RESUMEN
The potential health effects of fine and ultrafine particles are of increasing concern. A better understanding of particle characteristics and dispersion behavior is needed. This study aims at characterizing spatial and temporal variations in fine and ultrafine particle dispersion after emission from a model source in an experimental house. Particles emitted by an incense stick burning for 15 min were characterized. Number concentration, specific surface area and mass were measured. Partial chemical analysis of particles was also realized. Near the burning incense stick, the maximum concentration was 25,500 particles/cm(3); the indoor PM(2.5) concentration reached 197 microg/m(3), and the specific surface area concentration was 180 microm(2)/cm(3). The estimated incense smoke density was 1.1 g/cm(3). Time of Flight Aerosol Mass Spectrometer measurements indicated that the organic fraction was predominant in the aerosol mass detected, and other minor components identified were K(+), NO(3)(-), and Cl(-). The combustion of an incense stick in the living room was associated with significant modifications of the concentrations of particles measured in the different rooms of the house. This demonstration of pollution by particle dispersion by a model source of moderate intensity may have significant implications in terms of assessment of indoor exposure to such particles. Practical Implications The particles emitted in a domestic environment by a source of moderate intensity such as burning incense disperse throughout the house, even in rooms with closed doors and in rooms as far away as the next floor. This dispersion has significant implications in terms of evaluating human indoor exposure to fine and ultrafine particles.
Asunto(s)
Contaminación del Aire Interior/análisis , Vivienda , Material Particulado/análisis , Humo/análisis , Conducta Ceremonial , Humanos , Tamaño de la PartículaRESUMEN
Heterogeneous reactions between organic films, taken as proxies for atmospheric aerosols, with ozone in presence of simulated sunlight and the photosensitizer 4-carboxybenzophenone (4-CB) were observed to alter surface properties as monitored by contact angle during the reaction. Attenuated total reflectance Fourier transform infrared spectroscopy (FTIR-ATR) was used in addition for product identification. Two types of model surfaces were systematically studied: 4-CB/4-phenoxyphenol and 4-CB/catechol. Solid organic films made of 4-CB/catechol were observed to become hydrophilic by simultaneous exposure to ozone and simulated sunlight, whereas organic films made of 4-CB/4-phenoxyphenol become hydrophobic under the same conditions. These changes in contact angle indicate that photo-induced aging processes involving ozone (such as oligomerisation) not necessarily favour increased hygroscopicity of organic aerosols in the atmosphere. The ratio between hydrophobic and hydrophilic functional groups should reflect the chemical property of organic films with respect to wettability phenomena. Contact angles and surface tensions of the exposed organic film made of 4-CB/4-phenoxyphenol were found to correspond to the hydrophobic/hydrophilic ratios obtained from the FTIR-ATR spectra.
Asunto(s)
Aerosoles/química , Benzofenonas/química , Benzofenonas/efectos de la radiación , Membranas Artificiales , Ozono/química , Ozono/efectos de la radiación , Fármacos Fotosensibilizantes/química , Fármacos Fotosensibilizantes/efectos de la radiación , Luz Solar , Aerosoles/efectos de la radiación , Catecoles/química , Catecoles/efectos de la radiación , Éteres Fenílicos/química , Éteres Fenílicos/efectos de la radiación , Espectroscopía Infrarroja por Transformada de Fourier/métodos , Propiedades de Superficie , Factores de Tiempo , HumectabilidadRESUMEN
1. There is always some degree of stress in the OR. The trick is to play up the eustress (positive, motivating energy) and alleviate the distress (negative/draining energy). Eustress is characterized by smiles, chatter, purposeful movement, and an OR that hums with efficiency. Distress can be assessed by unhappy faces, loud grumbling, dragging feet, and an OR that grinds to a halt. 2. Humor relaxes people and situations. It allows creative juices to flow and enhances what people take away from meetings by facilitating the creative process. The staff members feel good about themselves and what they are doing, and they become more productive. 3. The OR can be both a wonderful (eustress) and a horrible (distress) place in which to work. We need to savor the wonderful--and season the horrible with humor to make it palatable. As directors use humor to reduce staff stress levels, they should remember to bring laughter and humor into their own lives as well.