Impacts of operational conditions on oxygen transfer rate, mixing characteristics and residence time distribution in a pilot scale high rate algal pond.

Different combinations of operational parameters including water level, paddle rotational speed and influent flow rate were applied to investigate their impacts on mixing characteristics, residence time distribution and gas transfer rate in a pilot-scale high rate algal pond. In closed condition, the paddle rotational speed had a positive correlation with the Bodenstein number (Bo), water velocity and oxygen volumetric mass transfer coefficient (kLaO2) while increasing water level generated a negative impact on these parameters, although the impact of water level on water linear velocity was small. The amplification effect of water level and paddle rotational speed on the sensitivity of Bo and kLaO2 should be noticed. Moreover, paddle rotational speed had more impact on kLaO2 than on Bo. The study in open condition indicated that effective volume fraction had a positive correlation with inlet flow rate and negative correlation with paddle rotation, while the opposite was observed in the case of Peclet number. The impact of water level variation on these parameters was unclear. Both water level and paddle rotational speed had negative impacts on the short-circuiting index, while no correlation was observed when varying inlet flow rate. In this study, the optimal operational conditions included low water level (0.1 m) and medium paddle rotational speed (11.6 rpm).

Micropollutants removal and storage efficiencies in urban stormwater constructed wetland.

Stormwaters is identified as a major source of pollution in waterbodies. Particularly, heavy metals (HMs) and Polycyclic Aromatic Hydrocarbons (PAHs) in stormwater are highly toxic compounds for living organisms. To limit the impact of these micropollutants on hydrosystems quality, stormwater constructed wetlands (SCWs) have been built worldwide. This study aims to i) assess the efficiency of a SCW that combines a sedimentation pond followed by a vertical flow sand filter in urban area (Strasbourg 67, France) and ii) determine micropollutants storage in water and soils during dry periods. Stormwater quality was analysed during 13 sampling sessions and the SCW storage ability during dry period was highlighted. The rainfall events sampled are characterized by very high variability: dry periods lasted from 5 h to 10 d, rain durations varied from 15 min to 22 h and the return periods were between 2 and 4 wk. and 3-6 mo. The inflow stormwater included a high amount of Zn and a variety of PAHs. Cu, Zn and some PAHs concentrations are impacted by hydrological characteristics. During a rain event, the filter catches the majority of both dissolved and particulate micropollutants and the mobilization of particulate micropollution by incoming flow decreases pond removal efficiency. The treatment removal efficiency varied from 50% (naphthalene) to 100% (particulate Zn). Four HMs (Co, Cu, Pb, Zn) were found in the pond and seven (Cd, Cr, Co, Cu, Ni, Pb, Zn) in the filter during a dry period at high concentrations compared to their occurrence in rainfall. A release of HMs from the filter sand to the interstitial water is highlighted. In water and the soil matrix, PAHs occurrence was consistent with their water solubility, logKow and logKoc.

Urban stormwater treatment by a constructed wetland: Seasonality impacts on hydraulic efficiency, physico-chemical behavior and heavy metal occurrence.

Urban stormwater affects the general quality of water bodies because of their hydraulic and pollution impacts. Stormwater discharges modify stream water flow and are reported as major source of heavy metals (HMs) in urban streams. Stormwater Constructed Wetlands (SCWs) have been built worldwide to manage stormwater before it is released into hydrosystems. In SCWs, stormwater is stored, evaporated and sometimes infiltrated. Subsequently, the HMs in stormwater can be settled, filtered and bioassimilated by microorganisms. Hence, the efficiency of SCWs in managing stormwater depends on climatic conditions, which change with season. The aim of this study was to investigate the impacts of seasonality on the performance of a 6-year-old constructed wetland made with a pond followed by a vertical flow filter. Hydraulic performance of, physico-chemical behaviour of, and HM mitigation via the SCW were evaluated using over 3 years of monitoring (2015-2017) data. Only 35% of the rain events that occurred in the studied catchment caused a discharge into the pond and 17% into the filter. The SCW was mostly supplied with stormwater in spring and summer and provided peak flow attenuation from 97 to 100% in all seasons. Variations in physico-chemical parameters (temperature, dissolved oxygen, pH, and redox potential) were caused by seasonal and dry/wet weather changes. They were greater in the pond than in the filter, which buffers these variations. The high physico-chemical variations in the pond probably had a deleterious effect on HM storage in the pond sediments. Finally, hydrologic and physico-chemical conditions (antecedent dry period length, pH, redox potential) affected the HM concentrations along the SCW. However, HM removal efficiencies were >97% in all seasons.

