Phosphinecarboxamide based InZnP QDs - an air tolerant route to luminescent III-V semiconductors.

We describe a new synthetic methodology for the preparation of high quality, emission tuneable InP-based quantum dots (QDs) using a solid, air- and moisture-tolerant primary phosphine as a group-V precursor. This presents a significantly simpler synthetic pathway compared to the state-of-the-art precursors currently employed in phosphide quantum dot synthesis which are volatile, dangerous and air-sensitive, e.g. P(Si(CH3)3)3.

Carrier density tuning in CuS nanoparticles and thin films by Zn doping via ion exchange.

Copper sulphide (covellite) nanoplatelets have recently emerged as a plasmonic platform in the near-infrared with ultrafast nonlinear optical properties. Here we demonstrate that the free-carrier density in CuS, which is an order of magnitude lower than in traditional plasmonic metals, can be further tuned by chemical doping. Using ion exchange to replace Cu with an increasing content of Zn in the nanoparticles, the free-hole density can be lowered, resulting in a long-wavelength shift of the localised plasmon resonances from 1250 nm to 1750 nm. The proposed approach provides new opportunities for tuning the plasmonic response of covellite nanocrystals as well as the carrier relaxation time which decreases for lower free-carrier densities.

Theranostic Near-Infrared-Active Conjugated Polymer Nanoparticles.

Conjugated polymer nanoparticles (CPNs) based on a common solar cell material (PTB7) have been prepared, and their potential in theranostic applications based on bioimaging and photosensitizing capabilities has been evaluated. The main absorption and emission bands of the prepared CPNs both fell within the NIR-I (650-950 nm) transparency window, allowing facile and efficient implementation of our CPNs as bioimaging agents, as demonstrated in this work for A549 human lung cancer cell cultures. The prepared CPN samples were also shown to produce reactive oxygen species (ROS) upon photoexcitation in the near-infrared or ultraviolet spectral regions, both in aqueous solutions and in HaCaT keratinocyte cell cultures. Importantly, we show that the photosensitizing ability of our CPNs was largely determined by the nature of the stabilizing shell: coating the CPNs with a Pluronic F-127 copolymer led to an improvement of photoinitiated ROS production, while using poly[styrene-co-maleic anhydride] instead completely quenched said process. This work therefore demonstrates that the photosensitizing capability of CPNs can be modulated via an appropriate selection of stabilizing material and highlights the significance of this parameter for the on-demand design of theranostic probes based on CPNs.