Performance of the multi-U-style structure based flow field for polymer electrolyte membrane fuel cell.

The design of the reactant gas flow field structure in bipolar plates significantly influences the performance of proton exchange membrane fuel cells (PEMFCs). In this study, we introduced four innovative U-shaped flow field designs, namely: In-Out Multi-U, Out-In Multi-U, Distro In-Out Multi-U, and Distro Out-In Multi-U. To investigate the impact of these various flow fields on PEMFC performance, we conducted computational fluid dynamics (CFD) numerical simulations, validated through model experiments. Our results indicate that the Distro Out-In Multi-U flow field offers notable advantages compared to the conventional parallel flow field (CPFF) and conventional serpentine flow field (CSFF). These benefits include reduced inlet and outlet pressures, lower liquid water content, more uniform liquid water distribution, and a more even current density distribution. Furthermore, the Distro Out-In Multi-U design demonstrates improved efficiency, consuming less H2 (91.9%) than the CSFF while achieving a higher net power density output (10.1%). As a result, for the same power output, the Distro Out-In Multi-U utilizes only 83.5% of the H2 consumed by the CSFF. In summary, the U-shaped structured flow field exhibits superior output performance, enhanced energy efficiency, and improved resistance to flooding. These findings suggest that the U-shaped flow field design holds significant potential as a reactive flow field for PEMFCs.

Boosting Acidic Hydrogen Evolution Kinetics Induced by Weak Strain Effect in PdPt Alloy for Proton Exchange Membrane Water Electrolyzers.

Strain engineering is an effective strategy for manipulating the electronic structure of active sites and altering the binding strength toward adsorbates during the hydrogen evolution reaction (HER). However, the effects of weak and strong strain engineering on the HER catalytic activity have not been fully explored. Herein, the core-shell PdPt alloys with two-layer Pt shells (PdPt2L) and multi-layer Pt shells (PdPtML) is constructed, which exhibit distinct lattice strains. Notably, PdPt2L with weak strain effect just requires a low overpotential of 18 mV to reach 10 mA cm-2 for the HER and shows the superior long-term stability for 510 h with negligible activity degradation in 0.5 M H2SO4. The intrinsic activity of PdPt2L is 6.2 and 24.5 times higher than that of PdPtML and commercial Pt/C, respectively. Furthermore, PdPt2L||IrO2 exhibits superior activity over Pt/C||IrO2 in proton exchange membrane water electrolyzers and maintains stable operation for 100 h at large current density of 500 mA cm-2. In situ/operando measurements verify that PdPt2L exhibits lower apparent activation energy and accelerated ad-/desorption kinetics, benefiting from the weak strain effect. Density functional theory calculations also reveal that PdPt2L displays weaker H* adsorption energy compared to PdPtML, favoring for H* desorption and promoting H2 generation.

Topologically Close-Packed Frank-Kasper C15 Phase Intermetallic Ir Alloy Electrocatalysts Enables High-Performance Proton Exchange Membrane Water Electrolyzer.

Chemical synthesis of unconventional topologically close-packed intermetallic nanocrystals (NCs) remains a considerable challenge due to the limitation of large volume asymmetry between the components. Here, a series of unconventional intermetallic Frank-Kasper C15 phase Ir2M (M = rare earth metals La, Ce, Gd, Tb, Tm) NCs is successfully prepared via a molten-salt assisted reduction method as efficient electrocatalysts for hydrogen evolution reaction (HER). Compared to the disordered counterpart (A1-Ir2Ce), C15-Ir2Ce features higher Ir-Ce coordination number that leads to an electron-rich environment for Ir sites. The C15-Ir2Ce catalyst exhibits excellent and pH-universal HER activity and requires only 9, 16, and 27 mV overpotentials to attain 10 mA cm-2 in acidic, alkaline, and neutral electrolytes, respectively, representing one of the best HER electrocatalysts ever reported. In a proton exchange membrane water electrolyzer, the C15-Ir2Ce cathode achieves an industrial-scale current density of 1 A cm-2 with a remarkably low cell voltage of 1.7 V at 80 °C and can operate stably for 1000 h with a sluggish voltage decay rate of 50 µV h-1. Theoretical investigations reveal that the electron-rich Ir sites intensify the polarization of *H2O intermediate on C15-Ir2Ce, thus lowering the energy barrier of the water dissociation and facilitating the HER kinetics.

