Responses of CO2 and CH4 in the alpine wetlands of the Tibetan Plateau to warming and nitrogen and phosphorus additions.

Wetland ecosystems store large amounts of carbon, and CO2 and CH4 fluxes from this ecosystem receive the double impact of climate change and human activities. Nonetheless, research on how multi-gradient warming and nitrogen and phosphorus additions affect these wetland greenhouse gas emissions is still limited, particularly in alpine wetland ecosystems. Therefore, we conducted a field experiment on the Tibetan Plateau wetlands, investigating the effects of warming and nitrogen and phosphorus additions on the CO2 and CH4 fluxes in alpine wetlands. Results indicated that warming enhanced the CO2 absorption and CH4 emission in the alpine meadow ecosystem, possibly related to changes in plant growth and microbial activity induced by warming, while we noticed that the promotion of CO2 uptake weakened with the increase in the magnitude of warming, suggesting that there may be a temperature threshold beyond which the ecosystem's capacity for carbon sequestration may be reduced. Nitrogen addition increased CH4 emission, with the effect on CO2 absorption shifting from inhibition to enhancement as the amount of applied nitrogen or phosphorus increased. The interaction between warming and nitrogen and phosphorus additions further influenced CH4 emission, exhibiting a synergistic enhancement effect. This study deepens our understanding of the greenhouse gas responses of alpine wetland ecosystems to warming and nitrogen and phosphorus additions, which is significant for predicting and managing ecosystem carbon balance under global change.

Global evapotranspiration from high-elevation mountains has decreased significantly at a rate of 3.923 %/a over the last 22 years.

Clarifying the responses of human activities and climate change to the water cycle under variable environments is crucial for accurately assessing regional water balance. An analysis of the changes in actual evapotranspiration and its driving factors was conducted in the global high-elevation mountains during the period from 2001 to 2022. Utilizing 18 formulas for calculating evapotranspiration, which are based on comprehensive, temperature, radiation, and mass transfer, and then simulated the variations in reference evapotranspiration. Furthermore, we optimized the ET simulation model based on the most effective simulation results and projected future changes using scenario simulation data. Our findings reveal that: 1) ET at high-elevation mountains has significantly decreased at an average rate of 3.923 %/a, with monthly values ranging from 31.179 to 33.652 mm and an average of 32.646 mm; 2) The radiation-based model of Irmark-Allen is particularly well-suited for simulating ET at high-elevation mountains, with precision analysis and the Taylor diagram confirming its superior simulation performance. After optimizing the model using the method of least squares, the value of R2 before and after the optimization were 0.633 and 0.853, respectively. 3) An upward trend in ET under both SSP245 and SSP585 scenario in future simulation projections. Attribution analysis has identified Vapor Pressure Deficit as the key positive driver influencing the change of ET in global high-elevation mountains. Structural equation modeling further reveals that variations in net radiation and precipitation play a significant role in altering evapotranspiration rates. Meanwhile，The water balance analysis reveals that ET has been declining from 2001 to 2022. This phenomenon can be largely attributed to the substantial decline in vapor pressure deficit, the rise in the Normalized Difference Vegetation Index signifying increased vegetation cover, and the reduction in shallow soil moisture during the same period. These factors collectively explain the notable decrease in ET observed in high-elevation mountains.

Atmospheric precipitation chemistry and environmental significance in major anthropogenic regions globally.

In order to investigate the spatiotemporal distribution and influencing factors of global precipitation chemistry, we conducted a comprehensive analysis using multiple data sources, revealing the impact of human activities on the natural environment. The results indicate a decreasing trend in global precipitation acidity over the past 20 years. The distribution of global precipitation is influenced by both natural and anthropogenic factors. Alkaline cation concentrations are higher in desert and arid regions, while high concentrations of SO42- and NO3- are primarily found in industrial areas, and agricultural areas exhibit higher NH4+ concentrations. Coastal regions have higher Na+ and Cl- concentrations compared to inland areas. However, the increased Na + and Cl- concentrations due to inland salinization should not be overlooked. Additionally, influenced by atmospheric circulation, transboundary pollution from South Asia leads to higher SO42- and NO3- concentrations in precipitation over the Tibetan Plateau. Meteorological factors have a weaker influence on precipitation chemistry compared to geographical and human activity factors, although ion concentrations in snowfall are higher than in rainfall.

