Water Framework Directive programmes of measures: Lessons from the 1st planning cycle of a catchment in England.

The European Union's Water Framework Directive (WFD) required Member States to establish programmes of measures to achieve good water status formally by 2015, but on postponing the deadline by two six-year periods, by 2027 at the latest. With many Member States facing problems with developing such measures in the first planning cycle, and limited change in ecological status since the first river basin management plans were reported, we look at the implementation of the Directive in England, where only 17% of the surface water bodies were found at good status in 2015, a reduction of 4% since 2009. Using as a case study the Broadland Rivers catchment, we examine the measures taken for Cycle 1 and changes in the classifications of water body status, to investigate whether the way the measures were developed could have limited their potential to deliver WFD objectives. While the WFD was adopted to succeed and replace management practices targeting individually non-compliant element, findings indicate that little had changed in the way measures were developed. Although considerable progress has been made on the implementation of these measures, the limited progress in improving classifications demonstrates the limits of this approach and further makes the case for what the WFD was introduced for: the harmonised transposition of the Integrated River Basin Management paradigm, as the key for delivering good ecological status.

Integrated catchment management for reducing pesticide levels in water: Engaging with stakeholders in East Anglia to tackle metaldehyde.

In the agriculture intensive eastern region of England, plant protection products are widely applied to protect crops such as wheat and oilseed rape from pests and diseases, thus creating a risk of reaching nearby water courses through surface runoff. The EU Drinking Water Directive sets a stringent limit of 0.1 µg/l and 0.5 µg/l for individual and total pesticides respectively in treated potable water. However, peak metaldehyde levels have been persistently detected in raw water and reducing them to these limits has proven challenging and costly, in particular when using conventional treatment. In line with the EU Water Framework Directive, a more suitable approach and one adopted by the local water company, Anglian Water Services Ltd., would require moving towards mitigating pollution at source, preferably through participative action with multiple stakeholders in the agricultural industry. Initial findings demonstrate the potential of product substitution for reducing metaldehyde levels in surface waters. Reviewing Anglian Water's "Slug it Out" trial, we discuss key learnings derived from their experiences and make recommendations about the potential of the catchment approach to address the wider pesticide challenge.

The potential of using the Ecosystem Approach in the implementation of the EU Water Framework Directive.

The Ecosystem Approach provides a framework for looking at whole ecosystems in decision making to ensure that society can maintain a healthy and resilient natural environment now and for future generations. Although not explicitly mentioned in the Water Framework Directive, the Ecosystem Approach appears to be a promising concept to help its implementation, on the basis that there is a connection between the aims and objectives of the Directive (including good ecological status) and the provision of ecosystem services. In this paper, methodological linkages between the Ecosystem Approach and the Water Framework Directive have been reviewed and a framework is proposed that links its implementation to the Ecosystem Approach taking into consideration all ecosystem services and water management objectives. Individual River Basin Management Plan objectives are qualitatively assessed as to how strong their link is with individual ecosystem services. The benefits of using this approach to provide a preliminary assessment of how it could support future implementation of the Directive have been identified and discussed. Findings also demonstrate its potential to encourage more systematic and systemic thinking as it can provide a consistent framework for identifying shared aims and evaluating alternative water management scenarios and options in decision making. Allowing for a broad consideration of the benefits, costs and tradeoffs that occur in each case, this approach can further improve the economic case for certain measures, and can also help restore the shift in focus from strict legislative compliance towards a more holistic implementation that can deliver the wider aims and intentions of the Directive.

Open Air Laboratories (OPAL): a community-driven research programme.

OPAL is an English national programme that takes scientists into the community to investigate environmental issues. Biological monitoring plays a pivotal role covering topics of: i) soil and earthworms; ii) air, lichens and tar spot on sycamore; iii) water and aquatic invertebrates; iv) biodiversity and hedgerows; v) climate, clouds and thermal comfort. Each survey has been developed by an inter-disciplinary team and tested by voluntary, statutory and community sectors. Data are submitted via the web and instantly mapped. Preliminary results are presented, together with a discussion on data quality and uncertainty. Communities also investigate local pollution issues, ranging from nitrogen deposition on heathlands to traffic emissions on roadside vegetation. Over 200,000 people have participated so far, including over 1000 schools and 1000 voluntary groups. Benefits include a substantial, growing database on biodiversity and habitat condition, much from previously unsampled sites particularly in urban areas, and a more engaged public.

The influence of engineered Fe(2)O(3) nanoparticles and soluble (FeCl(3)) iron on the developmental toxicity caused by CO(2)-induced seawater acidification.

An embryo development assay using a common test organism, the edible mussel (Mytilus galloprovincialis), exposed to both Fe(2)O(3) nanoparticles and soluble FeCl(3) at 3 acidic pHs, has provided evidence for the following: (1) CO(2) enriched seawater adjusted to pH projections for carbon capture leakage scenarios (CCS) significantly impaired embryo development; (2) under natural pH conditions, no significant effect was detected following exposure of embryos to Fe, no matter if in nano- or soluble form; (3) at pH of natural seawater nano-Fe particles aggregate into large, polydisperse and porous particles, with no biological impact detected; (4) at pH 6 and 7, such aggregates may moderate the damage associated with CO(2) enrichment as indicated by an increased prevalence of normal D-shell larvae when nano-Fe was present in the seawater at pH 7, while soluble iron benefited embryo development at pH 6, and (5) the observed effects of iron on pH-induced development toxicity were concentration dependent.

