Investigation of the mechanical performance of young glass-ionomer cement using dynamic mechanical analysis.

Glass-ionomer (or more correctly, glass polyalkenoate) cements have wide applications in dentistry. This paper reports an investigation using dynamic mechanical analysis (DMA) on the setting of typical conventional glass-ionomer cements of varying age. Rectangular section cement samples were stored for four weeks in distilled water at 37 degrees C before being tested. The experimental procedure involved the clamping of the sample in tensile mode and heating through a 37-95 degrees C temperature range in water. A general behavioral trend was followed where all the samples showed increased flexibility with rise in temperature until a "threshold" temperature was reached, whereupon sudden tensile stiffening was observed. The temperature at which the stiffening took place was dependent on the age of the cement, and was interpreted in terms of the secondary cement forming reactions of silica and phosphate. The younger samples stiffened at significantly lower temperatures than the older ones. The activated nature of glass-ionomer setting chemistry meant that younger cements could be prematurely aged through heating. Differential scanning calorimetry was used to study the effect of heating on the distribution of loosely bound water in the cements that had, and had not been exposed to a DMA cycle. Most notably, it was seen that the DMA process did not affect the water in the matrix. This leant further credence to the hypothesis that the stiffening observed during the DMA heating process was caused by accelerated network formation.

Stress relaxation modelling of polymethylmethacrylate bone cement.

This paper describes tests that were carried out to model the stress relaxation behaviour of polymethylmethacrylate (PMMA) bone cement. Stress relaxation of bone cement is believed to be a significant factor in the mechanism of load transfer in the femoral stem of a polished, collarless taper-fit replacement hip joints. It is therefore important that this condition and its implications are understood. Stress relaxation was carried out on PMMA samples of varying age in four-point bending configuration. It was shown that the samples stiffened with age and that the amount of stress relaxation reduced as the samples aged. The experimental results of the stress relaxation were accurately modelled on the double exponential of the Maxwell model so that long-term predictions of the stress condition could be made from short-term mechanical tests.