RESUMEN
The selective conversion of syngas to higher alcohols is an attractive albeit elusive route in the quest for effective production of chemicals from alternative carbon resources. We report the tandem integration of solid cobalt Fischer-Tropsch and molecular hydroformylation catalysts in a one-pot slurry-phase process. Unprecedented selectivities (>50â wt %) to C2+ alcohols are achieved at CO conversion levels >70 %, alongside negligible CO2 side-production. The efficient overall transformation is enabled by catalyst engineering, bridging gaps in operation temperature and intrinsic selectivity which have classically precluded integration of these reactions in a single conversion step. Swift capture of 1-olefin Fischer-Tropsch primary products by the molecular hydroformylation catalyst, presumably within the pores of the solid catalyst is key for high alcohol selectivity. The results underscore that controlled cooperation between solid aggregate and soluble molecular metal catalysts, which pertain to traditionally dichotomic realms of heterogeneous and homogeneous catalysis, is a promising blueprint toward selective conversion processes.
RESUMEN
Adjusting hydrocarbon product distributions in the Fischer-Tropsch (FT) synthesis is of notable significance in the context of so-called X-to-liquids (XTL) technologies. While cobalt catalysts are selective to long-chain paraffin precursors for synthetic jet- and diesel-fuels, lighter (C10-) alkane condensates are less valuable for fuel production. Alternatively, iron carbide-based catalysts are suitable for the coproduction of paraffinic waxes alongside liquid (and gaseous) olefin chemicals; however, their activity for the water-gas-shift reaction (WGSR) is notoriously detrimental when hydrogen-rich syngas feeds, for example, derived from (unconventional) natural gas, are to be converted. Herein the roles of pore architecture and oxide promoters of Lewis basic character on CoRu/Al2O3 FT catalysts are systematically addressed, targeting the development of catalysts with unusually high selectivity to liquid olefins. Both alkali and lanthanide oxides lead to a decrease in turnover frequency. The latter, particularly PrO x , prove effective to boost the selectivity to liquid (C5-10) olefins without undesired WGSR activity. In situ CO-FTIR spectroscopy suggests a dual promotion via both electronic modification of surface Co sites and the inhibition of Lewis acidity on the support, which has direct implications for double-bond isomerization reactivity and thus the regioisomery of liquid olefin products. Density functional theory calculations ascribe oxide promotion to an enhanced competitive adsorption of molecular CO versus hydrogen and olefins on oxide-decorated cobalt surfaces, dampening (secondary) olefin hydrogenation, and suggest an exacerbated metal surface carbophilicity to underlie the undesired induction of WGSR activity by strongly electron-donating alkali oxide promoters. Enhanced pore molecular transport within a multimodal meso-macroporous architecture in combination with PrO x as promoter, at an optimal surface loading of 1 Prat nm-2, results in an unconventional product distribution, reconciling benefits intrinsic to Co- and Fe-based FT catalysts, respectively. A chain-growth probability of 0.75, and thus >70 C% selectivity to C5+ products, is achieved alongside lighter hydrocarbon (C5-10) condensates that are significantly enriched in added-value chemicals (67 C%), predominantly α-olefins but also linear alcohols, remarkably with essentially no CO2 side-production (<1%). Such unusual product distributions, integrating precursors for synthetic fuels and liquid platform chemicals, might be desired to diversify the scope and improve the economics of small-scale gas- and biomass-to-liquid processes.
RESUMEN
The effect of both the Fe : Ni ratio (5 to 1 : 1) and the relative Lewis acidity of a metal oxide support on catalytic activity, selectivity and stability was investigated in the CO2 mediated oxidative dehydrogenation of ethane (CO2-ODH). To avoid effects of varying pore sizes, shapes and volumes of the supports, chromia and zirconia overlayers were coated onto a common γ-Al2O3 carrier (CrOx@Al2O3 and ZrOx@Al2O3). Separately, oxidic FexNiy alloy precursor nanoparticles were prepared using a nonaqueous surfactant-free method and deposited by sonication onto the carrier. In comparison to previous studies in the field, this synthesis technique yields closely associated iron and nickel increasing the chances for alloy formation. During reduction, a mixture of a bcc and a fcc alloy phase was formed, with the content of bcc increasing with increasing iron content as predicted by the bulk phase diagram. Upon exposure to carbon dioxide at elevated temperatures, the bcc metallic phase is selectively oxidised to an inverse spinel structure via the dissociation of CO2. When exposed to CO2-ODH conditions, the bare ZrOx@Al2O3 support shows no activity. The presence of FeNi phases increases the conversion of ethane and CO2 marginally (<2%) but forms ethylene at high selectivity (SC2H4 > 80%). The CrOx@Al2O3 support shows some initial activity (XC2H6 < 5%) at very high ethylene selectivity (SC2H4 > 90%) but deactivates with time on stream. Comparison of the ethane and carbon dioxide conversions suggests that direct dehydrogenation rather than the oxidative pathway is taking place. When FeNi particles with the highest Fe content are added, the ethane conversion behavior hardly changes, but the CO2 conversion is increased now supporting the stoichiometric CO2-ODH reaction (SC2H4 > 95%). It is therefore evident that a tandem catalyst system between a reducible oxide carrier and the FeNi species is required. Increasing the Ni content results in an increase in activity and stability while changing the dominant reaction pathway to a combination of dry reforming, CO2-ODH and possibly the reverse Boudouard reaction, with the latter countering catalyst deactivation through carbon deposition.