A Universal Strategy to Enhance Polarization Performance and Anode Reversal Tolerance by Polyaniline-Coated Carbon Support for Proton Exchange Membrane Fuel Cells.

Anode cell reversal typically leads to severe carbon corrosion and catalyst layer collapse, which significantly compromises the durability of proton exchange membrane fuel cells. Herein, three types of commercial carbon supports with various structures are facilely coated by polyaniline (PANI) and subsequently fabricated into reversal-tolerant anodes (RTAs). Consequently, the optimized PANI-coated catalyst RTAs demonstrate enhanced polarization performance and improved reversal tolerance compared to their uncoated counterparts, thus confirming the universality of this coating strategy. Essentially, the surface engineering introduced by PANI coating incorporates abundant N-groups and enhances coulombic interactions with ionomer side chains, which in turn reduces lower carbon exposure, promotes more uniform Pt deposition, and ensures better ionomer distribution. Accordingly, the membrane-electrode-assembly containing the Pt/PANI/XC-72R-1+IrO2 RTA presents a 100 mV (at 2500 mA cm-2) polarization performance improvement and 26-fold reduction in the degradation rate compared to the uncoated counterpart. This work provides a universal strategy for developing durable anodes and lays the groundwork for the practical fabrication of high-performance, low-degradation RTA.

Formation Characteristics of Pt-Ni Alloy Nanoparticles Fabricated by Nanolamination of Atomic Layer Deposition in Hydrogen.

Forced-flow atomic layer deposition nanolamination is employed to fabricate Pt-Ni nanoparticles on XC-72, with the compositions ranging from Pt94Ni6 to Pt67Ni33. Hydrogen is used as a co-reactant for depositing Pt and Ni. The growth rate of Pt is slower than that using oxygen reactant, and the growth exhibits preferred orientation along the (111) plane. Ni shows much slower growth rate than Pt, and it is only selectively deposited on Pt, not on the substrate. Higher ratios of Ni would hinder subsequent stacking of Pt atoms, resulting in lower overall growth rate and smaller particles (1.3-2.1 nm). Alloying of Pt with Ni causes shifted lattice that leads to larger lattice parameter and d-spacing as Ni fraction increases. From the electronic state analysis, Pt 4f peaks are shifted to lower binding energies with increasing the Ni content, suggesting charge transfer from Ni to Pt. Schematic of the growth behavior is proposed. Most of the alloy nanoparticles exhibit higher electrochemical surface area and oxygen reduction reaction activity than those of commercial Pt. Especially, Pt83Ni17 and Pt87Ni13 show excellent mass activities of 0.76 and 0.59 A mgPt -1, respectively, higher than the DOE target of 2025, 0.44 A mgPt -1.

New Morphology Modifier Enables the Preparation of Ultra-Long Platinum Nanowires Excluding Mo Component for Efficient Oxygen Reduction Reaction Performance.

The structural tailoring of Pt-based catalysts into 1D nanowires for oxygen reduction reactions (ORR) has been a focus of research. Mo(CO)6 is commonly used as a morphological modifier to form nanowires, but it is found that it inevitably leads to Mo doping. This doping introduces unique electrochemical signals not seen in other Pt-based catalysts, which can directly reflect the stability of the catalyst. Through experiments, it is demonstrated that Mo doping is detrimental to ORR performance, and theoretical calculations have shown that Mo sites that are inherently inactive also poison the ORR activity of the surrounding Pt. Therefore, a novel gas-assisted technique is proposed to replace Mo(CO)6 with CO, which forms ultrafine nanowires with an order of magnitude increase in length, ruling out the effect of Mo. The catalyst performs at 1.24 A mgPt -1, 7.45 times greater than Pt/C, demonstrating significant ORR mass activity, and a substantial improvement in stability. The proton exchange membrane fuel cell using this catalyst provides a higher power density (0.7 W cm-2). This study presents a new method for the preparation of ultra-long nanowires, which opens up new avenues for future practical applications of low-Pt catalysts in PEMFC.

Ionomeric Binders for High Temperature Proton Exchange Membrane Fuel Cells.