Quantifying mobile and immobile zones during simulated stormwater infiltration through a new permeable pavement material.

We have designed a new eco-material for use in permeable pavements in view to ensuring the sustainable management of stormwater in urban areas. The specific characteristic of this material is that it allows the infiltration of rainfall, storing the infiltrated water and trapping the pollutants carried by runoff such as engine oil and heavy metals. This new material is composed of a mixture of crushed concrete , resulting from inert construction waste, and organic material (compost). We performed tracing experiments in view to monitor the flow of the water within this material in order to study its hydrodynamics under heavy rainfall (rain with a return period of 10 years). The experimental results revealed preferential flows due to the heterogeneity of the material and liable to act as a major vector for the mobility of the pollutants transported within the material by stormwater. The work presented in this article consists in quantifying these preferential flows by determining their water contents in mobile (θm) and immobile (θim) water during infiltration. To do this, we used the (NON-EQUILIBRIUM Convection-Dispersion Equation) model, in order to evaluate mobile and stagnant zones in the framework of tracing experiments.

Modelling aerobic biodegradation in vertical flow sand filters: impact of operational considerations on oxygen transfer and bacterial activity.

Oxygen renewal, as a prominent phenomenon for aerobic bacterial activity, deeply impacts Vertical Flow Constructed Wetland (VFCW) treatment efficiency. We introduce a multiphase model able to simulate multi-component transfer in VFCWs. It is based on a two-phase flow module, and a transport module. The flow module can quantify both water and air velocities throughout the filter during operation. The reactive transport module follows dissolved and gaseous oxygen concentrations, and the transport of solutes such as ammonium and readily biodegradable COD (Chemical Oxygen Demand). The consumption of components is governed by Monod-type kinetics. Heterotrophic and autotrophic bacteria, which are responsible for COD and ammonium degradation respectively, are part of the model components. The kinetics are based on the Constructed Wetlands Model 1. The results from the simulation tool were compared with existing experimental data, and two kinds of operation with VFCWs were investigated. The authors show strong interplay between oxygen renewal and bacterial consumption in case of sequential batch feeding with transient flooding of surface. Oxygen renewal is essentially convection mediated in such operation, while convection is not significant in non-flooding operation. Simulated bacterial patterns are impacted by the operation, both quantitatively and spatially. From a modelling point of view, the authors highlight some limitations of the biological model: the description of bacterial lysis processes needs to be enhanced, as well as ammonium adsorption to organic matter.

Diphasic transfer of oxygen in vertical flow filters: a modelling approach.

Oxygen renewal, as a prominent phenomenon for aerobic bacterial activity, deeply impacts vertical flow constructed wetland (VFCW) treatment efficiency. The authors introduce a multiphase model able to simulate oxygen transfer in VFCWs. It is based on a two-phase flow module, and a transport module. The transport module is able to deal with convection/diffusion phenomena, inter-phase (air-water) mass exchange, and first-order kinetics. The first results displayed for the air phase allow us to draw the following ideas on the design of vertical filters. The ponding phenomenon is more efficient for oxygen renewal than non-ponding batch loading: it provides a higher value, sooner, and deeper in the filter. In non-colonised filters and for standard batch loading, oxygen convection in the air phase is predominant for oxygen renewal. The seepage front limits oxygen renewal through the bottom of the filter and leads to an insufficient oxygen concentration on the lowest part of the filter.

Two-phase flow modelling for oxygen renewal estimation in vertical flow filter: luxury or necessity?

Scientists and practitioners exhibit an increasing interest on effluent transfer and degradation modelling in Vertical Flow Sand Filters (VFSF) and Vertical Flow Constructed Wetland (VFCW). Modelling software used to this purpose is mainly monophasic: in the unsaturated zone, only water flow is taken into account and air phase influence is assumed to be negligible. In hydrology, many studies have point out the limitations of this assumption in order to quantify air phase movement but little has been done in the modelling of vertical flow filter. Despite its complexity, two-phase flow modelling allows to overcome these difficulties. In this work, we describe the complex air and water flows in the particular case of vertical flow filter fed intermittently using both numerical and experimental results. Complete different behaviour is observed depending on ponding occurs or not. If it does, flow is clearly influenced by air entrapment which is responsible of a reduction of the infiltration speed and of the drainage of a part of the water kept at the interface between the sand and the drainage layer. Finally, we study the dependency of oxygen income by convection on hydraulic load and compare numerical results with experimental results obtained on oxygen consumption.