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1.
ACS Sustain Chem Eng ; 11(39): 14435-14444, 2023 Oct 02.
Artículo en Inglés | MEDLINE | ID: mdl-37799816

RESUMEN

Production of algal biomass and its conversion to biofuels are important technological platforms within the larger umbrella of CO2 capture and utilization. This analysis incorporates a life-cycle assessment (LCA) with respect to global warming potential and techno-economic assessment (TEA) of algae biofuels, focusing on the sourcing and delivery of CO2. This analysis evolves past work in this area to include high-purity biogenic CO2, industrial fossil fuel use, fossil power plants, and direct air capture, and uses a Sherwood plot approach to estimate the CO2 capture energy penalty. We also show that allocation or displacement facilitates a more intuitive distinction between biogenic and fossil sources of carbon. Thus, the LCA better reflects the influence of coproduct handling strategies as compared to previous works. The TEA is also strongly influenced by the CO2 concentration in the flue gas. Currently, when CO2 is sourced from large-point sources, the price of biofuels ($4.5-6.5/GGE) may become comparable to fossil diesel. However, as DAC systems become more economical, they may deliver competitive CO2 sources for biofuels in 2050 with a total cost of <$7/GGE. Based on the net emissions and costs, algae biofuels with CO2 sourced from biogenic sources are consistent with a decarbonized economy as of now, with substantial potential for DAC with decreasing costs.

2.
Water Res ; 240: 120078, 2023 Jul 15.
Artículo en Inglés | MEDLINE | ID: mdl-37244015

RESUMEN

A consequential life cycle assessment (LCA) was utilized to compare the environmental impacts of food waste and sewage sludge management strategies. The strategies included a novel two-phase anaerobic digestion (AD) system and alternatives including landfill, waste-to-energy, composting, anaerobic membrane bioreactor, and conventional AD (wet continuous stirred-tank reactor [CSTR]). The co-management of food waste with sewage sludge was also considered for the two-phase AD system and for a conventional AD reactor. A multidimensional LCA approach was taken, considering the five-midpoint impact categories of global warming, smog, human health particulate, acidification, and eutrophication estimated using the U.S. EPA Tool for the Reduction and Assessment of Chemical and Other Environmental Impacts. Co-management of food waste and sewage sludge using the novel two-phase AD system was shown to maximize energy recovery and had a net global warming benefit while reducing other environmental impacts compared with the alternative management strategies. It had similar relative environmental advantages across all categories as conventional AD, with the advantage of a smaller physical footprint. However, both approaches featured net environmental burdens when the background electric grid intensity fell below 0.25 kg CO2-eq kWh-1, as could be expected in a decarbonized electric future. Upgrading the biogas produced from AD to renewable natural gas can displace the use of fossil natural gas for other non-electricity energy requirements that are difficult to decarbonize and may extend the time period of significant environmental benefits of utilizing AD for organic waste management. Treatment of the nutrient-rich supernatant generated by the novel two-phase AD system could be an obstacle for utilities with stringent nutrient discharge limits. Future research and full-scale implementation are needed to demonstrate the benefits of the two-phase AD system predicted through this analysis.


Asunto(s)
Eliminación de Residuos , Administración de Residuos , Humanos , Animales , Aguas del Alcantarillado , Eliminación de Residuos/métodos , Alimentos , Gas Natural , Administración de Residuos/métodos , Estadios del Ciclo de Vida , Anaerobiosis
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