Rhinology Future Debates, an EUFOREA Report.

The first Rhinology Future Debates was held in Brussels in December 2016, organized by EUFOREA (European Forum for Research and Education in Allergy and Airways diseases). The purpose of these debates is to bring novel developments in the field of Rhinology to the attention of the medical, paramedical and patient community, in a highly credible and balanced context. For the first time in Rhinology, a peer to peer scientific exchange with key experts in the field of rhinology and key medical colleagues from leading industries let to a brainstorming and discussion event on a number of hot issues in Rhinology. Novel developments are presented by key experts from industry and/or key thought leaders in Rhinology, and then followed by a lively debate on the potential positioning of new developments in care pathways, the strengths and weaknesses of the novel development(s), and comparisons with existing and/or competing products, devices, and/or molecules. As all debates are recorded and distributed on-line with limited editing (www.rhinology-future.com), EUFOREA aims at maximizing the education of the target groups on novel developments, allowing a critical appraisal of the future and a more rapid implementation of promising novel tools, techniques and/or molecules in clinical practise in Europe. The next Rhinology Future debate will be held in Brussels in December 2017.

Rotationally resolved vacuum ultraviolet pulsed field ionization-photoelectron vibrational bands for HD+(X 2Sigmag+,v+=0-20).

The authors have obtained rotationally resolved vacuum ultraviolet pulsed field ionization-photoelectron (vuv-PFI-PE) spectrum of HD in the photon energy range of 15.29-18.11 eV, covering the ionization transitions HD+(X 2Sigmag+,v+=0-21,N+)<--HD(X 1Sigmag+,v"=0,J"). The assignment of rotational transitions resolved in the vuv-PFI-PE vibrational bands for HD+(X 2Sigmag+,v+=0-20) and their simulation using the Buckingham-Orr-Sichel (BOS) model are presented. Rotational branches corresponding to the DeltaN=N+-J"=0, +/-1, +/-2, +/-3, and +/-4 transitions are observed in the vuv-PFI-PE spectrum of HD. The BOS simulation shows that the perturbation of vuv-PFI-PE rotational line intensities due to near resonance autoionization is very minor at v+>or=5 and decreases as v+ is increased. Thus, the rotationally resolved PFI-PE bands for HD+(v+>or=5) presented here provide reliable estimates of state-to-state cross sections for direct photoionization of HD, while the rotationally resolved PFI-PE bands for HD+(v+<5) are useful data for fundamental understanding of the near resonance autoionizing mechanism. On the basis of the rovibrational assignment of the vuv-PFI-PE bands, the ionization energies for the formation of HD+(X 2Sigmag+,v+=0-20,N+) from HD(X 1Sigmag+,v"=0,J") and the vibrational constants (omegae, omegaechie, omegaeye, and omegaeze), the rotational constants (Be and alphae), the vibrational energy spacings, and the dissociation energy for HD+(X 2Sigmag+) are determined. As expected, these values are found to be in excellent agreement with high level theoretical predictions.