RESUMEN
Weakly agglomerated nanoparticles of (Ho1-xLax)2O3 solid solutions were synthesized with the help of a self-propagating high-temperature synthesis (SHS). The nanopowders were studied by a simultaneous thermal analysis (TG-DSC), X-ray diffraction (XRD), BET and FT-IR spectroscopy methods. Changes of the particles morphology after annealing at different temperatures and ball milling were investigated by a scanning electron microscopy (SEM) and a dynamic light scattering (DLS) method. It was found that annealing at a temperature of 900 °C in air and ball milling of the SHS nanopowders allow obtaining rounded shape particles with a mean diameter of about 20 nm and C-type cubic crystal structure. Up to 10 mol.% of the lanthana was shown to dissolve in the holmium oxide nanoparticles.
RESUMEN
The method of self-propagating high-temperature synthesis of submicron powders with subsequent vacuum sintering was used to produce a series of optical ceramics based on dysprosium oxide (DyxY0.95-xLa0.05)2O3, where x=0.7, 0.85, and 0.9. The influence of ceramics composition on optical transmission of the obtained samples was investigated. The studied materials had several transparency windows in the visible 500-730 nm, near-IR 1900-2300 nm, and mid-IR 3500-7500 nm ranges. The dependence of the Verdet constant on wavelength in the 400-1940 nm range was measured for each ceramics composition, and analytical approximations were obtained. When Y and La dopants were used, the Verdet constant depended linearly on the concentration of Dy3+ ions, and its value in the visible wavelength range was about twice that of the analogous value for a terbium gallium garnet crystal. The high transmission and relatively high Verdet constant make the produced materials highly promising for fabricating Faraday devices for Tm3+ and Ho3+ lasers and for lasers emitting in the visible spectrum.