High-temperature proton exchange membrane fuel cell (HT-PEMFC) based on phosphoric acid doped polybenzimidazole membrane (PBI/PA) operating at 120-200 °C can provide insensitivity to carbon monoxide (CO) and simplified managements of water and heat and thus attract significant global attention. However, one significant drawback is its low utilization of precious metal catalysts resulted from the PA poisoning and inefficient three-phase boundary. Studies of binder materials in catalyst layers for HT-PEMFC are gradually emerging and there are few literature reviews on this important topic. The purpose of this review is to describe the various types of binders based on their molecular structure and electrochemical properties, with particular emphasis on catalyst layer for fuel cells. Importantly, this review provides a better understanding of relationship between fuel cell performance and the gas permeability and conductivity of different binders. Then, future directions of research and development in binder materials of HT-PEMFC are pointed out.

Proton Conduction via Water and Ammonia Coordinated Metal Cationic Species in MOF and MHOF Platforms.

Although metal-organic frameworks (MOFs) and metalo hydrogen-bonded organic frameworks (MHOFs) are designed as promising solid-state proton conductors by incorporating various protonic species intrinsically or extrinsically, design and development of such materials by employing the concept of proton conduction through coordinated polar protic solvent is largely unexplored. Herein, we have constructed two proton-conducting materials having different solvent coordinated metal cationic species: In-H2O-MOF, ({[In(H2O)6][In3(Pzdc)6]·15H2O}n; H2Pzdc: pyrazine-2,3-dicarboxylic acid) with coordinated water molecules from hexaaquaindium cationic species, and MHOF-4, ([{Co(NH3)6}2(2,6-NDS)2(H2O)2]n; 2,6-H2NDS: 2,6-naphthalenedisulfonic acid) with coordinated ammonia from hexaammoniacobalt cationic species. Interestingly, higher proton conductivity was achieved for In-H2O-MOF (1.5 × 10-5 S cm-1) than MHOF-4 (6.3 × 10-6 S cm-1) under the extreme conditions (80 ºC and 95% RH), which could be attributed to enhanced acidity of coordinated water molecules having much lower pKa value than that of coordinated ammonia. Greater charge polarization on hydrogen atoms of In3+-coordinated water molecules than that of Co2+-coordinated ammonia led to the high conductivity of In-H2O-MOF, as evident by quantum chemical studies. Such a comparative study on metal-coordinated protic polar solvents in achieving proton conduction in crystalline solids is yet to be made.

Construction of three-dimensional proton-conduction networks with functionalized PU@PAN/UiO-66 nanofibers for proton exchange membranes.

Proton exchange membranes (PEMs) play an important role in fuel cells. For realizing a nanofiber (NF) structure design in PEMs, the material should have tunable pores and a high specific area. In this study, we attempt to design a novel NF with synergistic architecture doped MOF for constructing three-dimensional (3D) proton conduction networks in PEMs. In this framework, UiO-66-COOH serves as a platform for proton sites to synergistically promote proton conductivity via polyvinylpyrrolidone dissolution, hydrolyzation of polyacrylonitrile, and sulfamic acid functionalization of the shell-layer NF. Benefiting from enriched proton-transfer sites in NFs, the obtained composite membrane overcomes the trade-off among proton conductivity, methanol permeability, and mechanical stability. The composite membrane with 50 % fiber (Nafion/S@NF-50) exhibited a high proton conductivity of 0.212 S cm-1 at 80 °C and 100 % relative humidity, suppressed methanol permeability of 0.66 × 10-7 cm2 s-1, and the maximum power density of direct methanol fuel cell is 182.6 mW cm-2. Density functional theory was used to verify the important role of sulfamic acid in proton transfer, and the activation energy barriers under anhydrous and hydrous conditions are only 0.337 and 0.081 kcal, respectively. This study opens up new pathways for synthesizing NF composite PEMs.

Data from steady-state simulation and economic evaluation in the power to methane context for synthetic natural gas production and power generation.

The data presented in this article is generated by a steady-state simulation for performing a techno-economic assessment for comparing three electrolysis technologies in the PtM context. The data is focused on two aspects. First, the description of the steady-state simulation of six PtM systems modeled using Aspen Custom Modeler (ACM) and Aspen Plus (AP). Second, an economic assessment is carried out for each of the mentioned PtM systems to compare the feasibility, the profitability and performance of these systems on a larger scale to produce synthetic natural gas, power generation and carbon utilization given in the main research article. Three electrolysis technologies (namely Alkaline Electrolysis - AE, Proton Exchange Membrane Electrolysis - PEME and Solid Oxide Electrolysis - SOE) were modeled having in mind two methane applications: a combined cycle for power generation and the syngas generation. In addition, on each PtM system is carried out an economic evaluation by calculating fixed capital investment (FCI) and manufacturing costs (MC).

