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1.
Sensors (Basel) ; 24(12)2024 Jun 18.
Artículo en Inglés | MEDLINE | ID: mdl-38931732

RESUMEN

The recent advancements of mobile edge computing (MEC) technologies and unmanned aerial vehicles (UAVs) have provided resilient and flexible computation services for ground users beyond the coverage of terrestrial service. In this paper, we focus on a UAV-assisted MEC system in which the UAV equipped with MEC servers is used to assist user devices in computing their tasks. To minimize the weighted average energy consumption and delay in the UAV-assisted MEC system, a LQR-Lagrange-based DDPG (LLDDPG) algorithm, which jointly optimizes the user task offloading and the UAV trajectory design, is proposed. To be specific, the LLDDPG algorithm consists of three subproblems. The DDPG algorithm is used to address the issue of UAV desired trajectory planning, and subsequently, the LQR-based algorithm is employed to achieve the real-time tracking control of UAV desired trajectory. Finally, the Lagrange duality method is proposed to solve the optimization problem of computational resource allocation. Simulation results indicate that the proposed LLDDPG algorithm can effectively improve the system resource management and realize the real-time UAV trajectory design.

2.
Int J Biol Macromol ; 263(Pt 2): 130065, 2024 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-38423912

RESUMEN

The development of high value-added lignin-based functional porous carbon electrodes with excellent properties from sustainable industry lignin powder remains a challenge. This work aims to create robust, binder-free, conductive additives-free, and current collector-free monolithic porous carbon electrodes using industrial lignin powder for membrane-free capacitive deionization (CDI). The material exhibits high mechanical strength, hierarchical porosity structure, large uniform size, and thickness of just a few millimetres (<2.6 mm). In a three-electrode supercapacitor system, the areal specific capacitance of CLCA300-3-1.0 reaches 5.03-1.02 F cm-2 when the scan rate between 1 and 20 mV s-1 in 1 M NaCl solution. As CDI electrodes, the charge efficiency of CLCA300-3-1.0 at different voltages of 1.2 V, 1.4 V and 1.6 V is 0.53, 0.72 and 0.71, respectively. The energy consumption of CLCA280-3-1.0, CLCA300-3-1.0 and CLCA320-3-1.0 tested at 1.2 V are 3.27, 3.40 and 3.25 Wh m-3, respectively. In addition, with thickness increasing to 1.5 mm, the developed CLCA300-3-1.5 electrode exhibits an areal adsorption capacity of 0.46 mg cm-2, and relative highly capacity retention of 84.78 % after 70 cycles. The impressive desalination performance is attributed to the well-designed hierarchical porosity, superhydrophilicity and robust monolithic structure.


Asunto(s)
Carbono , Purificación del Agua , Carbono/química , Lignina , Porosidad , Adsorción , Polvos , Electrodos
3.
ACS Appl Mater Interfaces ; 16(1): 915-923, 2024 Jan 10.
Artículo en Inglés | MEDLINE | ID: mdl-38145458

RESUMEN

The interface VOC loss between the active layer and the hole transport layer (HTL) of lead sulfide colloidal quantum dot (PbS-CQD) solar cells is a significant factor influencing the efficiency improvement of PbS colloidal quantum dot solar cells (PbS-CQDSCs). Currently, the most advanced solar cells adopt organic P-type HTLs (PbS-EDT) via solid-state ligand exchange with 1,2-ethanedithiol (EDT) on the CQD top active layer. However, EDT is unable to altogether remove the initial ligand oleic acid from the quantum dot surface, and its high reactivity leads to cracks in the HTL film caused by volume contractions, which inevitably results in significant VOC loss. These flaws prompted this research to develop a method involving hybrid organic ligand exchange using 3-mercaptopropionic acid (MPA) and 1,2-EDT (PbS-Hybrid) to overcome these drawbacks of VOC loss. The results indicated that the new exchange strategy improved the quality of the HTL film and benefited from the enhanced passivation of the quantum dot surface and better alignment of energy levels, and the average VOC of PbS-Hybrid devices is increased by approximately 25 mV compared to control devices. With the enhanced VOC, the average power conversion efficiency (PCE) of the devices is improved by 10%, with the highest PCE reaching 13.24%.

