Updated database on natural radioactivity in building materials in Europe.

The paper presents the latest collection of activity concentration data of natural radionuclides (226Ra, 232Th and 4 K) in building materials. This database contains about 24200 samples of both bulk materials and their constituents (bricks, concrete, cement, aggregates) and superficial materials used in most European Union Member States and some European countries. This collection also includes radiological information about some NORM residues and by-products (by-product gypsum, metallurgical slags, fly and bottom ashes and red mud) which can be of radiological concern if recycled in building materials as secondary raw materials. Moreover, radon emanation and radon exhalation rate data are reported for bricks and concrete.

Estonian waterworks treatment plants: clearance of residues, discharge of effluents and efficiency of removal of radium from drinking water.

Considerable levels of radium were detected in a certain fraction of the Estonian drinking water supply network. Some of these waterworks have treatment systems for the removal of (mainly) iron and manganese from drinking water. Three of these waterworks and another one equipped with a radium removal pilot plant were examined, and a specific study was conducted in order to assess the environmental compatibility of effluents and residues produced in the plants. (226)Ra and (228)Ra activity concentrations were analysed in both liquid (backwash water) and solid (sand filter and sediment) materials to evaluate their compliance, from the radiological point of view, with current Estonian legislation and international technical documents that propose reference levels for radium in effluents and residues. Also with regard to water treatment by-products, a preliminary analysis was done of possible consequences of the transposition of the European Basic Safety Standards Draft into Estonian law. Radium removal efficiency was also tested in the same plants. Iron and manganese treatment plants turned out to be scarcely effective, whilst the radium mitigation pilot plant showed a promising performance.

Natural radioactivity in building material in the European Union: robustness of the activity concentration index I and comparison with a room model.

Using a wide database collected in the last 10 years, the authors have calculated the activity concentration index I for many building materials in the European Union. Suggested by a European technical guidance document, the index I has recently been adopted as a screening tool in the proposal for the new Euratom basic safety standards directive. The paper analyses the possible implications of the choice of different parameters for the computation of index I, i.e. background to be subtracted, dose criteria, etc. With the collected data an independent assessment of gamma doses was also made with an ISS room model, choosing reasonable hypotheses on the use of materials. The results of the two approaches, i.e. index I and a room model, were compared.

Natural radioactivity in building materials in the European Union: a database and an estimate of radiological significance.

The authors set up a database of activity concentration measurements of natural radionuclides (²²6Ra, ²³²Th and 4°K) in building material. It contains about 10,000 samples of both bulk material (bricks, concrete, cement, natural- and phosphogypsum, sedimentary and igneous bulk stones) and superficial material (igneous and metamorphic stones) used in the construction industry in most European Union Member States. The database allowed the authors to calculate the activity concentration index I--suggested by a European technical guidance document and recently used as a basis for elaborating the draft Euratom Basic Safety Standards Directive--for bricks, concrete and phosphogypsum used in the European Union. Moreover, the percentage could be assessed of materials possibly subject to restrictions, if either of the two dose criteria proposed by the technical guidance were to be adopted.

Radium isotopes in Estonian groundwater: measurements, analytical correlations, population dose and a proposal for a monitoring strategy.

In some areas of Estonia, groundwater contains a significant number of natural radionuclides, especially radium isotopes, which may cause radiation protection concern depending on the geological structure of the aquifer. Indeed, the parametric value of 0.1 mSv y⁻¹ for the total indicative dose established by European Directive 98/83/EC, adopted as a limit value in Estonian national legislation, is often exceeded. A Twinning Project between Estonia and Italy was carried out within the framework of the Estonian Transition Facility Programme, sponsored by the European Union. Its aims were to assess the radiological situation of Estonian groundwater and related health consequences. The first step was a study of Estonian aqueducts and the population served by them, and a thorough analysis of the radiological database for drinking water, from which the relevant effective doses for the population were obtained. Particular attention was devoted to doses to children and infants. Correlations between the chemical parameters were investigated, in order to suggest the best possible analytical approach. Lastly, a monitoring strategy, i.e. sampling points and sampling frequencies, was proposed.

A preliminary intercomparison of gamma-ray spectrometry on building materials.

A preliminary intercomparison on gamma-ray spectrometry determination of natural radionuclides in building materials was carried out in 1999-2002. Samples measured were fly ash, sand and tuff. Laboratories used different experimental equipment and procedures. Corrections for blank, spectral interference, self-absorption and coincidence summing effects were applied in most cases. The agreement between results was within 15-20%, most often within the reported uncertainties. Several general conclusions can be drawn regarding procedures correctness, uncertainty budget, secular equilibrium condition, and radionuclide representativeness in each natural series. Further studies are needed to draw more specific conclusions.

Radioactivity in building materials: room model analysis and experimental methods.

First, models (room models) published in the international literature allowing the exposure to gamma radiation indoors due to building materials to be assessed are reviewed and discussed. For one of them, a sensitivity analysis concerning the effect of changing the parameters (e.g. dimensions of the room, thickness and density of the walls, etc.) used in calculations is performed. Second, a method is proposed for calculating the activity concentration in the walls of a room using: (a) the measured absorbed dose rate in air in the room; (b) the contributions of natural radionuclides (238U, 232Th and 40K) to the absorbed dose rate in air assessed by means of gamma spectrometry indoors; and (c) the specific dose rate (nGy h(-1) per Bq kg(-1)) of natural radionuclides, for the chosen room geometry, calculated with the room model.

