Recent advances in metal-based nanoporous materials for sensing environmentally-related biomolecules.

Highly sensitive, stable, selective, efficient, and short reaction time sensors play a substantial role in daily life/industry and are the need of the day. Due to the rising environmental issues, nanoporous carbon and metal-based materials have attracted significant attention in environmental analysis owing to their intriguing and multifunctional properties and cost-effective and rapid detection of different analytes by sensing applications. Environmental-related issues such as pollution have been a significant threat to the world. Therefore, it is necessary to fabricate highly promising performance-based sensor materials with excellent reliability, selectivity and good sensitivity for monitoring various analytes. In this regard, different methods have been employed to fabricate these sensors comprising metal, metal oxides, metal oxide carbon composites and MOFs leading to the formation of nanoporous metal and carbon composites. These composites have exceptional properties such as large surface area, distinctive porosity, and high conductivity, making them promising candidates for several versatile sensing applications. This review covers recent advances and significant studies in the sensing field of various nanoporous metal and carbon composites. Key challenges and future opportunities in this exciting field are also part of this review.

Nanocatalytic Assemblies for Catalytic Reduction of Nitrophenols: A Critical Review.

Nitrophenol is common carcinogenic pollutant known for its adverse effects on human beings and aquatic life. During the last few decades, the chemical reduction of nitrophenol compounds has been widely reported as the advanced removal methodology for such hazardous dyes from aqueous reservoirs. Many researchers have utilized different nanocatalytic systems using sodium borohydride (NaBH4) as the reducing agent for acquiring industrially useful reduction product of aminophenol by carrying out the chemical reduction of nitrophenols. Polymeric material supported monometallic nanoparticles are widely reported catalyst for the degradation of 2-nitrophenol (2-NP) and 4-nitrophenol (4-NP). This review critically discusses the pros and cons of numerous supporting mediums of nanocatalytic assemblies used for the immobilization of nanomaterials. Mechanism and kinetic analysis of the reduction reaction of 2-NP and 4-NP have also been explained in this study. In addition, recent literature has also been effectively summarized in the tabular form for developing a better understanding of the reader. Pictorial representation of key nanocatalytic assemblies and catalytic reduction mechanism has also been narrated in this study.