (PM10); 3.936 µg m-3 (PM2.5); 333-11,300 # cm-3 (PNC); 225-9,131 # cm-3 (UFP); 0.6-11 µg m-3 (BC); 28-201 µg m-3 (NO2); and 130-3,456 µg m-3 (NOX). The impact of different factors on in-train concentrations was evaluated. The presence of tunnels was the factor with the largest impact on the in-train particle concentrations with enhancements by a factor of 40 greater than baseline for BC, and a factor 6 to 7 for PM and PNC. The engine fuel mode was the factor with the largest impact on NO2 with enhancements of up to 14-times larger when the train run on diesel compared to the times running on electric on hybrid trains. Train classes with an age < 10 years observed the lowest in-train PM, BC and NOX concentrations reflecting improvements in aspects of rail technology in recent years. Air quality on UK diesel trains is higher than ambient concentrations but has lower PM2.5 and PNC than most other transport modes, including subway systems, diesel and petrol cars. This paper adds significantly to the evidence on exposure to poor air quality in transport micro-environments and provides the industry and regulatory bodies with reference-grade measurements on which to establish in-train air quality guidelines.


Subject(s)
Air Pollutants , Air Pollution , Environmental Monitoring , Particulate Matter , Vehicle Emissions , United Kingdom , Air Pollutants/analysis , Particulate Matter/analysis , Vehicle Emissions/analysis , Air Pollution/statistics & numerical data , Air Pollution/analysis , Environmental Monitoring/methods , Railroads , Nitrogen Oxides/analysis , Nitrogen Dioxide/analysis , Gasoline/analysis
20.
Environ Int ; 187: 108696, 2024 May.
Article in English | MEDLINE | ID: mdl-38678934

ABSTRACT

Ambient air ultrafine particles (UFP, particles with a diameter <100 nm) have gained significant attention in World Health Organization (WHO) air quality guidelines and European legislation. This review explores UFP concentrations and particle number size distributions (PNC-PNSD) in various transportation hotspots, including road traffic, airports, harbors, trains, and urban commuting modes (walking, cycling, bus, tram, and subway). The results highlight the lack of information on personal exposure at harbors and railway stations, inside airplanes and trains, and during various other commuting modes. The different lower particle size limits of the reviewed measurements complicate direct comparisons between them. Emphasizing the use of instruments with detection limits ≤10 nm, this review underscores the necessity of following standardized UFP measurement protocols. Road traffic sites are shown to exhibit the highest PNC within cities, with PNC and PNSD in commuting modes driven by the proximity to road traffic and weather conditions. In closed environments, such as cars, buses, and trams, increased external air infiltration for ventilation correlates with elevated PNC and a shift in PNSD toward smaller diameters. Airports exhibit particularly elevated PNCs near runways, raising potential concerns about occupational exposure. Recommendations from this study include maintaining a substantial distance between road traffic and other commuting modes, integrating air filtration into ventilation systems, implementing low-emission zones, and advocating for a general reduction in road traffic to minimize daily UFP exposure. Our findings provide important insights for policy assessments and underscore the need for additional research to address current knowledge gaps.


Subject(s)
Air Pollutants , Air Pollution , Environmental Monitoring , Particle Size , Particulate Matter , Transportation , Vehicle Emissions , Particulate Matter/analysis , Environmental Monitoring/methods , Air Pollutants/analysis , Vehicle Emissions/analysis , Air Pollution/statistics & numerical data , Humans , Cities
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