The effect of freeze-thaw action on the dynamic change of supra-permafrost water sources: A stable isotope perspective.

Due to the continuous degradation (gradual thawing) of permafrost, supra-permafrost water has become an important component of runoff that occurs in cold regions. However, current research has only focused on the amount of water provided by permafrost, and little has been reported regarding the source and formation mechanisms of supra-permafrost water. Due to the difficulty of observation and sampling in cold regions and insufficient data accumulation, model simulations face various difficulties in regard to solving problems related to hydrological processes. Considering the advantages of stable isotope tracer methods in hydrology, the source of supra-permafrost water in Qilian Mountain was analyzed based on 1,840 samples, and the source of supra-permafrost water was determined by end-member mixing analysis (EMMA). Negative line-conditioned excess (lc-excess), lower slope, and particularly the negative intercept of the evaporation line (EL) indicates strong evaporation effects on supra-permafrost water. Remarkably, the evolutionary process, influencing factors, and relationship with other water bodies all indicate that supra-permafrost water is replenished by precipitation, ground ice meltwater, and snow meltwater. The results indicated that from May to October, the contributions of precipitation to the supra-permafrost water were 79%, 83%, 90%, 84%, 87%, and 83%, respectively. Snow meltwater contributed 11%, 13%, 10%, 16%, 11%, and 9%, respectively. Permafrost degradation impacts the water cycle and can increase the minimum monthly runoff and increase groundwater storage. To mitigate the effects of this change, monitoring and early warning systems are essential for detecting signs of permafrost degradation in a timely manner so that appropriate measures can be taken. This may involve the use of remote-sensing technologies, sensor networks, and other methods for real-time monitoring. Establishing mechanisms for sharing information with the relevant departments is crucial. The research results provide scientific and technological support and aid in decision-making to mitigate the negative effects of continuous permafrost degradation in a changing environment.

Vegetation restoration strategies based on plant water use patterns.

The study on the water source of plants in alpine mountainous is of great significance to optimize the allocation and management of water resources, and can also provide important reference for ecological restoration and protection. However, the controls of water sources for different plants in alpine mountainous region remain poorly understood. Based on the advantages of stable isotope tracer and Bayesian (MixSIAR) model, the water source of plants in Qilian Mountains was quantitatively analyzed. The results showed that the water sources of plants in Qilian Mountain mainly included two parts: direct source and indirect source. The direct source is soil water, which provides most of the water that plants need. The highest contribution of soil water to shrubs was 80 %, followed by trees (73 %) and herbs (72 %). It is worth mentioning that trees mainly use deeper soil water (below 60 cm), shrubs mainly use surface and intermediate soil water (0-60 cm), and herbs mainly use surface soil water (0-40 cm). What is more noteworthy is that indirect sources, such as precipitation, glacier and snow meltwater, and groundwater, are also water sources that cannot be ignored for plant growth in study area. Shrubs and Herbs use more soil water in the range of 40-60 cm, which leads to the possibility of water competition between these two planting types. Therefore, attention should be paid to this phenomenon in the process of vegetation restoration and water resources management. Especially when planting or restoring artificial plants, it is necessary to consider the water use strategy of the two plants to avoid unnecessary water competition and water waste. This is of great significance for ecological stability and sustainable utilization of water resources in the study region.

Sand fixation and human activities on the Qinghai-Tibet Plateau for ecological conservation and sustainable development.