4.
Mol Breed ; 43(6): 48, 2023 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-37313222

RESUMEN

Leaf color-related genes play key roles in chloroplast development and photosynthetic pigment biosynthesis and affect photosynthetic efficiency and grain yield in crops. In this study, a recessive homozygous individual displaying yellow leaf color (yl1) was identified in the progeny population derived from a cross between wheat cultivars Xingmai1 (XM1) and Yunong3114 (YN3114). Phenotypic identification showed that yl1 exhibited the yellow character state over the entire growth period. Compared with XM1, yl1 plants had significantly lower chlorophyll content and net photosynthetic rate, and similar results were found between the green-type lines and yellow-type lines in the BC2F3 XM1 × yl1 population. Gene mapping via the bulked segregant exome capture sequencing (BSE-seq) method showed that the target gene TaYL1 was located within the region of 582,556,971-600,837,326 bp on chromosome 7D. Further analysis by RNA-seq suggested TraesCS7D02G469200 as a candidate gene for yellow leaf color in common wheat, which encodes a protein containing the AP2 domain. Moreover, comparative transcriptome profiling revealed that most differentially expressed genes (DEGs) were enriched in chlorophyll metabolism and photosynthesis pathways. Together, these results indicate that TaYL1 potentially affects chlorophyll synthesis and photosynthesis. This study further elucidates the biological mechanism of chlorophyll synthesis, metabolism, and photosynthesis in wheat and provides a theoretical basis for high photosynthetic efficiency in wheat breeding. Supplementary Information: The online version contains supplementary material available at 10.1007/s11032-023-01395-z.

5.
Opt Express ; 31(2): 3092-3113, 2023 Jan 16.
Artículo en Inglés | MEDLINE | ID: mdl-36785308

RESUMEN

3D imaging and metrology of complex micro-structures is a critical task for precision manufacturing and inspection. In this paper, an accurate and flexible calibration method for 3D microscopic structured light system with telecentric imaging and Scheimpflug projector is proposed. Firstly, a fringe projection 3D microscopy (FP-3DM) system consisting of a telecentric camera and a Scheimpflug projector is developed, which can take full advantage of the depth of field (DOF) and increase the measurement depth range. Secondly, an accurate and flexible joint calibration method is proposed to calibrate the developed system, which utilizes the established pinhole imaging model and Scheimpflug distortion model to calibrate telecentric imaging, and fully considers the correction and error optimization of the Scheimpflug projection model. Meanwhile, the optimized local homography is calculated to obtain more accurate sub-pixel correspondence between the camera and the projector, and the perspective-n-point (PnP) method make the 3D coordinate estimation of the feature point more accurate. Finally, a prototype and a dedicated calibration program are developed to realize high-resolution and high-precision 3D imaging. The experimental results demonstrate that the re-projection error is less than 1µm, and the 3D repeated measurement error based on feature fitting is less than 4µm, within the calibrated volume of 10(H)mm × 50(W)mm × 40(D)mm.

6.
Int J Biol Macromol ; 225: 1415-1425, 2023 Jan 15.
Artículo en Inglés | MEDLINE | ID: mdl-36435463

RESUMEN

Lignin is a renewable biomacromolecule that can be used as precursors for carbon materials. In this work, highly flexible lignin-based carbon nanofibers with abundant ultra-micropores are constructed via electrospinning, oxidative stabilization and carbonization. The results indicate that replacing PAN with 80 % lignin is feasible in regulating ultra-micropores. The synthesized L4P1-CNFs possess many attractive properties (e.g., pore size distribution, electrochemical and deionization property) compared with that produced from other non-renewable precursors or more-complexed processes. It shows excellent electrochemical double-layer capacitance in 6 M KOH (233 to 162 F g-1 at 0.5 to 5 A g-1) and 1 M NaCl (158 to 82 F g-1 at 0.5 to 5 A g-1) electrolytes. Upon assembling into CDI cells, the average salt adsorption rate could reach 1.79 mg g-1 min-1 at 1.2 V and 3.32 mg g-1 min-1 at 2 V in 500 mg L-1. Benefiting from the excellent flexibility, we innovatively stack four layers of L4P1-CNFs to improve the areal electrosorption capacity to 0.0817 mg cm-2 at 500 mg L-1, significantly higher than that of traditional carbon-based electrodes. The good desalination property makes lignin-based carbon nanofibers ideal for practical, low-cost capacitive deionization applications.


