RESUMEN
Optical hole burning has been observed in the 5941-A transition of Pr(3+) in a charge-compensated tetragonal site of CaF(2) . The Pr(3+) ground state is doubly degenerate and shows a large first-order hyperfine splitting, which is clearly resolved because of the very narrow inhomogeneous linewidth of 650 MHz. The hole burning involves a new mechanism, in which optically induced spin flips of neighboring nuclei (here (19)F) shift the optical transition frequency outside its homogeneous linewidth. This mechanism was confirmed by optical rf double resonance.
RESUMEN
A simple technique for single-scan T(1) measurements in solids is proposed and analyzed for single exponential spin-lattice relaxation. In this technique, the direct spin heating caused by the sampling process is significantly reduced in comparison with conventional techniques by utilizing the ''solid echo'' to refocus the magnetization. The applicability of this technique to both the solid and liquid phases is demonstrated.