The sand fixation ecosystem services and human activities on the Qinghai-Tibet Plateau (QTP) play a crucial role in local sustainable development and ecosystem health, with significant implications for surrounding regions and the global ecological environment. We employed an improved integrated wind erosion modeling system (IWEMS) model for the QTP to simulate sand fixation quantities under the unique low temperature and low pressure conditions prevalent on the plateau. Using the human footprint index (HFI), the intensity of human activities on the plateau was quantified. Additionally, an econometric model was constructed to analyze the impacts of the natural factors, the HFI, and policy factors on the sand fixation capacity. The results revealed that the average sand fixation quantity was 1368.0 t/km2/a, with a standard deviation of 1725.4 t/km2/a, and the highest value during the study period occurred in 2003. The average value of the HFI for 2020 was 6.69 with a standard deviation of 6.61, and the HFI exhibited a continuous growth trend from 2000 to 2020. Despite this growth, the average human activity intensity remained at a low level, with over 50 % of the area having an index value of <4.84. Overall, a strong negative correlation was observed between the sand fixation ecological capacity and the HFI on the QTP. However, extensive regions exhibited high values or low values for both indicators. The sand fixation capacity on the QTP is influenced by both natural and human factors. In light of these findings, suggestions are made for optimizing protected area design, rational control of human activity scales, and targeted human activity aggregation within certain regions as part of ecological conservation strategies. This study has implications for assessing sand fixation ecological functions in high-altitude regions and enhancing sand fixation capacity within the region, providing valuable practical guidance.

Particularity of hydrological processes under heavy ablation based on environmental isotopes in transition zones between endorheic and exorheic basins.

Drastic changes in the cryosphere have a significant impact on the quantity and formation process of water resources in the Qilian Mountains. The present study focused on quantitative evaluation of runoff components and runoff formation processes during strong ablation periods (August), in 2018, 2020, and 2021, in the transition zone between endorheic and exorheic basins in China, based on 1906 stable isotope samples. The results revealed that as the altitude decreased, the contribution of glacier and snow meltwater and permafrost water to runoff decreased, whereas that of the precipitation increased. Precipitation is a major source of river runoff in the Qilian Mountains. Notably, the runoff yield and concentration of rivers that were greatly affected by the cryosphere exhibited the following characteristics: (1) The altitude effect of stable isotopes was not significant and even showed a reverse trend in some rivers. (2) The processes of runoff yield and composition were relatively slow; as such, precipitation, glacier and snow meltwater, and supra-permafrost water were first transformed into groundwater and then supplied runoff to upstream mountainous region. (3) Finally, stable isotope composition in such rivers were similar to those in glaciers and snow meltwater, with small fluctuations. Therefore, the water sources of rivers affected by the cryosphere are more uncertain than those of rivers unaffected by the cryosphere. In future study, a prediction model of extreme precipitation and hydrological events will be developed, and a prediction technology for runoff formation and evolution in glacier snow and permafrost will be developed to integrate short-and long-term forecasts.

Precipitation changes and its interaction with terrestrial water storage determine water yield variability in the world's water towers.

Previous studies have quantified the contributions of climate factors, vegetation, and terrestrial water storage change, and their interaction effects on hydrological process variation within the Budyko framework; however, further decomposition of the contributions of water storage change has not been systematically investigated. Therefore, focusing on the 76 water tower units of the world, the annual water yield variance was first examined, followed by the contributions of changes in climate, water storage change, and vegetation, as well as their interaction effects on water yield variance; finally, the contribution of water storage change on water yield variance was further decomposed into the effect of changes in groundwater, snow water, and soil water. The results showed that large variability exists in the annual water yield with standard deviations ranging from to 10-368 mm in water towers globally. The water yield variability was primarily controlled by the precipitation variance and its interacted effect with water storage change, with the mean contributions of 60 % and 22 %, respectively. Among the three components of water storage change, the variance in groundwater change had the largest effect on water yield variability (7 %). The improved method helps separate the contribution of water storage components to hydrological processes, and our results highlight that water storage changes should be considered for sustainable water resource management in water-tower regions.

[Spatial Distribution Characteristics and Influencing Factors of Soil Organic Carbon Density in Yellow River Basin Based on MGWR Model].

