Determination of risk of spontaneous waste ignition and leachate quality for open municipal solid waste dumpsite.

The waste receiving capacity of most municipal solid waste (MSW) landfill sites in India is exhausted, resulting in the formation of larger waste heaps. In the majority of Indian cities, these old waste heaps are prone to frequent smoldering and ignition resulting into fires. In this study, the potential risk of spontaneous ignition of landfilled waste at landfill surface was analyzed based on the physico-chemical characteristics of waste, carbon monoxide (CO) levels, landfill surface temperature (LST). The leachate pollution index was also determined to analyze the leachate quality for three different seasons (monsoon, pre-monsoon and post-monsoon). The regression analysis was carried out to understand the thermal properties (smoldering temperature, smoldering time, ignition temperature etc.) of MSW. The results showed that old waste has a higher tendency to undergo ignition compared to fresh waste. It has also been observed that the lower MC of old waste samples in the range of 3.4% and 18.2% is the most likely cause of early smoldering (106.6-109.5 °C) and ignition (198.6-208.4 °C) of old waste. In pre-monsoon season, CO concentrations for sub-surface (10-30 cm depth) smoldering events (SSE) were observed to be between âˆ¼ 150 to 200 ppm. This CO level substantially dropped to 10 ± 1 ppm in the post-monsoon season. The estimation of the leachate pollution index (LPI) showed an index score of 27.35, 30.47 and 10.71 for pre-monsoon, monsoon and post-monsoon seasons, respectively. The determination of CO levels, increased LST and physico-chemical properties of landfilled waste will greatly assist in the abatement of environmental pollution arising from landfill fires.

Preparation, characterization and agri applications of biochar produced by pyrolysis of sewage sludge at different temperatures.

Sewage sludge (SS) is an abundantly available feedstock, which is generally considered as potential threat to human health and environment. Its utilization in any process would be of great help for environmental sustainability. Accordingly, this work aimed to prepare and characterize the sewage sludge biochar (SSB) at temperatures, i.e. (500, 450, 400, and 350 °C), and further analyze the available nutrients and contaminants as well as agri application potential. The results indicated that the total nitrogen (TN), electrical conductivity (EC), and total organic carbon (TOC) content in SSBs decreased with increasing pyrolysis temperature. The overall concentration of polycyclic aromatic hydrocarbons (PAHs) in SSBs was substantially lower (1.8-9.7-fold depending on pyrolysis temperature) than in SS. Pyrolysis of SS enriched the heavy metals content in SSBs and the relative enrichment factor (RE) factor varied between 1.1 and 2.1 depending on the pyrolysis temperature. Furthermore, compared to SS, the leaching rate of heavy metals was significantly decreased in SSBs (1.1-100-fold depending on the pyrolysis temperature) and the pyrolysis temperature of 400-450 °C prevented the Ni, Pb, Cr, and Zn leaching in SSB. The total PAH and heavy metals content in biochars were below the control standard for land application. Finally, testing of the growth-promoting effect of biochar extracts on fenugreek plants revealed that SSB prepared at 350 °C significantly stimulated the root and shoot length of 5-days old seedlings. This study provides important data for potential environmental risks of SSB applications.

Industrial wastewater treatment: Current trends, bottlenecks, and best practices.

Rapid urbanization and industrialization have inextricably linked to water consumption and wastewater generation. Mining resources from industrial wastewater has proved to be an excellent source of secondary raw materials i.e., proficient for providing economic and financial benefits, clean and sustainable resilient environment, and achieving sustainable development goals (SDGs). Treatment of industrial wastewater for reusable resources has become a tedious task for decision-makers due to several bottlenecks and barriers, such as inefficient treatment options, high-cost expenditure, poor infrastructure, lack of financial support, and technical know-how. Most of the existing methods are conventional and fails to provide an economic benefit to the industries and have certain disadvantages. Also, the untreated industrial wastewater is discharged into the open drains, lakes, and rivers that lead to environmental pollution and severe health hazards. This paper has consolidated information about the current trends, opportunities, bottlenecks, and best practices associated with wastewater treatment and scope for the advancement in the existing technologies. Along with the efficient resource recovery, the wastewater could be ideally explored in the development of value-added materials, energy, and product recovery. The concepts, such as the circular economy (CE), partitions-release-recover (PRR), and transforming wastewater into bio factory are anticipated to be more convenient options to tackle the industrial wastewater menace.