Experimental and measurement issues in natural radioactivity.

The paper deals with some open experimental problems in the field of natural radioactivity. Its aim is to stimulate discussion on the type of research efforts needed in the field and to be planned for the future. The review, which makes no claims to completeness. analyses some issues in gamma spectrometry of natural radionuclides, and the measurement of natural radioactivity in non-nuclear industries and of 222Rn and 220Rn concentration in air.

Prenatal exposure to ionizing radiation: sources, effects and regulatory aspects.

Knowledge and awareness of physicians and the general public concerning the risks of prenatal exposure to ionizing radiation are important when developing a correct attitude to ionizing radiation. This is particularly important in the justification of medical diagnostic exposure of pregnant women and in case of possible accidents. The present paper reviews the most recent data on the effects of prenatal exposure to ionizing radiation reported in the scientific literature and in documents of international organizations dealing with this subject. Potentially significant exposure for women of childbearing age in medical diagnostics, working conditions and environmental contamination following the Chernobyl accident are reported. Some examples of doses associated with medical exposure in the course of diagnostic examinations with X-rays and radiopharmaceuticals, and occupational exposure in workplaces are given. Lastly, the regulatory aspects of the European Union directives and the Italian legislation on medical and occupational exposure of women during pregnancy or in reproductive age are reviewed.

[The Chernobyl incident: emergency management in Italy and other European countries]. / Incidente di Chernobyl: gestione dell'emergenza in Italia e in altri paesi europei.

Several measures were adopted by European countries in the aftermath of the Chernobyl accident. In this paper these measures are reviewed and the European Communities initiatives for food marketing and exports are analyzed, together with the reference levels for radioactive concentration in the main food matrices chosen in different European countries in the very few days after the accident. A particular attention has been devoted to the emergency management in Italy, outlining exhaustively the laws enforced at the time of the accident and explaining how the reference levels for food contamination were chosen. Finally, a tentative balance about emergency management in Italy is struck and some questions are raised about the commitments undertaken or to be undertaken by international institutions.

Results of the representative Italian national survey on radon indoors.

A representative national survey on population exposure to radon in Italian dwellings was carried out from 1989 to 1994, with the co-operation of the National Health Service. The measurements were performed by 19 Regional Laboratories, all using the same techniques and protocols. A stratified, two-stage sampling procedure was used to sample families. The sampled families were approached door-to-door to maximize response. To optimize the quality of the measurements, two dosimeters, each containing two alpha track detectors, were placed together in one room (typically the bedroom) for two consecutive 6-mo periods. The distribution of annual radon concentration was derived from measurements in 4,866 dwellings. The average value is 75 Bq m(-3) and the fractions of dwellings above the reference levels of 150, 200, 400, and 600 Bq m-3 are 8.7%, 4.7%, 1.0%, and 0.2%, respectively. The geometric mean is 57 Bq m-3 while the geometric standard deviation is 2.0. The average values in the Italian Regions fall within the 20-120 Bq m-3 range. When the average radon concentration is examined vs. story, building materials seem to play a significant role. The average lifetime risk of lung cancer for chronic radon exposure of Italian population at home would be about 5 x 10(-3), using the risk factor proposed by the ICRP in 1993.

Caesium contamination in human milk and transfer factor from diet.

A study on caesium contamination in human milk, as a consequence of the Chernobyl fallout, was conducted in 1989 on a group of women from one of the areas of northern Italy most heavily affected by the radioactive fallout. Their diet was studied, and the caesium intake was calculated by using the mean food activity concentration in that area. The caesium transfer factor was evaluated both as the ratio of caesium concentration in mother's milk to the daily intake, and by using a simplified milk compartment model.

Radioactivity in human milk.

A brief introduction outlines the sources of radionuclides in the environment, their diffusion and transfer to different environmental compartments and their pathways to individuals; definitions of the main quantities and measurement units used in the study are included. A review is given on published data concerning the radioactive contamination of human milk after the Chernobyl accident. The authors' investigation on breast milk contamination in Italy in the same period is discussed together with an examination of the natural radioactive content. Finally, possible future developments and prospects of the research on this issue are explored.

Radon and radon daughter evaluation in a natural radioactivity survey indoors.

An indoor survey in order to estimate the population exposure in five towns of an Italian Region is presented. A particular methodology for the campaign was planned and is being applied. Gamma spectrometry of building materials, exposure rate measurements indoors and outdoors and radon concentration measurements indoors were taken with different techniques. A correlation was found between mean gamma exposure rate and mean radon concentration in the houses investigated. An evaluation of mean effective dose equivalents for the inhabitants of the five towns is reported.

Radioactivity connected with coal burning.

The enhanced environmental radioactivity resulting from the operation of a 72 MWe brown coal-fired power plant in central Italy is considered. A source-related control procedure is suggested. The calculated values for the atmospheric dispersion of radioactive effluents and the results of some measurements on brown coals, ash, environmental samples and gamma-exposure levels performed at representative points are reported.

Feasibility study of radiation protection guidelines in the use of building materials in the Italian dwellings.

The Italian situation concerning the indoor radiation exposure is examined. A tentative comparison of the risk connected with radon and radon daughter indoor exposures and other every day life risks is made. The social economic impact of imposing possible constraints on home building industry is also discussed.