Smart supramolecular photoresponsive gelator with long-alkyl chain azobenzene incorporated sugar derivatives for recycling aromatic solvents and sequestration of cationic dyes.

Phase-selective gelation of low molecular-weight photoresponsive organogelator possessing long aliphatic chain azobenzene sugar derivatives and its applications in the recycling of aromatic solvents and also the removal of cationic dyes is reported. Very low critical gelation concentration (CGC) in aromatic solvents implies that it acts as a very good gelator. The photoinduced gel-to-sol transition was attained by irradiation with UV light at 350 nm. These organogels work as a selective adsorbent for efficiently removing cationic dyes from individual aqueous dye solutions and in a mixture of cationic and anionic dye solutions show more than 95% removal within 12 h. These insights indicate that these sugar derivatives could be exploited in implementing smart materials for environmental remediation.

Insights into a novel class of azobenzenes incorporating 4,6-O-protected sugars as photo-responsive organogelators.

A novel class of 4,6-O-butylidene/ethylidene/benzylidene ß-d-glucopyranose gelator functionalized with photo-responsive azobenzene moieties were designed and synthesized and also characterized using different spectral techniques. These azobenzene-based organogelators can gel even at lower concentrations (critical gelation concentration - 0.5% and 1%). A morphological study of the gels shows one-dimensional aggregated bundles and helical fibres. The main driving force for the self-assembly is through cooperative interactions exhibited by the different groups viz., sugar hydroxyl (hydrogen bonding interaction), azobenzene (aromatic π-π interaction) and alkyl chain of the protecting group (van der Waals interaction).