Urban mining of obsolete computers by manual dismantling and waste printed circuit boards by chemical leaching and toxicity assessment of its waste residues.

Waste residues and acidic effluents (post-processing of E-waste) released into the local surroundings cause perilous environmental threats and potential risks to human health. Only limited research and information are available toward the sustainable management of waste residues generated post resource recovery of E-waste components. In the present study, the manual processing of obsolete computer (keyboard, monitor, CPU, and mouse) and chemical leaching of waste printed circuit boards (WPCBs) (motherboard, hard drive, DVD drive, and power supply) were performed for urban mining. The toxicity characteristics of typical pollutants in the residues of the WPCBs (post chemical leaching) were studied by toxicity characteristics leaching procedure (TCLP) test. Manual dismantling techniques resulted in an efficient urban mining concept with an overall average profit estimation of INR 2513.73/US$ 34.59. The chemical leaching of WPCBs showed a high concentration of metal leaching like Cu (229662 ± 575.3 mg/kg) and Pb (36785.67 ± 13.07 mg/kg) in the motherboard after stripping epoxy coating. The toxicity test revealed that the concentration of Cu (245.746 ± 0.016 mg/l) in the treated waste residue and Cu (430.746 ± 0.0015 mg/l) and Pb (182.09 ± 0.0035 mg/l) in the non-treated waste residue exceeded the threshold limit. The concentrations of other elements As, Cd, Co, Cr, Ag, Mn, Zn, Ni, Fe, Se, and In were within the permissible limit. Hence, the waste residue stands non-hazardous except Cu and Pb. Stripping out the epoxy coating of WPCBs enhances the metal leaching concentrations. The study highlighted that efficient and appropriate E-waste urban mining has immense potential in tracing the waste scrap into secondary resources. This study also emphasized that the final processed waste residue (left unattended or discarded due to lack of appropriate skill and technology) can be taken into consideration and exploited for value-added materials.

E-waste management and its effects on the environment and human health.

Challenges in managing electronic waste (E-waste) arise from a lack of technical skills, poor infrastructure, inadequate financial support, and inactive community engagement. This study provides a systematic review of efforts to overcome these challenges in the context of inappropriate recycling protocols of E-waste and their toxic effects on human health and the environment. An inventory of end-of-life electronic products, which can be established through the creation of an environment friendly regulatory regime for recycling, is essential for the proper control of E-waste. An approach has been articulated to help implement effective management of E-waste in both developed and developing countries. Enforcement of systematic management measures for E-waste in developing countries coupled with best practices is expected to minimize adverse impacts while helping maintain a sustainable and resilient environment.

Bioleaching: urban mining option to curb the menace of E-waste challenge.

Resource Recovery from Waste Electronics has emerged as one of the most imperative processes due to its pressing challenges all over the world. The Printed Circuit Board (PCB) is one of the typical E-waste components that comprise large varieties of metals and nonmetals. Urban Mining of these metals has received major attention all over the world. The existing treatment procedures used extensively for the resource extraction are hydrometallurgy and pyro-metallurgy and crude recycling practices in the informal sector. However, these methods are prone to cause secondary pollutants with certain drawbacks. Also, the existing informal recycling procedures resulted in insignificant occupational health hazards and severe environmental threats. The application of biotechnology is extensively exploited for metal extraction and emerged as one of the sustainable and eco-friendly tools. However, a limited field-scale study is prevailing in the realm of resource recovery from E-waste using bioleaching method. Hence, the application of bioleaching requires more attention and technical know-how in developing countries to curtail crude practices. The application of bioleaching in E-waste, including its available methods, kinetics mechanism associated opportunities, and barriers, have been discussed in this paper. A glance of E-waste management in India and the menace of 95% crude E-waste recycling are also elaborated. The incentives toward profit, socio-economic, and environmentally sustainable approaches have been delineated based on critical analysis of the available literature.