As the largest terrestrial carbon pool, the spatial distribution characteristics and influencing factors of soil organic carbon have important implications for global carbon cycle processes. Soil organic carbon density (SOCD) and influencing factors were predicted in the Yellow River basin using a mixed geographically weighted regression (MGWR) model based on soil organic carbon density data and environmental factors. The results showed that:① the SOCD ranged from 0-14.82 kg·m-2 and 0-32.39 kg·m-2 for the soil depths of 0-20 cm and 0-100 cm, with mean values of 3.48 kg·m-2 and 8.07 kg·m-2 and reserves of 2.76 Pg and 6.48 Pg, respectively. The high SOCD value areas were mainly located in the southern part of the Qinghai-Tibet Plateau and Loess Plateau, and the low value areas were located in the eastern part of the upper Yellow River and the inland flow area. ②Among the ecosystem types, the SOCD of soil depth in 0-20 cm was in the descending order of:forest>water body and wetland>other>grassland>farmland>settlement>desert, with mean values of 4.52, 4.31, 3.84, 3.73, 2.89, 2.78, and 2.22 kg·m-2, respectively, and the SOCD of the 0-100 cm soil depth was in the descending order of:water bodies and wetlands>forest>other>grassland>farmland>settlement>desert, with mean values of 9.58, 9.58, 8.85, 8.66, 7.07, 6.81, and 5.29 kg·m-2, respectively. The SOCR in descending order was:grassland>farmland>forest>desert>water bodies and wetlands>settlement>others, with 1.40, 0.60, 0.47, 0.11, 0.07, 0.06, and 0.05 Pg at a soil depth of 0-20 cm and 3.31, 1.49, 0.99, 0.26, 0.17, 0.14, and 0.12 Pg at a soil depth of 0-100 cm, respectively. ③ The main factors affecting the SOCD distribution were intercept, profile curvature, NDVI, and precipitation; in addition, curvature and silt also had important effects on the deep SOCD distribution in the Yellow River basin. Among the ecosystem types, precipitation and NDVI were the main factors affecting the SOCD distribution. The intercept also had important effects on the SOCD distribution in the all ecosystems except forests, whereas curvature and silt only had important effects on deserts and other ecosystems. These results revealed the spatial distribution of SOCD, influencing factors, and SOCR in the Yellow River basin and can provide a scientific basis for carbon balance, soil quality evaluation, and ecological management restoration and consolidation in the region.

Autotrophic denitrification using Fe(II) as an electron donor: A novel prospective denitrification process.

As a newly identified nitrogen loss pathway, the nitrate-dependent ferrous oxidation (NDFO) process is emerging as a research hotspot in the field of low carbon to nitrogen ratio (C/N) wastewater treatment. This review article provides an overview of the NDFO process and summarizes the functional microorganisms associated with NDFO from different perspectives. The potential mechanisms by which external factors such as influent pH, influent Fe(II)/N (mol), organic carbon, and chelating agents affect NDFO performance are also thoroughly discussed. As the electron-transfer mechanism of the NDFO process is still largely unknown, the extensive chemical Fe(II)-oxidizing nitrite-reducing pathway (NDFOchem) of the NDFO process is described here, and the potential enzymatic electron transfer mechanisms involved are summarized. On this basis, a three-stage electron transfer pathway applicable to low C/N wastewater is proposed. Furthermore, the impact of Fe(III) mineral products on the NDFO process is revisited, and existing crusting prevention strategies are summarized. Finally, future challenges facing the NDFO process and new research directions are discussed, with the aim of further promoting the development and application of the NDFO process in the field of nitrogen removal.

Environmental effect and spatiotemporal pattern of stable isotopes in precipitation on the transition zone between the Tibetan Plateau and arid region.

