Porous Organic Polymers as Active Electrode Materials for Energy Storage Applications.

Eco-friendly and efficient energy production and storage technologies are highly demanded to address the environmental and energy crises. Porous organic polymers (POPs) are a class of lightweight porous network materials covalently linked by organic building blocks, possessing high surface areas, tunable pores, and designable components and structures. Due to their unique structural and compositional advantages, POPs have recently emerged as promising electrode materials for energy storage devices, particularly in the realm of supercapacitors and ion batteries. In this work, a comprehensive overview of recent progress and applications of POPs as electrode materials in energy storage devices, including the structural features and synthesis strategies of various POPs, as well as their applications in supercapacitors, lithium batteries, sodium batteries, and potassium batteries are provided. Finally, insights are provided into the future research directions of POPs in electrochemical energy storage technologies. It is anticipated that this work can provide readers with a comprehensive background on the design of POPs-based electrode materials and ignite more research in the development of next-generation energy storage devices.

Flexible ultrathin Nitrogen-Doped carbon mediates the surface charge redistribution of a hierarchical tin disulfide nanoflake electrode for efficient capacitive deionization.

Constructing pseudocapacitive electrodes with high specific capacities is indispensable for increasing the large-scale application of capacitive deionization (CDI). However, the insufficient CDI rate and cycling performance of pseudocapacitive-based electrodes have led to a decline in their use due to the corresponding volumetric expansion and contraction that occurs during long-term CDI processes. Herein, hierarchical porous SnS2 nanoflakes are encapsulated inside an N-doped carbon (NC) matrix to achieve efficient CDI. Benefiting from the synergistic properties of the pseudocapacitive SnS2 nanoflakes and few-layered N-doped carbon, the heterogeneous interface simultaneously provides more available vigorous sites and demonstrates rapid charge-transfer kinetics, resulting in a superior desalination capability (49.86 mg g-1 at 1.2 V), rapid desalination rate (1.66 mg g-1 min-1) and better cyclic stability. Computational research reveals a work function-induced surface charge redistribution of the SnS2@NC heterojunction, which can lead to an auspicious surface electronic structure that reduces the adsorption energy to improve the diffusion kinetics toward sodium adsorption. This work contributes to providing a thoughtful understanding of the interface engineering between transition metal dichalcogenides and NC to construct high-performance CDI electrode materials for further industrialization.

Single-atom electrocatalysts templated by MOF for determination of levodopa.

To overcome the problem of incorrect levodopa (LD) dosage in the treatment of Parkinson's disease, a new analytical tool is urgently needed for accurately determining the concentration of LD in human fluids. Herein, an effective and stable sensor based on a Co-single-atomic-site catalyst (Co-SASC)-modified glassy carbon electrode (Co-SASC/GCE) was developed for the determination of LD concentration. The physicochemical characterization of Co-SASC is systematically investigated. It has excellent thermal stability, graphitization degree, and a large specific surface area. Benefiting from its porous structure for kinetically fast catalysis and component advantages for fix a single cobalt atom to improve stability, Co-SASC/GCE exhibits a superior electrochemical response. Under optimal conditions (pH 2.0, coating amount is 10 µg), an ideal linear relationship is achieved between the logarithm of the peak current of the sensor and the logarithm of LD concentration. The linear range is 0.1-200 µM, and the limit of detection (LOD) is 0.033 µM. After a simple pretreatment, LD in human serum is detected by Co-SASC/GCE with excellent stability and selectivity. As such, this work enlarges the existing electrochemical sensor toolbox by offering a reasonable design and synthesis protocol for advanced materials to accurately determine LD in human fluids for the clinical treatment of Parkinson's disease.

A robust electrochemical sensing based on bimetallic metal-organic framework mediated Mo2C for simultaneous determination of acetaminophen and isoniazid.

Herein, a Mo2C/bimetallic zeolitic imidazolate framework-modified glassy carbon electrode (Mo2C@BMZIFs/GCE) was established as an electrochemical sensor for the simultaneous sensitive determination of acetaminophen (APAP) and isoniazid (INZ). The apparent morphology, structural composition, and electrochemical properties were comprehensively investigated. The outstanding electrocatalytic activity and conductivity endow the sensor desirable electrochemical performance toward APAP and INZ compared to the bare GCE, such as wide linear range, low detection limit, and high selectivity. Under the optimum conditions, a linear relationship between the oxidation peak current and the concentration of the measured object was obtained, with linear ranges from 0.1 to 300 µM for APAP and from 10 to 3500 µM for INZ. The detection limits for APAP and INZ were 0.03 µM and 1.5 µM, respectively. More importantly, the APAP and INZ oxidation peaks could be completely separated. Moreover, the highly sensitive and stable sensor was applied to detect APAP and INZ in human serum. This work can provide a viable route to rational design and construct electrochemical sensors for drug monitoring and clinical diagnosis.

Ratiometric electrochemical sensing based on Mo2C for detection of acetaminophen.

In this work, MoO2 nanoparticles were synthesized and annealed to form Mo2C nanoparticles. This is the first report of a ratiometric electrochemical sensor (R-ECS) for the detection of acetaminophen (AP), in which Mo2C is used as the sensing agent and ferrocene (FC) is used as an internal reference. FC (100 µM) is added directly to the electrolyte solution for convenient operation. The synthesized materials were fully characterized with respect to composition, morphology and electrochemical performance. The oxidation peak potentials of FC (0.196 V) and AP (0.364 V) can be completely separated by the Mo2C modified glassy carbon electrode, and their ratiometric signals are used for the quantification of AP. It was found that the oxidation peak currents of AP at separated potentials on Mo2C/GCE are linear with concentration in the range of 0.5-600 µM, and the detection limit is 0.029 µM (S/N = 3). Mo2C/GCE exhibited decent repeatability, reproducibility, stability, and selectivity. The sensor was then applied to measure AP in tap water and river water.

A novel electrochemical sensor for determination of hydroxyl radicals in living cells by coupling nanoporous gold layer with self-assembled 6-(Ferrocenyl) hexanethiol.

The detection of hydroxyl radicals (•OH) in live cells is significant to study its physiological and pathological roles, while it is full of challenge due to the extremely low concentration and short lifetime of •OH. Herein, we have developed a novel electrochemical sensor based on 6-(Ferrocenyl) hexanethiol (6-FcHT) self-assembled nanoporous gold layer (NPGL) modified GE (6-FcHT/NPGL/GE), which can detect the release of •OH from living cells with high sensitivity and selectivity. The superior sensitivity can stem from the unique porous architecture of NPGL, which enlarged electrode surface area and expedited electron transportation during electrochemical reactions. Additionally, NPGL provides more active binding sites for the assembly of capture agent (6-FcHT) of •OH, thus ensuring high selectivity. For comparison, 6-FcHT/GE was applied to detect •OH, and the obtained sensitivity was 0.0305 mA nM-1 and detection limit was 0.133 nM in the linear range of 0.4 nM-70 nM. After modification of NPGL, the sensitivity of 6-FcHT/NPGL/GE to the •OH response was increased to 0.1364 mA nM-1, detection limit was reduced to 0.316 pM and the linear range was extended from 1 pM to 100 nM. It is worth mentioning that a plenty of extra merits has also been validated like reproducibility, repeatability and stability, enabling to direct electrochemical detection of •OH in HepG2 cells.