Environmental quality monitoring and impact assessment of solid waste dumpsites in high altitude sub-tropical regions.

Solid Waste Management (SWM) in high altitude regions is critically phased because of the non-availability of suitable facilities for the treatment and handling of large quantities of Municipal Solid Waste (MSW). Open burning practices at hill slopes were noticed which affect the surrounding environment. Hence, it became essential to measure the environmental components around the dumpsites to examine the impacts and suggest new technological solutions. The pollution parameters were monitored in and around the dumpsites, and the data was analysed using statistical tools. The assessment of air quality indicated maximum fine suspended particulate matter (PM2.5) concentration of 206.66 µg/m3 followed by respairable particulate matter (PM10), oxides of nitrogen (NOx) and sulphur dioxide (SO2). Among the gaseous emissions, methane (CH4) concentration was very high (38.53 mg/L) followed by carbon monoxide (CO) concentration (0.96 mg/L). Volatile organic compounds (VOCs) were also detected at few dumpsites with highest observed benzene (C6H6) concentration of 157.53 µg/m3. The soil sample analysis indicated that iron (Fe) concentration dominates followed by manganese (Mn), zinc (Zn), chromium (Cr), copper (Cu), and nickel (Ni). For evaluation of different alternatives for the SWM system, Rapid Impact Assessment Matrix (RIAM) was applied.

Malathion and dithane induce DNA damage in Vicia faba.

The increasing use of pesticides such as malathion and dithane in agriculture causes environmental mutagenicity. However, their genotoxicity in edible crops is seldom assessed. In this study, the genotoxic potential of malathion and dithane was evaluated in the roots of Vicia faba L. All three concentrations (0.05, 0.1, and 0.2%) of malathion and dithane tested resulted in a significant decrease in root length and inhibited seed germination. Cytological observations showed that the mitotic frequency in the root meristematic cells decreased parallel to the increase in concentrations, and the increase in chromosome aberrations and micronuclei frequency was concentration dependent. Alkaline comet assay revealed significant onset of DNA damage at all tested concentrations. For the randomly amplified polymorphic (RAPD)-polymerase chain reaction (PCR) analyses, 10 random RAPD primers were found to produce 116 unique polymorphic RAPD band fragments of 223-3139 bp. Each primer generated 3-15 RAPD bands on an average. The percentage of polymorphic DNA fragments was higher in malathion-exposed plants than dithane ones. The changes in RAPD profiles included disappearance and/or appearance of DNA bands in malathion and dithane treatment. Hence, DNA damage observed by the cytogenetic endpoints and comet assay corroborated with RAPD-PCR analysis. A total of 15 new protein bands of molecular weight ranging 11.894-226.669 kDa were observed in roots of Vicia plants that were exposed to the pesticides. The number of new protein bands was higher in malathion-treated DNA samples than in dithane-treated ones. Based on the results, we conclude that the pesticides can alter genomic template stability and change protein profiles. Malathion was more genotoxic than dithane. Therefore, RAPD assays can be useful in determining genotoxicity of pesticides in V. faba and other crops along with other quantitative parameters.

Challenges and opportunities associated with waste management in India.