Modelling the behaviour of mechanical biological treatment outputs in landfills using the GasSim model.

The pretreatment of the biodegradable components of municipal solid waste (MSW) has been suggested as a method of reducing landfill gas emissions. Mechanical biological treatment (MBT) is the technology being developed to provide this reduction in biodegradability, either as an alternative to source segregated collection or for dealing with residual MSW which still contains high levels of biodegradable waste. The compost like outputs (CLOs) from MBT plants can be applied to land as a soil conditioner; treated to produce a solid recovered fuel (SRF) or landfilled. In this study the impact that landfilling of these CLOs will have on gaseous emissions is investigated. It is important that the gas production behaviour of landfilled waste is well understood, especially in European member states where the mitigation of gaseous emissions is a legal requirement. Results of an experiment carried out to characterise the biodegradable components of pretreated biowastes have been used with the GasSim model to predict the long term emissions behaviour of landfills accepting these wastes, in varying quantities. The landfill directive also enforces the mitigation of potential methane emissions from landfills, and the ability of landfill operators to capture gaseous emissions from low emitting landfills of the future is discussed, as well as new techniques that could be used for the mitigation of methane generation.

Sustainable risk management of emerging contaminants in municipal wastewaters.

The presence of emerging contaminants in municipal wastewaters, particularly endocrine-disrupting compounds such as oestrogenic substances, has been the focus of much public concern and scientific attention in recent years. Due to the scientific uncertainty still surrounding their effects, the Precautionary Principle could be invoked for the interim management of potential risks. Therefore, precautionary prevention risk-management measures could be employed to reduce human exposure to the compounds of concern. Steroid oestrogens are generally recognized as the most significant oestrogenically active substances in domestic sewage effluent. As a result, the UK Environment Agency has championed a 'Demonstration Programme' to investigate the potential for removal of steroid oestrogens and alkylphenol ethoxylates during sewage treatment. Ecological and human health risks are interdependent, and ecological injuries may result in increased human exposures to contaminants or other stressors. In this context of limiting exposure to potential contaminants, examining the relative contribution of various compounds and pathways should be taken into account when identifying effective risk-management measures. In addition, the explicit use of ecological objectives within the scope of the implementation of the EU Water Framework Directive poses new challenges and necessitates the development of ecosystem-based decision tools. This paper addresses some of these issues and proposes a species sensitivity distribution approach to support the decision-making process related to the need and implications of sewage treatment work upgrade as risk-management measures to the presence of oestrogenic compounds in sewage effluent.

The management of household hazardous waste in the United Kingdom.

Waste legislation in the United Kingdom (UK) implements European Union (EU) Directives and Regulations. However, the term used to refer to hazardous waste generated in household or municipal situations, household hazardous waste (HHW), does not occur in UK, or EU, legislation. The EU's Hazardous Waste Directive and European Waste Catalogue are the principal legislation influencing HHW, although the waste categories described are difficult to interpret. Other legislation also have impacts on HHW definition and disposal, some of which will alter current HHW disposal practices, leading to a variety of potential consequences. This paper discusses the issues affecting the management of HHW in the UK, including the apparent absence of a HHW-specific regulatory structure. Policy and regulatory measures that influence HHW management before disposal and after disposal are considered, with particular emphasis placed on disposal to landfill.

Calculating human exposure to endocrine disrupting pesticides via agricultural and non-agricultural exposure routes.

Endocrine Disrupting Chemicals (EDCs) are of increasing concern because of their potential impacts on the environment, wildlife and human health. Pesticides and some pesticide metabolites are an important group of EDC, and exposure to them is a poorly quantified source of human and environmental exposure to such chemicals generally. Models for estimating human exposure to Endocrine Disrupting (ED) pesticides are an important risk management tool. Probabilistic models are now being used in addition to deterministic ones in all areas of risk assessment. These can provide more realistic exposure estimates, because they are better able to deal with variation and uncertainty more effectively and better inform risk management decisions. Deterministic models are still used and are of great value where exposure data are scarce. Models or groups of models that provide holistic human ED pesticide exposure estimates are required if the risk posed to humans by ED pesticides is to be better assessed. Much more research is needed to quantify different exposure routes such as exposure from agricultural spray drift and the medical use of pesticides to develop such models. Most available probabilistic models of human exposure were developed in the USA and require modification for use elsewhere. In particular, datasets equivalent to those used to create and apply the American models are required. This paper examines the known routes of human pesticide exposure with particular reference to ED pesticides and their quantification as unlike pesticides generally, many ED pesticides are harmful at very low doses, especially if exposure occurs during sensitive stages of development, producing effects that may not manifest for many years or that affect descendants via epigenetic changes. It also summarises available deterministic and probabilistic models commonly used to calculate human exposure. The main requirement if such models are to be used in the UK is more quantitative data on the sources and pathways of human ED pesticide exposure.