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Talanta ; 107: 292-6, 2013 Mar 30.
Artículo en Inglés | MEDLINE | ID: mdl-23598225

RESUMEN

Sample-decomposition methods using microwave radiation in closed systems have been commonly used in the analysis of inorganic constituents; however, these methods are limited to small amounts of organic samples. This work proposes the combined use of infrared radiation and microwave radiation (IR-MW) to increase the amount of organic samples digested. The determination of Al, Ca, Cu, Fe, K, Mg, Mn, Na, P and Zn in human-feed samples was accomplished by ICP OES. The results were in agreement with those obtained from conventional decomposition by microwave radiation (closed system). The results obtained using the proposed IR-MW system for standard reference material (whole milk powder, NIST 8435) were also compared. Agreements of 85-100% were obtained for Al, Ca, Cu, Fe, K, Mg, Na, P and Zn in the standard reference material. The IR-MW system is simple to implement and cheap because it uses commercially available infrared lamps and allows the use of infrared radiation in the microwave-digestion vessel. Additionally, it is possible to reach better precision in the analysis of the human-feed samples using the IR-MW system. The proposed method also allows total digestion of large sample amounts or samples rich in organic compounds can also be performed in the IR-MW system using small volumes of nitric acid.


Asunto(s)
Análisis de los Alimentos/métodos , Leche/química , Espectrofotometría Atómica/métodos , Oligoelementos/análisis , Animales , Diseño de Equipo , Análisis de los Alimentos/instrumentación , Humanos , Rayos Infrarrojos , Microondas , Sensibilidad y Especificidad
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