RESUMEN
Particulate matter less than 2.5 µm particle diameter (PM2.5) is the most significant environmental issue globally. PM2.5 is an integral component of air quality monitoring and management, human health, weather, climate, and epidemiological research. In this work, we investigate the seasonal variation in PM2.5 mass concentrations and the association between the sea-land breeze system and particulate matter in five coastal urban locations in India (Kolkata, Visakhapatnam, Chennai, Thiruvananthapuram, and Mumbai). The relative occurrence of high PM2.5 mass concentrations was the greatest during the winter season (December through February) while the relative occurrence of low PM2.5 mass concentrations was the greatest during the monsoon season (June through September). Amongst locations, Kolkata experiences the highest PM2.5 loading in winter while Thiruvananthapuram experiences the lowest PM2.5 loading in monsoon. Indo-Gangetic Plain (IGP) outflow onto the Bay of Bengal significantly impacts locations along the eastern coast of India with reduced impact from north (Kolkata) to south (Chennai). The sea-breeze component analysis revealed daily cycles of the sea-land breeze with varying magnitudes of the breeze between the different seasons. Overall, we found a negative association between the sea-land breeze magnitude and PM2.5 mass concentrations, implying that the weakened sea-land breeze may deteriorate air quality in coastal locations due to poor ventilation. The vertical profiles of aerosol extinction showed elevated aerosol layers within 1 km from the surface in almost all locations. The decreasing trend in the land-sea temperature contrast in coastal locations is expected to deteriorate air quality in coastal locations in the warming future. Nevertheless, critical analyses using ground-based remote sensing techniques are required for a better understanding the impact of sea-land breeze dynamics on air quality in coastal locations.
RESUMEN
India is highly vulnerable to air pollution in the recent decade, especially urban areas with rapidly growing urbanisation and industrialisation. Here, we present spatio-temporal variability of air pollutants at four distinct locations in Andhra Pradesh State of India. The mean concentrations of air pollutants were generally higher at Visakhapatnam site than Amaravati, Rajahmundry, and Tirumala sites. The mean concentration of particulate matter of diameter less than 2.5 µm (PM2.5) was higher at Visakhapatnam site (48.5 ± 27.3 µg/m3) by a factor of about 1.6 as compared to Tirumala site (29.5 ± 17 µg/m3). On the contrary, the mean concentrations of oxides of nitrogen (NOx, 70.3 ± 28.1 µg/m3) and ammonia (NH3, 20.5 ± 9.2 µg/m3) were higher at Tirumala by a factor of about 1.4 and 1.9, respectively, as compared to Visakhapatnam (49 ± 5 µg/m3 and 10.7 ± 5 µg/m3). This was mainly attributed to higher vehicular emissions at Tirumala site. PM2.5, carbon monoxide (CO), NOx, and sulfur dioxide (SO2) showed distinct seasonal variation, with higher concentrations in winter followed by post-monsoon, pre-monsoon and monsoon. The Concentration Weighted Trajectory analysis of PM2.5 based on 5-days backward air mass trajectories showed that all sites experienced northeast air mass flow indicative of the outflow from Indo-Gangetic Plain, particularly in the post-monsoon and winter seasons. The Continuous Wavelet Transform analysis further showed that higher variations in PM2.5 concentrations occurring at a regular interval from a week to 16 days at both Tirumala and Visakhapatnam sites, while weekly periods are dominant over Amaravati and Rajahmundry sites with 95% significance during post-monsoon and winter seasons. Overall, our results underline heterogeneity in air pollution emission sources and influx of pollutants from distant sources, which would be useful when formulating the policies and mitigation procedures for this region.