Parameter extraction of proton exchange membrane fuel cell based on artificial rabbits' optimization algorithm and conducting laboratory tests.

Proton exchange membrane fuel cell (PEMFC) parameter extraction is an important issue in modeling and control of renewable energies. The PEMFC problem's main objective is to estimate the optimal value of unknown parameters of the electrochemical model. The main objective function of the optimization problem is the sum of the square errors between the measured voltages and output voltages of the proposed electrochemical optimized model at various loading conditions. Natural rabbit survival strategies such as detour foraging and random hiding are influenced by Artificial rabbit optimization (ARO). Meanwhile, rabbit energy shrink is mimicked to control the smooth switching from detour foraging to random hiding. In this work, the ARO algorithm is proposed to find the parameters of PEMFC. The ARO performance is verified using experimental results obtained from conducting laboratory tests on the fuel cell test system (SCRIBNER 850e, LLC). The simulation results are assessed with four competitive algorithms: Grey Wolf Optimization Algorithm, Particle Swarm Optimizer, Salp Swarm Algorithm, and Sine Cosine Algorithm. The comparison aims to prove the superior performance of the proposed ARO compared with the other well-known competitive algorithms.

In-situ strategies for melamine-functionalized graphene oxide nanosheets-based nanocomposite proton exchange membranes in wide-temperature range applications.

The traditional preparation of nanocomposite proton exchange membranes (PEM) is hindered by poor organic-inorganic interface compatibility, insufficient proton-conducting sites, easy aggregation of nanoparticles, and difficulty in leveraging nanoscale advantages. In this study, a novel method involving electrochemical anodic oxidation exfoliation was employed to prepare melamine-coated graphene oxide (Me@GO), which was subsequently subjected to in-situ polymerization with poly(2,5-benzimidazole) (ABPBI) to prepare a Me@GO/ABPBI composite proton exchange membrane. Benefiting from the strong hydrogen bonding and large π stacking interactions, melamine (Me) tightly bound to graphene oxide (GO), effectively preventing the secondary aggregation of GO after exfoliation. Moreover, the abundant alkaline functional groups of melamine enhanced the enhancement of phosphoric acid (PA) retention in the Me@GO/ABPBI membranes, thereby increasing the number of proton-conducting sites. The experimental results indicated that the introduction of Me@GO enhanced membrane properties. For Me@GO at a concentration of 1 wt%, the tensile strength of the 1Me@GO/ABPBI composite membrane reached 207 MPa, nearly 2.52 times that of the pure membrane. The proton conductivity of the 1Me@GO/ABPBI composite membrane reached 0.01 S cm-1 across a wide temperature range (40-180 °C), peaking at 0.087 S cm-1 at 180 °C. Additionally, a single-cell incorporating the 1Me@GO/ABPBI composite membrane achieved a peak power density of 0.304 W cm-2 at 160 °C, nearly 1.46 times that of the pure membrane. Benefiting from the well-dispersed and PA-enriched proton channels provided by Me@GO, the Me@GO/ABPBI composite membrane exhibits excellent prospects for wide-temperature range (40-180 °C) applications.

A High-Methanol-Permeation Resistivity Polyamide-Based Proton Exchange Membrane Fabricated via a Hyperbranching Design.

Four non-fluorinated sulfonimide polyamides (s-PAs) were successfully synthesized and a series of membranes were prepared by blending s-PA with polyvinylidene fluoride (PVDF) to achieve high-methanol-permeation resistivity for direct methanol fuel cell (DMFC) applications. Four membranes were fabricated by blending 50 wt% PVDF with s-PA, named BPD-101, BPD-102, BPD-111 and BPD-211, respectively. The s-PA/PVDF membranes exhibit high methanol resistivity, especially for the BPD-111 membrane with methanol resistivity of 8.13 × 10-7 cm2/s, which is one order of magnitude smaller than that of the Nafion 117 membrane. The tensile strength of the BPD-111 membrane is 15 MPa, comparable to that of the Nafion 117 membrane. Moreover, the four membranes also show good thermal stability up to 230 °C. The BPD-x membrane exhibits good oxidative stability, and the measured residual weights of the BPD-111 membrane are 97% and 93% after treating in Fenton's reagent (80 °C) for 1 h and 24 h, respectively. By considering the mechanical, thermal and dimensional properties, the polyamide proton-exchange membrane exhibits promising application potential for direct methanol fuel cells.

