1.
Catal Sci Technol
; 6(14): 5304-5310, 2016 Jul 21.
Artículo
en Inglés
| MEDLINE
| ID: mdl-28066540
RESUMEN
This manuscript describes the systematic development of pyridine-type ligands, which promote the Pd catalyzed, non-directed amination of benzene in combination with novel, hydroxylamine-based electrophilic amination reagents. DFT calculations and mechanistic experiments provide insights into the factors influencing the arene C-H amination protocol.