RESUMEN
Experimental proof is presented for a hitherto undetected solid-state reaction between the solar cell material Cu(2)ZnSn(S,Se)(4) (CZTS(e)) and the standard metallic back contact, molybdenum. Annealing experiments combined with Raman and transmission electron microscopy studies show that this aggressive reaction causes formation of MoS(2) and secondary phases at the CZTS|Mo interface during thermal processing. A reaction scheme is presented and discussed in the context of current state-of-the-art synthesis methods for CZTS(e). It is concluded that alternative back contacts will be important for future improvements in CZTS(e) quality.
RESUMEN
We report the demonstration of two-tone optical heterodyne spectroscopy with a tunable lead-salt diode laser. Using high-frequency modulation of the diode-laser injection current, we demonstrated a detection-sensitivity limit of 1 x 10(-5) to differential absorption from Doppler-broadened NH(3) lines in the 930-cm(-1) region. In our experiment, this limit was set by preamplifier noise and the low quantum efficiency of the photodetector. A substantial increase in sensitivity should be possible by using an improved detector, an improved preamplifier, and higher optical power.
RESUMEN
Optical mixing of waves separated in frequency by many gigahertz can be accomplished by allowing the waves to mix in a nonlinear medium to generate microwave difference frequencies. This basis for high-bandwidth optical mixers is demonstrated by mixing optical frequencies approximately 4 GHz apart of a pulsed dye-laser beam at approximately 660 nm in a LiTaO(3) crystal to produce readily detectable microwave power at approximately 4 GHz.
RESUMEN
We report the first known demonstration of frequency-modulation spectroscopy outside the visible spectral region. Specifically, we report the use of second-harmonic generation on a frequency-modulated visible dye-laser beam to produce a frequency-modulated ultraviolet beam that is used to observe the Na 3S ? 4P absorption at 3302 A.