Enhancing renewable energy utilization and energy management strategies for new energy yachts.

Hydrogen energy, due to its clean and efficient nature, has shown great potential during the current transition period in the shipbuilding industry. However, the application of hydrogen energy in ship energy systems is influenced by variations in operational load and the integration of new energy sources during actual navigation. To address these issues, this paper focuses on optimizing and scheduling the operation of ships under various navigation conditions, considering the distributed nature of hydrogen energy. System simulations were conducted to model the photovoltaic (PV), proton exchange membrane fuel cells (PEMFCs), lithium batteries (LIBs), electrolytic cells (ECs), and energy storage modules of yacht energy systems. Component boundaries and objective functions were set, and two cases (excess photovoltaic state and constant power state) were designed to optimize and regulate the energy balance of hydrogen-powered yachts, enhancing their comprehensive utilization of renewable energy. By comparing the changes in ship energy under the two cases, it was concluded that case 1 ensures the maximum utilization of renewable energy. When photovoltaic power generation is insufficient, the PEMFC and LIB in the system provide the required power to achieve a supply-demand balance. Moreover, when PV power generation is sufficient, hydrogen energy is used to store renewable energy. The optimization method designed in this study can, to some extent, maximize the application of renewable energy in new energy yachts, ensuring the efficiency of the comprehensive energy system of new energy yachts, reducing emissions, and improving the sustainability and economic efficiency of the ships.

Oxygen Reduction Reaction Activity and Stability of Shaped Metal-Doped PtNi Electrocatalysts Evaluated in Gas Diffusion Electrode Half-Cells.

The synthesis of bimetallic and trimetallic platinum-based octahedral catalysts for the cathode of proton exchange membrane fuel cells (PEMFCs) is a particularly active area aimed at meeting technological requirements in terms of durability and cost. The electrocatalytic activity and stability of these shaped catalysts were tested at relatively high potentials (@0.9 V vs RHE) and at lower current densities using the rotating disk electrode, which is less suitable for assessing their behavior under the operating conditions of PEMFCs. In this work, we use a gas diffusion electrode (GDE) half-cell setup to test the performance of the catalysts under application-oriented conditions, relatively higher current densities, and a square-wave stability test. After the stability test, we analyzed the GDE catalytic layer to study the agglomeration and dissolution of the transition metal under these conditions by using high-resolution scanning electron microscopy and energy-dispersive X-ray spectroscopy. The present results provide valuable guidance for developing next-generation active and durable catalysts for PEMFCs.

An improved nutcracker optimization algorithm for discrete and continuous optimization problems: Design, comprehensive analysis, and engineering applications.

This study is presented to examine the performance of a newly proposed metaheuristic algorithm within discrete and continuous search spaces. Therefore, the multithresholding image segmentation problem and parameter estimation problem of both the proton exchange membrane fuel cell (PEMFC) and photovoltaic (PV) models, which have different search spaces, are used to test and verify this algorithm. The traditional techniques could not find approximate solutions for those problems in a reasonable amount of time, so researchers have used metaheuristic algorithms to overcome those shortcomings. However, the majority of metaheuristic algorithms still suffer from slow convergence speed and stagnation into local minima problems, which makes them unsuitable for tackling these optimization problems. Therefore, this study proposes an improved nutcracker optimization algorithm (INOA) for better solving those problems in an acceptable amount of time. INOA is based on improving the performance of the standard algorithm using a newly proposed convergence improvement strategy that aims to improve the convergence speed and prevent stagnation in local minima. This algorithm is first applied to estimating the unknown parameters of the single-diode, double-diode, and triple-diode models for a PV module and a solar cell. Second, four PEMFC modules are used to further observe INOA's performance for the continuous optimization challenge. Finally, the performance of INOA is investigated for solving the multi-thresholding image segmentation problem to test its effectiveness in a discrete search space. Several test images with different threshold levels were used to validate its effectiveness, stability, and scalability. Comparison to several rival optimizers using various performance indicators, such as convergence curve, standard deviation, average fitness value, and Wilcoxon rank-sum test, demonstrates that INOA is an effective alternative for solving both discrete and continuous optimization problems. Quantitively, INOA could solve those problems better than the other rival optimizers, with improvement rates for final results ranging between 0.8355 % and 3.34 % for discrete problems and 4.97 % and 99.9 % for continuous problems.