In the transition zone between the Tibetan Plateau and the arid region of northwestern China, the spatiotemporal patterns and environmental controls of stable isotopes in precipitation remain unclear. A network of 19 sampling stations was established across the Qilian Mountains to observe stable isotopes in precipitation, and 1310 precipitation event-scale samples were collected. The local meteoric water line (LMWL) was obtained and expressed as δD = 7.99δ18O + 14.57 (R2 = 0.96). The spatiotemporal patterns of the stable isotopes were mainly dominated by the co-influence of the water vapor sources and the local environment. The westerly circulation, monsoon circulation, and Arctic circulation accounted for 79%, 13%, and 8% of all precipitation events in the study region, respectively. The rainout process also caused oxygen isotope depletion for continuous precipitation events. When the temperature increased by 1 °C, δ18O increased by 0.47‰, but this increase varied with the temperature range. The effect of precipitation amount was apparent in summer and was caused by sub-cloud evaporation. In addition, δ18O decreased by 0.13‰ for every 100 m increase in altitude in the Qilian Mountains. Future research should focus on quantifying the co-influence of sub-cloud evaporation, local moisture recycling, and water vapor sources on stable isotopes in precipitation.

An ecological footprint approach for cropland use sustainability based on multi-objective optimization modelling.

Croplands are heterogeneous in productivity and their sustainable use holds a prominent place in supporting a virtual society-economy-ecology-environment circle. This study developed a model for the evaluation of cropland use sustainability by integrating the revised ecological footprint model with multi-objective optimization. The model enabled to gain insights into changes of the supply-demand balance of cropland use ecologically from a planning perspective, and also enables policy makers to determine the optimal patterns of cropland use in order to reconcile contradictions between multiple dimensions in agroecosystems, such as resource utilization, economy, society, and environment. The model was demonstrated by solving a real-world problem of cropland use management in Heilongjiang Province, northeast China. Results of demonstration were found to be satisfactory for generating sustainable cropland use patterns in promoting the equilibrium of water use efficiency, net economic benefit, land resource allocation equity, and greenhouse gas emissions. Then, whether various cropland use patterns were ecologically safe based on crop ecological footprint and crop ecological carrying capacity were determined. The status and scenario-based trend of cropland use sustainability provided alternatives for policy makers to allocate cropland efficiently and sustainably. The model is applicable for similar planting-centered regions with limited land and water resources.

The sources of supra-permafrost water and its hydrological effect based on stable isotopes in the third pole region.

The sources of supra-permafrost water and its hydrological effects were studied, based on the presence of stable isotopes in 562 samples collected in different ablation periods from the source regions of the Yangtze River. The δ18O (δD and d-excess) values for the initial ablation, ablation, and end ablation periods were -10.18‰ (-71.39‰ and 10.08‰), -12.14‰ (-85.58‰ and 11.51‰) and -11.50‰ (-78.75‰ and 13.23‰), respectively. The order of the slopes for the supra-permafrost water evaporation lines from the different ablation periods was initial ablation (IA) > ablation (A) > end ablation (EA). An anti-altitude effect is documented here, for a specific altitude range, in what is believed to be the first record of such an occurrence. Outside of that range, clear altitude effects were apparent. We have been able to show that supra-permafrost water was mainly recharged by atmospheric precipitation, ground ice, and glacier and snow meltwater, in the initial ablation and end ablation periods, and contributions from glacier and snow meltwater were mainly concentrated in higher altitude regions. In contrast, in the ablation period, supra-permafrost water was mainly recharged by atmospheric precipitation and ground ice. The contributions of precipitation to supra-permafrost water were 78.79%, 85.47%, and 82.99% in the initial ablation, ablation, and end ablation periods, respectively. The contributions of ground ice to the supra-permafrost water were 14.05%, 14.53%, and 11.94%, respectively, while contributions of glacier and snow meltwater were 7.15% and 5.07% in the initial and end ablation period. For the initial ablation, ablation, and end ablation periods, contributions from atmospheric precipitation to the supra-permafrost water were 85.47%, 86.86%, and 86.84%, while contributions from ground ice were 14.53%, 13.14% and 13.16%, respectively.

Transformation mechanism of ions on different waters in alpine region.