India faces major environmental challenges associated with waste generation and inadequate waste collection, transport, treatment and disposal. Current systems in India cannot cope with the volumes of waste generated by an increasing urban population, and this impacts on the environment and public health. The challenges and barriers are significant, but so are the opportunities. This paper reports on an international seminar on 'Sustainable solid waste management for cities: opportunities in South Asian Association for Regional Cooperation (SAARC) countries' organized by the Council of Scientific and Industrial Research-National Environmental Engineering Research Institute and the Royal Society. A priority is to move from reliance on waste dumps that offer no environmental protection, to waste management systems that retain useful resources within the economy. Waste segregation at source and use of specialized waste processing facilities to separate recyclable materials has a key role. Disposal of residual waste after extraction of material resources needs engineered landfill sites and/or investment in waste-to-energy facilities. The potential for energy generation from landfill via methane extraction or thermal treatment is a major opportunity, but a key barrier is the shortage of qualified engineers and environmental professionals with the experience to deliver improved waste management systems in India.

Manganese induced changes in growth, chlorophyll content and antioxidants activity in seedlings of broad bean (Vicia faba L.).

The effect of manganese (Mn) on broad bean (Vicia faba L.) was studied with regard to growth, Mn accumulation in root and shoot, chlorophyll, proline content and peroxidase activity. Seeds were treated with Mn (10, 20, 40, 80,120,160 microM) and grown hydroponically up to 15 days. Manganese level in both root and shoot increased progressively in response to increasing concentration and it was high in roots (13 fold) overthe shoots (8 fold). The reductions in root (52%) and shoot (62.92%) development were evident for the maximum Mn concentration (160 microM). The chlorophyll amount gradually declined with increasing Mn concentrations and attained its maximum (42%) at 160 microM. By contrast, the guaiacol peroxidase activity was high (71%) along with the accompanying rise in proline content (75%) in shoots of the highest Mn concentration (160 microM). However, there was about 2 fold increase in total glutathione content at 40 microM than the basal level and further declined to 21.65 microg g(-1) fresh wt. at 160 microM Mn. The alterations in overall reflected Mn concentration-dependent changes in the parameters studied. The results suggest thatthe plant Vicia faba L. copes with Mn exposure through enhanced production of antioxidants.

Glutathione and cysteine biosynthesis in two varieties of Abelmoschus esculentus in response to mine spoil.

The extent of accumulation of some heavy metals and glutathione and cysteine levels in the roots and aerial plant parts in two genotypically different varieties of A. esculentus (KS404 and BO2) exposed to mine spoil were investigated. Glutathione (GSH) level in both the varieties on control sites increased from basal level to 155.15 nmol g(-1) dry weight (d.wt.), almost 1.5 fold on 30 day and attained a plateau within 60 day Mine spoil exposure of both the varieties decreased glutathione 1.13 fold (89.2 nmol g(-1) dry weight) during 60 day from its basal level. GSH concentration in shoots of these varieties increased accompanying growth contrary to roots where it finally declined 2 fold. Cysteine content in control plants increased 2 fold (31.6 nmol g(-1) dry weight) on 30 day and finally declined 1.38 fold (22.35 nmol g(-1) dry weight, at 60 day). Both the varieties, when exposed to mine spoil, showed enhanced cysteine content almost 2 fold during 30 day (50.95 nmol g(-1) dry weight) but failed to increase further Forshoots in both the varieties challenged with mine spoil, cysteine maxima reached late (15.2 nmol g(-1) dry weight, at 40 day) relative to control but the levels declined subsequently (11.85 nmol g(-l) dry weight). Contrary to GSH, cysteine content in roots of both the varieties responded positively to mine spoil as apparent from the 2.23 fold increase during 30 d than basal level although it lowered to a level of 12.85 nmol g(-1) dry weight finally at 60 day. Both the varieties accumulated almost maximum level of selected cations (Fe > Mn> Zn> Cu > Ni) during 30 day, but BO2 variety was significantly superior in this regard. Invariably high accumulation of such cations in roots over shoots indicated accumulation, retention or restricted translocation from root to shoot. The metal share of the edible part was just 6% of the plant load. Thus, present work reflects a genotypic differences in metal accumulation and that affected the major non-enzymatic traits or synthesis of sulthydryl compounds as well. The present results also indicate that metal tolerance is in part associated with anti-oxidant system activity.