Utilization of Water-Insoluble Carbon Nitride-Phosphotungstic Acid Hybrids in Composite Proton Exchange Membranes.

Phosphotungstic acid (HPW) can retain water in proton exchange membranes to increase proton conductivity; however, its water-soluble nature limits further application. In this work, we combined HPW and graphitic carbon nitride (g-C3N4) via sintering to prepare water-insoluble hybrids (HWN), where HPW was chemically linked to g-C3N4 to fix HPW. Then, HWN fillers were added to a sulfonated polyether ether ketone (SPEEK) matrix to prepare composite membranes. The conductivity of the composite membrane with 10 wt% HWN is up to 0.066 S cm-1 at room temperature, which is 53% higher than that of the SPEEK control membrane (0.043 S cm-1). The composite membrane also showed stable proton conductivity after being immersed in water for 2000 h. Therefore, our study demonstrates that preparing water-insoluble nanofillers containing HPW components through sintering is a promising approach.

Sensitivity and Stability Study of Test Conditions for a 1 kW Proton Exchange Membrane Fuel Cell Stack.

This study investigates the impact of compression force on stack performance and the effect of testing conditions on sensitivity of stack performance. It explores the variation of assembly force on the pressure distribution at different positions in a 1 kW proton exchange membrane fuel cell stack. Polarization curves and high-frequency resistance (HFR) changes of the stack were measured under different assembly forces, and the optimal assembly force of the stack was determined using the average single-cell voltage (HFR-free). The sensitivity of testing conditions was optimized, and the optimum test parameters at different current densities were identified within the selected range. Stack stability was tested at different current densities using the optimized test conditions, and the sensitivity of test conditions was verified by the fluctuation amplitude of single cell voltage and internal impedance.

Functionalized Modified Ti4O7 Polyaniline Coating for 316SS Bipolar Plate in Proton-Exchange Membrane Fuel Cells.

In this paper, the PANI/PDA-Ti4O7 composite coating was prepared on 316L by constant current deposition with a current density of 2.8 mA·cm-2, in which the Ti4O7 powders were modified by PDA (polydopamine). The open-circuit potential of the obtained PANI/PDA-Ti4O7 composite coating is about 365 mVAg/AgCl, which is more positive than that of the bare 316L. During immersion in 1 M H2SO4 + 2 ppm HF for 200 h, the high stable corrosion potential and the lower Rf indicate that the composite coating has long-term corrosion resistance.

High proton conductivity of sulfonate-amine ionic HOFs and enhancement of SPEEK composite membranes.

Hydrogen-bonded organic frameworks (HOFs) are crystalline materials assembled by intermolecular hydrogen-bonding interactions, and their hydrogen-bonding structures are effective pathways for proton transport. Herein, we synthesize iHOF-45 using 4,4'-diaminodiphenylmethane and 1,3,6,8-pyrenetetrasulfonicacid sodium salt with 2D hydrogen-bonding networks. The introduction of ionic bond based on the weak hydrogen-bonding force was employed to enhance the stability of ionic HOFs (iHOFs). Thermal analyses demonstrated that iHOF-45 exhibited excellent thermal stability up to 332 °C. The proton conductivity of iHOF-45 was evaluated, demonstrating a notable increase with rising temperature and RH. At 100 °C and 98% RH, the conductivity reached 5.25 × 10-3 S cm-1. The activation energy (Ea) of iHOF-45 was calculated to be 0.281 eV for 98% RH, and the proton conduction was attributed to the Grotthuss mechanism, whereby the protons were transported in 2D hydrogen-bonding networks. Moreover, iHOF-45 was doped into SPEEK to prepare composite membranes, the proton conductivity of the 15%-iHOF-45/SPEEK membrane reached 9.52 × 10-2 S cm-1 at 80 °C and 98% RH, representing a 45.1% increase over that of the SPEEK. This suggests that doping enhances the proton conductivity of SPEEK and providing a reference for the development of high proton conductivity materials.