Charge transfer transitions of the O2+-Ar and O2+-N2 complexes.

Electronic transitions are observed for the O2+-Ar and O2+-N2 complexes over the 225-350 nm range. The transitions are not associated with recognized electronic band systems of the respective atomic and diatomic constituents (Ar+, Ar, O2+, O2, N2+, and N2) but rather are due to charge transfer transitions. Onsets of the O2+-Ar and O2+-N2 band systems occur at 3.68 and 3.62 eV, respectively, corresponding to the difference in the ionization potentials of Ar and O2 (3.69 eV), and N2 and of O2 (3.51 eV), suggesting the band systems arise from intramolecular charge transfer transitions to states correlating with O2(X3Σg-) + Ar+ (2Pu) and O2(X3Σg-) + N2+(X2Σg+) limits, respectively. The dominant vibronic progressions have ωe values of 1565 cm-1 for O2+-Ar and 1532 cm-1 for O2+-N2, reasonably close to the value for the neutral O2 molecule in its X3Σg- state (1580 cm-1). Higher energy band systems for O2+-Ar and O2+-N2 are assigned to transitions to states correlating with the O2 (a1Δg) + Ar+ (2Pu) and O2 (a1Δg) + N2+(X2Σg+) limits, respectively.

Electronic Spectra of Diacetylene Cations (HC4H+) Tagged with Ar and N2.

Electronic spectra of mass-selected HC4H+-Arn (n = 1-3) and HC4H+-(N2)n (n = 1-2) complexes are measured over the 290-530 nm range using resonance-enhanced photodissociation spectroscopy in a tandem mass spectrometer. Vibronic transitions in the visible region are compared with previous experimental and theoretical results for the Ã2Πu ← X̃2Πg band system of HC4H+. Hole burning experiments confirm that transitions over the 290-340 nm range involve the diacetylene cation (HC4H+). On the basis of previous experiments and comparison with spectra of isoelectronic molecules the peaks are assigned to the 22Πu ← X̃2Πg band system, with the origin transition for HC4H+-Ar occurring at 29723 cm-1. The main progression has a spacing of 906 cm-1 and is assigned to the symmetric C-C stretch vibrational mode (ν3). The assignment of additional bands is complicated by spectral congestion, the possible presence of energetically close-lying electronic states, vibronic coupling effects, and by the fact that HC4H+ possibly becomes nonlinear in the 22Πu state.

Difference between male and female workers lifting the same relative load when palletizing boxes.

A few biomechanical studies have contrasted the work techniques of female and male workers during manual material handling (MMH). A recent study showed that female workers differed from males mostly in the strategy they used to lift 15-kg boxes from the ground, especially regarding task duration, knee and back postures and interjoint coordination. However, the lifting technique difference observed in females compared to males was perhaps due to a strength differences. The objective of this study was to test whether female workers would repeat the same lifting technique with a load adjusted to their overall strength (females: 10 kg; males: 15 kg), which can be considered a "relative load" since the overall back strength of females is 2/3 that of males. The task for the participants consisted in transferring boxes from one pallet to another. A dynamic 3D linked segment model was used to estimate the net moments at L5/S1, and different kinematic variables were considered. The results showed that the biomechanics of the lifting techniques used by males and females were similar in terms of task duration and cumulative loading, but different in terms of interjoint coordination pattern. The sequential interjoint coordination pattern previously seen in females with an absolute load (15 kg) was still present with the relative load, suggesting the influence of factors more intrinsically linked to sex. Considering that the female coordination pattern likely stretched posterior passive tissues when lifting boxes from the ground, potentially leading to higher risk of injury, the reason for this sex effect must be identified so that preventive interventions can be proposed.

Intervention practices in musculoskeletal disorder prevention: a critical literature review.

Musculoskeletal disorders (MSDs) affect much of the workforce and remain a major form of occupational ill health. With a view to improving the efficacy of interventions, this review examined preventative actions relating to these disorders. A detailed analysis grid was used to classify the information contained in the 47 reviewed articles whose common aspect was to report actions carried out in the workplace that led to the implementation of changes to prevent MSDs. The analysis identified and characterized three major categories of intervention processes in MSD prevention: the complete type (n=17), the shortened type (n=16), and the turnkey type (n=14). These three groups of intervention processes were differentiated by their approaches and their contexts of application. The result was important differences in the changes implemented. Because of the variability in intervention processes and possible impacts on MSD prevention, a proposal to "delimit" these processes so as to improve their effectiveness is presented.

Perception and biomechanics data in a manual handling task: a comparative study.

This paper explores the use of subjective perception tasks and its correlations with biomechanical data in the evaluation of manual material handling. Three main dimensions were considered for perception: physical regroups sensations issued from a specific body area; operative regroups feelings related to the execution of the task; and performance regroups feelings that involve a judgement on the execution or reflect overall sensations. The following questions were then explored. To what extent are perception data related to biomechanics data? Do both approaches lead to similar conclusions or interpretations when effect of practice, format and off-centre were tested? How can they complement one another? The task consisted of transferring 50 series of three 15 kg loads in order to verify the impact of free practice, format (box/cylinder) and load centre of gravity position. Eleven subjects rated perception on a CR-10 scale (Borg 1982) after each series. The session was completed with an interview on perception. The net resulting moment was systematically found to be the best correlated with data perception. While all physical and performance items corresponded in various ways to biomechanics data, perceptions associated with operative dimension appeared to be less related with biomechanical data. As regards the impact of practice, format and off-centre, both approaches would lead to the same conclusions, except for the effect of the off-centre. Verbal data add rational information about how or why perception can or cannot be reflected in biomechanics data. How both approaches can be matched more closely in manual handling is discussed.