The study investigates transformation mechanism of ions on different waters in Alpine region through analyzed the hydrochemical characteristics of the major ions of precipitation, glacier and snow meltwater, supra-permafrost water and river water in permafrost regions in the Tibetan Plateau under climate warming. The results showed that, The relation between recharge and discharge was the major ways for ionic transformation of each water body. Precipitation and glacier and snow meltwater are the main input sources for ionic transformation, and river water is the final output source. Different water bodies had different ionic concentrations and different hydrochemical types. However, different water bodies in different months (from June to September) also had different hydrochemical types. The water - rock interaction, reactions for ions, dilution effect and other effect for ions played an important role in the process of ion transformation. The increasing of temperature would lead to the accelerated melting of glaciers, permafrost and snow in the alpine regions, so the amount of supra-permafrost water and glacier and snow meltwater will increase, which leads to the increase of runoff. Meanwhile, the increase of temperature makes evaporation stronger. The strong of evaporation will accelerate the transformation of liquid water to gaseous water. Moreover, ion translation and water conversion are synchronous. Accordingly, ions are also accelerating transformation in the process of accelerated transformation of water body. Climate change is not only the main driving force for multiphase water transformation, but also the main driving force for the ion transformation of various water bodies.

Tracing geochemical pollutants in stream water and soil from mining activity in an alpine catchment.

This research developed a method of tracing major water chemical parameters (WCP) and soil heavy metals (HM) to identify the processes of mining pollution in topographically complex landscapes. Ninety-nine spatially distributed water samples were collected to characterise the hydrochemical characteristics of an alpine river in north-west China. Sixty river WCP and fifty-six soil HM samples from areas near mining sites were then used to analyse the mining pollution process. Geographical and mining activity characteristics were derived from topographic and mine site information. The occurrence of sulphates (SO42-) and nitrates (NO3-) in river water were highly correlated (up to 0.70), providing strong evidence of pollution from nearby mining activities. Levels of arsenic and cadmium were high in first and fifth order streams, where mining activities were most concentrated. The modelling results showed that geographical patterns and mining activity account for predicting HM distribution, and WCP can be reasonable predictors to trace soil mining pollution. This research can help improve the accuracy of predicting the mining pollution process.

[Characteristics of Stable Isotopes and Analysis of Water Vapor Sources of Precipitation at the Northern Slope of the Qilian Mountains].

This study is based on precipitation samples from eight sites at the northern slope of the Qilian Mountains, combined with meteorological factors over the same period. Precipitation isotope characteristics, influence factors and the vapor sources of precipitation were analyzed, and the results show that:① The stable isotopes of precipitation in the study area show obvious seasonal changes, which are characterized by enrichment in the summer half-year and depletion in the winter half-year. The spatial precipitation δ18O value shows a significant downward trend with increasing altitude, and the altitude effect of the annual precipitation δ18O is -0.19‰/100 m, respectively;② At all stations, the slope and intercept of local meteoric water lines show an increasing trend from low altitude to high altitude. The high-altitude mountains above 2000 m are affected by local water vapor recirculation;③ The temperature effect is more significant and the temperature effect of δ18O is 0.64‰, and there is only a weak precipitation effect in summer;④ The results indicate that sub-cloud evaporation has a great influence on the δ18O of precipitation; the average raindrop evaporation rate of δ18O is 23%, 11%, 12%, and 16%,and the δ18O composition has been enriched by 46%, 27%, 38%, and 32% in May, June, July, and August from cloud base to ground, respectively.⑤ Under the condition of continuous rainfall in summer, the vapor sources of precipitation mainly come from the west and are affected by local evaporation of water vapor. The study enhances knowledge of isotopic evolution of precipitation and provides a basis for further study of isotopic hydrology in arid regions.

Response mode of hydrochemical types of river water to altitude gradient in alpine regions.

