RESUMEN
The title compound, [PdCl2(C18H24N2)]·(CH3)2SO·H2O, the Pd(II) ion is in a distorted square-planar geometry. The Pd-N bond distances are 2.022â (2) and 2.027â (2)â Å, the Pd-Cl bond distances are 2.2880â (7) and 2.2833â (7)â Å, and the ligand bite angle is 80.07â (9)°. The dimethyl sulfoxide and water mol-ecules form linear chains along [100] by O-Hâ¯O and O-Hâ¯S hydrogen bonds, generating eight- and 12-membered rings. C-Hâ¯Cl inter-actions link the chains, forming a three-dimensional arrangement. In addition, the 4,4-di-tert-butyl-2,2'-bi-pyridine ligand exhibits π-π stacking inter-actions [centroid-centroid distances = 3.8741â (15) and 3.8353â (15)â Å]. The DMSO solvent is disordered and was refined with an occupancy ratio of 0.866â (3):0.134â (3).