RESUMEN
Herein, we synthesized a CdSe quantum dots (QDs)-decorated ternary metal oxide nanocomposite of ZnO/TiO2/CuO through a simple hydrothermal method. The prepared nanocomposite exhibited monoclinic, hexagonal, and cubic phase structures in XRD (X-ray diffraction) analysis. UV-vis absorbance spectra showed the broad absorption spectrum. SEM (scanning electron microscopy) clearly showed the presence of nanoparticles and confirmed the elements through elemental mapping. TEM (transmission electron microscopy) confirmed the nanostructure of metal oxides decorated with QDs. The average particle size was 45 nm for metal oxides and 7 nm for QDs. XPS (X-ray photoelectron spectroscopy) also confirmed the surface elemental composition. The prepared nanocomposites were introduced as photoanodes in DSSCs (dye-sensitized solar cells) and as photocatalysts for industrial dye solution. Among these samples, CdSe@CuO/TiO2/ZnO showed an improved performance of PCE (photon conversion efficiency) of 3.68% in DSSC and 96% photocatalytic degradation efficiency. It showed a recycling efficiency of â¼92% after 4 cycles against methylene blue (MB) organic dye under visible light irradiation.
RESUMEN
Highly durable and antimicrobial tantalum nitride/copper (TaN/Cu) nanocomposite coatings were deposited on D-9 stainless steel substrates by pulsed magnetron sputtering. The Cu content in the coating was varied in the range of 1.42-35.42 atomic % (at.%). The coatings were characterized by electron probe microanalyzer, X-ray diffraction, scanning electron microscope and atomic force microscope. The antibacterial properties of the TaN/Cu coatings against gram-negative Pseudomonas aeruginosa were evaluated using a cell culture test. The peak hardness and Young's modulus of TaN/Cu with 10.46 at.% Cu were 24 and 295 GPa, respectively, which amounted to 15 and 41.67% higher than Cu-free TaN. Among all, TaN/Cu with 10.46 at.% exhibited the lowest friction coefficient. The TaN/Cu coatings exhibited significantly higher antibacterial activity than Cu-free TaN against Pseudomonas aeruginosa. On TaN, the bacterial count was about 4 × 106 CFU, whereas it was dropped to 1.2 × 102 CFU in case of TaN/Cu with 10.46 at.% Cu. The bacterial count was decreased from 9 to 6 when the Cu content increased from 25.54 to 30.04 at.%. Live bacterial cells were observed in the SEM images of TaN, and dead cells were found on TaN/Cu. Overall, TaN/Cu with 10.46 at.% Cu was found to be a potential coating composition in terms of higher antimicrobial activity and mechanical durability.