The study investigates the hydrochemical type and characteristics of river water in permafrost regions in the Tibetan Plateau by analyzing 532 samples collected from the source region of the Yangtze River. The hydrochemical type of the river water was Cl--Na+-SO42-, and its hydrochemical characteristics were primarily influenced by the soil sources, though the influence of the sea sources and anthropogenic factors could not be ignored. Significant negative correlations were found between temperature and NO3-, SO42-, Mg2+, Ca2+, and between precipitation, relative humidity, and SO42- and Mg2+ in the river water. River water in the higher altitudes of over 5000 m above sea level was mainly recharged from glacier snowmelt water and by the supra-permafrost water and precipitation at the altitudes between 3500 and 5000 m above sea level. The controlled sources of hydrochemical characteristics of glacier snowmelt water were different for different ablation rates in the area with elevations of over 5000 m above sea level. Different hydrochemical types in different ablation rates implied the hydrochemical type was extremely sensitive to ablation periods in areas with elevation of over 5000 m above sea level. However, hydrochemical type was not sensitive to ablation periods from 3500 to 5000 m above sea level. The ionic concentration of glacier snowmelt water was mainly controlled by pollutants in glaciers and snow. Melting rates of glacier snowmelt water also had a certain effect on ionic concentration. Meanwhile, the stability of the hydrochemical type implied river water mainly controlled the hydrochemical type from 3500 to 5000 m above sea level. Hydrochemical type had no effect on elevation in end ablation.

[Space-time Characteristics and Environmental Significance of Stable Isotopes in Precipitation at an Arid Inland River Basin].

This study was based on one complete hydrological year sampling of precipitation and meteorological data of the Shiyang River Basin in the Wuwei Station (1531 m a.s.l.), Minqin Station (1389 m a.s.l.), and Xidahe Station(2897 m a.s.l.) from July 2013 to July 2014. This paper aims to analyze temporal and spatial variation of stable isotopes in local precipitation, and discuss the impact of environmental factors during precipitation. The stable isotope evolution correlation with temperature, humidity, precipitation, vapor pressure, and average relative humidity is analyzed. The results show that:①During the study period, the stable isotope of precipitation showed significant seasonal changes, lower in the winter and spring, higher in the summer and autumn;②The monthly average D-excess of Wuwei Station is lower than that of Xidahe Station. In addition to the possibility of different water vapor sources, the high-altitude mountain areas are more affected by local recirculating water vapor, and the secondary evaporation under the clouds in low-altitude plain areas is stronger;③The stable isotope of precipitation in the basin shows a significant temperature effect, and the precipitation effect is reflected on the weather scale, which may be affected by leaching or monsoon circulation;④The δ18O value of precipitation is negatively correlated with the average relative humidity. It may be that the secondary evaporation under the cloud is weakened by the increase of precipitation and humidity.

Climate background, relative rate, and runoff effect of multiphase water transformation in Qilian Mountains, the third pole region.

Multiphase water transformation has great effects on alpine hydrology, but these effects remain unclear in the third pole region. Taking the Qilian Mountains as an example, the climate background and relative rates of multiphase water transformation were analyzed, and the runoff effect was evaluated based on long-term field observations. There are three climatic aspects driving multiphase water transformation, including lengthening ablation period, accelerative warming after 1990, and larger warming in the cryosphere belt than in the vegetation belt. The accelerative multiphase water transformation was quantified by three facts: the glacier area retreat rate accelerated by 50% after 1990, the percentage of snowfall in precipitation decreased by 7% after 1990, and the contribution from recycling moisture to precipitation increased by 60% from 1961-1990 to 1991-2016. Under the multiphase water transformation, the outlet runoff for three inland rivers increased by 5 × 108 m3/10 a after 1990. This runoff increase was concentrated mainly in the ablation period. For the seasonal runoff pattern, maximum runoff lagged maximum precipitation by one month under increasing glacier snow meltwater and thickening permafrost active layer. Meltwater from the cryosphere is a crucial runoff component in the Qilian Mountains. At present, these multiphase water transformations are accelerating, along with the yearly runoff increase, which will obviously have a profound impact on water resources management and flood control in the third pole region.