RESUMEN
Water quality related to non-point source pollution continues to pose challenges in agricultural landscapes, despite two completed cycles of Water Framework Directive actions by farmers and landowners. Future climate projections will cause new challenges in landscape hydrology and subsequently, the potential responses in water quality. Investigating the nutrient trends in surface waters and studying the efficiency of mitigation measures revealed that loads and measures are highly variable both spatially and temporally in catchments with different agro-climatic and environmental conditions. In Sweden, nitrogen and phosphorus loads in eight agricultural catchments (470-3300 ha) have been intensively monitored for >20 years. This study investigated the relationship between precipitation, air temperature, and discharge patterns in relation to nitrogen (N) and phosphorus (P) loads at catchment outlets. The time series data analysis was carried out by integrating Mann-Kendall test, Pettitt break-points, and Generalized Additive Model. The results showed that the nutrient loads highly depend on water discharge, which had large variation in annual average (158-441 mm yr-1). The annual average loads were also considerably different among the catchments with total N (TN) loads ranging from 6.76 to 35.73 kg ha-1, and total P (TP) loads ranging from 0.11 to 1.04 kg ha-1. The climatic drivers were highly significant indicators of nutrient loads but with varying degree of significance. Precipitation (28-962 mm yr-1) was a significant indicator of TN loads in five catchments (loamy sand/sandy loam) while annual average temperature (6.5-8.7 °C yr-1) was a significant driver of TN loads in six out of eight catchments. TP loads were associated with precipitation in two catchments and significantly correlated to water discharge in six catchments. Considering the more frequent occurrence of extreme weather events, it is necessary to tailor N and P mitigation measures to future climate-change features of precipitation, temperature, and discharge.
RESUMEN
Recent technological breakthroughs of optical sensors and analysers have enabled matching the water quality measurement interval to the time scales of stream flow changes and led to an improved understanding of spatially and temporally heterogeneous sources and delivery pathways for many solutes and particulates. This new ability to match the chemograph with the hydrograph has promoted renewed interest in the concentration-discharge (c-q) relationship and its value in characterizing catchment storage, time lags and legacy effects for both weathering products and anthropogenic pollutants. In this paper we evaluated the stream c-q relationships for a number of water quality determinands (phosphorus, suspended sediments, nitrogen) in intensively managed agricultural catchments based on both high-frequency (sub-hourly) and long-term low-frequency (fortnightly-monthly) routine monitoring data. We used resampled high-frequency data to test the uncertainty in water quality parameters (e.g. mean, 95th percentile and load) derived from low-frequency sub-datasets. We showed that the uncertainty in water quality parameters increases with reduced sampling frequency as a function of the c-q slope. We also showed that different sources and delivery pathways control c-q relationship for different solutes and particulates. Secondly, we evaluated the variation in c-q slopes derived from the long-term low-frequency data for different determinands and catchments and showed strong chemostatic behaviour for phosphorus and nitrogen due to saturation and agricultural legacy effects. The c-q slope analysis can provide an effective tool to evaluate the current monitoring networks and the effectiveness of water management interventions. This research highlights how improved understanding of solute and particulate dynamics obtained with optical sensors and analysers can be used to understand patterns in long-term water quality time series, reduce the uncertainty in the monitoring data and to manage eutrophication in agricultural catchments.
RESUMEN
In Kattegat and the coastal water of the Baltic Sea, high nitrogen input from agricultural land is considered to be the main reason for eutrophication. International agreements and governmental programs have set a target to reduce the anthropogenic nitrogen load by 50 percent. Improved nitrogen removal in treatment plants and efforts in agriculture have so far not decreased nitrogen transport to a sufficient extent. In this project the impact of agricultural practices on nitrogen leaching was investigated in two small agricultural catchments in Southwest Sweden. The root-zone leaching was estimated by an indexing technique. Simultaneously the transports in the stream outlets were monitored. During 1995 and 1999 the agricultural practices in the catchments were surveyed. Field data from the first survey indicated that fertilisation did not always match crop requirements, the area of undersown catch crop can be increased and autumn cultivation can be reduced. The second survey was preceded by an advisory campaign where each farmer was visited and presented with an environmental plan including fertilisation, cultivation, and crop rotation for the farm. The plan summarised the best management practices that could be realised under actual conditions. Results from the second survey showed that some changes in the agricultural practices were carried out after the advisory campaign. The nitrogen leaching from the root-zone was then estimated by the indexing technique, both for the time before and after the advisory program. The results showed that the estimated nitrogen leaching, as a mean value for 330 fields, decreased from 53 to 50 kgN ha(-1), due to adjustments of the agricultural practices. Monitoring of stream transports showed values of the same magnitude after correction for retention and other sources. In this short time perspective, decreases in transport due to changes in agricultural practices could not be separated from influence of weather conditions. In comparison to results from the Swedish monitoring programme for agriculture, the measured transports were normal for the region, where annual variation in precipitation and runoff is large. Theoretically, nitrogen leaching could be reduced by one third without any major economic constraints for the farmers. In general, the farmers were positive to advice and willing to try new farming techniques even if some measurements were not fully implemented during the investigation period.