Anomalous, dielectrophoretic transport of molecules in non-electrolytes.

The electric field (E-field) dielectric polarization-based separations mechanism represents a novel method for separating solutions at small length scales. An E-field gradient with a maximum strength of 0.4 MV/m applied across a 10 µm deep channel is shown to increase the concentration inside the low E-field region by ≈ 40% relative to the high E-field region. This concentration change is two orders of magnitude higher than the estimated change predicted using the classical equilibrium thermodynamics for the same E-field. The deviation between the predicted and the experimental results suggests that the change in volumetric E-field energy with solute concentration is insufficient to explain this phenomenon. The study also explores the effect of varying strength of E-field and frequency of supplied voltage on the dielectric polarization-based separation efficiency. While the increase in the former increases the separation efficiency, the increase in the latter reduces the degree of concentration change due to ineffective charging of the electrodes.

Thermodynamic Analysis of Capillary and Electric Field Effects on Liquid-Vapor Equilibrium: A Study on the Water-Ethanol Mixture.

This study investigates phase equilibrium manipulation in nonideal mixtures through a combined capillary and external electric field approach. Utilizing thermodynamic principles, an expression is established for estimating the equilibrium liquid mole fraction in a confined system subjected to a localized electric field within a capillary that is filled with a liquid phase in equilibrium with its vapor counterpart. Applied to a water-ethanol system, the model suggests large shifts in the equilibrium liquid mole fraction of water due to the electric field and capillary effects. These findings reveal that while the capillary's influence remains negligible for radii exceeding 10 nm, capillaries of smaller dimensions, when exposed to electric fields of around 300 MV/m, can amplify the equilibrium liquid water mole fraction by up to 55%. This suggests the potential for phase equilibrium control through larger capillaries and lower electric fields, while intriguing complexities arise at very small radii.

Dielectric polarization-based separations in an ionic solution.

A novel non-electrophoretic, electric field-based separation mechanism capable of transporting ions based on their dielectric properties is presented here for the first time. Though this polarization-based mechanism behaves similarly to dielectrophoresis, the separation mechanism is remarkably very efficient at small length scales compared to any dielectrophoretic separation mechanism for particles. For an applied electric field of strength as low as ∼0.75 MV m-1 across a 100 µm channel, the working solute - sodium fluorescein - is shown to decrease in its concentration by ≈20% in electric field region relative to the non electric field region. The existing macroscopic theoretical models like electrohydrodynamics and equilibrium thermodynamics are shown to underestimate the concentration change by two orders of magnitude for the same electric field strength. This surprisingly large difference between theory and experimental results suggests that the electric field-based equilibrium thermodynamic model lacks a key physics.

Thermodynamic Study of the Electric Field Effect on Liquid-Vapor Mixture at Equilibrium: An Analysis on a Water-Ethanol Mixture.

In this paper, the effect of electric fields on phase equilibria through polarization is investigated. A relation is derived for the chemical potential of a system, where the electric field is localized over a liquid phase mixture in equilibrium with a vapor phase mixture. This relation is then applied to a water-ethanol mixture to explore the effect of polarization-based electric fields on the liquid phase composition. It is observed that the quadratic dependence on electric field strength produces little effect below field strengths of approx. 10 MV/m. However, above this field strength, the mole fraction of water in the liquid phase grows rapidly, increasing by a factor of 8 for a water vapor phase fraction of 0.2 and a field strength of 500 MV/m, which approaches the dielectric breakdown strength of water. Nonetheless, this field strength could be achievable with microfluidic experimental setups.

Novel Raman Spectroscopy Method for Solutions in Uniform, High-Strength Electric Field.

A novel method of measuring the influence of high electric fields on the Raman scattering of fluids is introduced, which can help understand various interactions of a fluid with the high electric field. The microfluidic chip can impose highly controlled, uniform electric fields across the measurement volume with blocked electrodes, eliminating spurious reactions at the electrode surface. The developed methodology and the experimental setup are utilized to examine the effect of the electric field on three of the stretching vibrations of ethanol in water-ethanol mixtures with varying concentrations of ethanol and effective electric fields up to 1.0MV/m. The increase in the electric field is seen to broadly decrease the intensity of Raman scattering due to a decrease in the polarizability of the ethanol molecules. Although this effect is uniform for all water-ethanol mixtures, it reduces in mixtures with high weight-fractions of water because of the already reduced polarizability of an ethanol molecule due to hydrogen bonding. The combined effect of hydrogen bonding and increase in temperature due to the alternating high electric field even results in an increase in the magnitude of peak intensity for relatively low-weight fractions of ethanol.

Effects of Frequency and Joule Heating on Height Rise between Parallel Electrodes with AC Electric Fields.

High strength AC electric fields generate a body force on a dielectric medium confined between two electrodes. The body forces are due to two factors. First is the variation in permittivity across an interface such as liquid-air present between the electrodes. The second is a change in the dielectric property of the medium due to a variation in the thermodynamic properties such as temperature. The height rise of a dielectric medium between two electrodes is one of the consequences of these electrical body forces and is used here as a comparatively simple way to study these forces. In an aqueous solution with finite conductivity, the effects of the frequency of the supplied voltage source and the temperature change due to Joule heating on height rise have never been studied in this context. This study focuses on systems where the contributions of surface forces are negligible and highlights the interplay between solution conductivity, applied electric field, and the solution height/temperature behavior. Using a generic thermodynamic model for an aqueous solution under the application of an alternating current electric field, it is shown that for low conductivity solutions the resulting temperature and height rise change weakly with the applied field frequency and strongly with the applied electric field. For higher conductivity solutions, the behavior becomes more complex with respect to the electric field strength. As compared to Pellat's original model, the height rise varies from strongly suppressed to enhanced.