RESUMEN
We report a ^{51}V nuclear magnetic resonance investigation of the frustrated spin-1/2 chain compound LiCuVO_{4}, performed in pulsed magnetic fields and focused on high-field phases up to 56 T. For the crystal orientations Hâ¥c and Hâ¥b, we find a narrow field region just below the magnetic saturation where the local magnetization remains uniform and homogeneous, while its value is field dependent. This behavior is the first microscopic signature of the spin-nematic state, breaking spin-rotation symmetry without generating any transverse dipolar order, and is consistent with theoretical predictions for the LiCuVO_{4} compound.
RESUMEN
Hydroxyapatite films enriched with magnetite have been fabricated via a Pulsed Plasma Deposition (PPD) system with the final aim of representing a new platform able to disincentivate bacterial adhesion and biofilm formation. The chemical composition and magnetic properties of films were respectively examined by X-ray photoelectron spectroscopy (XPS) and Superconducting Quantum Interference Device (SQUID) measurements. The morphology and conductive properties of the magnetic films were investigated via a combination of scanning probe technologies including atomic force microscopy (AFM), electrostatic force microscopy (EFM), and scanning tunneling microscopy (STM). Interestingly, the range of adopted techniques allowed determining the preservation of the chemical composition and magnetic properties of the deposition target material while STM analysis provided new insights on the presence of surface inhomogeneities, revealing the presence of magnetite-rich islands over length scales compatible with the applications. Finally, preliminary results of bacterial adhesion tests, indicated a higher ability of magnetic hydroxyapatite films to reduce Escherichia coli adhesion at 4h from seeding compared to control hydroxyapatite films.
Asunto(s)
Adhesión Bacteriana , Materiales Biocompatibles Revestidos/química , Durapatita/química , Escherichia coli/crecimiento & desarrollo , Membranas Artificiales , Magnetismo , Microscopía de Fuerza Atómica , Espectroscopía de Fotoelectrones , Propiedades de SuperficieRESUMEN
Superconducting Pr(2)CuO(x), x ≃ 4 films with T' structure and a T(c) of 27 K have been investigated by millimeter-wave transmission and broadband (infrared-to-ultraviolet) reflectivity measurements in the normal and superconducting state. The results obtained by both experimental methods show a consistent picture of the superconducting condensate formation below T(c). An Eliashberg analysis of the data proves d-wave superconductivity and unitary-limit impurity scattering of the charge carriers below T(c). The derived electron-exchange boson interaction spectral function I(2)χ(ω) shows only marginal changes at the superconducting transition with the mass enhancement factor λ, the first inverse moment of I(2)χ(ω), being equal to 4.16 at 30 K and to 4.25 at 4 K.