1.
Chem Commun (Camb)
; 47(1): 406-8, 2011 Jan 07.
Artículo
en Inglés
| MEDLINE
| ID: mdl-20852769
RESUMEN
The m-terphenyl isocyanides CNAr(Mes2) and CNAr(Dipp2) support five-coordinate, isocyanide/carbonyl monoanions of manganese. For CNAr(Dipp2), a bis-isocyanide anion is available that is remarkably well behaved upon reaction with electrophiles. Most notable is the formation of an unprecedented chloride-substituted metallostannylene.