Asunto(s)
Carbono , Nanofibras , Carbono/química , Lignina , Nanofibras/química , Cloruro de Sodio/química , Electrodos
7.
Int J Biol Macromol ; 209(Pt A): 692-702, 2022 Jun 01.
Artículo en Inglés | MEDLINE | ID: mdl-35429516

RESUMEN

To achieve lignin valorization, we reported a simple method to direct covert lignin into carbon foam materials in this work. Unlike multiple steps required to fabricate traditional carbon foams from most of other precursors (often non-renewable), the approach herein required solely heating for carbon production. We found that the intrinsic features of lignin render the formation of lignin block meanwhile generate the porous structure under the invented heating course. Three key factors including glass transition temperature, crosslinking ability, and thermal stability of lignin were identified to determine the successful fabrication of lignin foam (i.e., precursor of carbon foam). Upon tuning the heating profile or fractionating the lignin, lignin foam with different morphologies and properties were obtained. After carbonization, the selected lignin-derived carbon foams possessed well porous structures with bulk densities of 0.52 or 0.62 g cm-3, superior integrity with strength properties of around 10 MPa, BET surface areas of 143.29 or 325.86 m2 g-1, and many other attractive properties. This work is expected to stimulate further seek of lignin valorization in carbon foam production.


Asunto(s)
Carbono , Lignina , Aerosoles , Carbono/química , Lignina/química , Porosidad
8.
Appl Opt ; 61(32): 9625-9633, 2022 Nov 10.
Artículo en Inglés | MEDLINE | ID: mdl-36606903

RESUMEN

The measurement accuracy of telecentric imaging technique straightforwardly depends on the calibration of the telecentric camera. We present a flexible and simple calibration method based on a telecentric imaging model and orthogonality of rotation matrix. First, we use the orthogonality of rotation matrix to solve the magnification. Second, the external parameters are solved by the imaging model, and the ambiguity of sign is solved. Finally, we use the LM nonlinear optimization method to solve the distortion parameters. Experimental results show that the reprojection error is 0.7 pixels, which represents the actual dimension of 6.37 µm. In addition, the standard measuring block and real objects are measured, and the results verify the measurement accuracy and robustness of the proposed method.

9.
Int J Biol Macromol ; 193(Pt A): 519-527, 2021 Dec 15.
Artículo en Inglés | MEDLINE | ID: mdl-34695494

RESUMEN

In this work, lignin-based carbon nanofibers (LCNFs) were for the first time served as substrate for in-situ electrodeposition of polyaniline (PANI) and tested as pseudocapacitor. Two LCNFs with different lignin ratios were designed to distinguish their morphology and structural properties. Next, PANI deposition mechanisms on both LCNFs were investigated and the electrochemical performance of the resulting LCNF/PANIs were evaluated. It was found although LCNF2 was composed of less uniform nanofibers due to more presence of lignin in precursor dope, it had higher tensile strength/modulus than LCNF1 (strength: 34.3MPa to 24.2 MPa; Modulus: 2.40 GPa to 1.45GPa) and was more cost-effective. Particularly, the beaded fibers on LCNF2 contributes to the deposition of PANI with higher specific mass capacitance (612.8 F g-1 to 547.0 F g-1). Upon assembling into solid-state supercapacitors, the Cm of LCNF2/PANI device was determined to be 229 F g-1 and the maximum energy density was 11.13Wh kg-1 at a power density of 0.08 kW kg-1. This work showed LCNF produced from renewable and low-cost lignin could be directly used as substrate for PANI deposition. Moreover, the composition in spinning dope played an important role in determining the performances of resulting pseudocapacitors.


Asunto(s)
Carbono/química , Electrodos , Lignina/química , Nanofibras/química , Capacidad Eléctrica , Resistencia a la Tracción
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