A new approach for cobalt (II) removal from simulated wastewater using electro membrane extraction with a flat sheet supported liquid membrane.

The aim of this work was to efficiently remove cobalt (Co) from aqueous solutions by using a novel Electromembrane Extraction (EME) technique. This novel electrochemical cell design featured two distinct glass chambers, incorporating a Supported Liquid Membrane (SLM) composed of a polypropylene flat membrane saturated with 1-octanol and a carrier substance, as well as electrodes constructed from graphite and stainless steel. The investigation covered an exploration of various effective parameters like, carrier type, voltage across the cell, donor solution pH, and the initial Co concentration, with the overarching goal of comprehending their individual effect on Co removal efficiency. Notably, two different carriers, tris(2-ethylhexyl) phosphate (TEHP) and bis(2-ethylhexyl) phosphate (DEHP), were systematically evaluated in combination with 1-octanol. The findings underscored the pivotal role of the cell voltage in significantly enhancing the mass transfer rate of cobalt across the membrane, thereby advancing the effectiveness of the removal process. After a comprehensive optimization process, the optimal operating conditions were established as follows: employing 1-octanol with 1.0 % v/v bis(2-ethylhexyl) phosphate as a carrier, applying a voltage of 60 V, maintaining an initial pH of 5, utilizing an initial cobalt concentration of 15 mg/L, conducting an extraction for 6 h, and employing a stirring rate of 1000 rpm. Remarkably, these conditions led to the attainment of an impressive removal efficiency of 87 %. In stark contrast, when no voltage was applied, the removal efficiency did not surpass 40 %. This underscores the pivotal role of the applied voltage in enhancing the cobalt removal process under the specified conditions.

Treatment vegetable oil refinery wastewater by sequential electrocoagulation-electrooxidation process.

In the present study a sequential process composed of electrocoagulation (EC) followed by electrooxidation (EO) was utilized at the laboratory scale to remove the chemical oxygen demand (COD) from wastewater generated in Iraqi vegetable oil refinery plant.in the EC, impacts of operating variables such as current density (10-30 mA cm-2) and pH (4-10),and EC time (30-90 min) on the COD removal (RE%) were investigated using response surface methodology (RSM) based on Box- Behnken design(BBD). a mathematical correlation that relates the operating factors with RE% was developed and its regression coefficient was 99.02% confirming the significant of the model. Response surface plots showed that RE% increased with increasing current density and time while it decreased with increasing pH. The optimum removal with a lower cost for EC process were achieved at current density of 30mA/cm2, pH of 4, and electrolysis time of 90 min in which RE% of 69.19% was obtained with requirement of 0.513kWh/kg COD as specific energy consumption (SEC). The effluent exit from EC was treated by EO for a period of 240min at a current density of 30mA/cm2 and an initial pH value of 4 to obtain RE% of 96% at SEC of 1.554 kWh/kg COD. Combining EC with EO resulted in a total RE% of 98.72% and a total SEC of 2.067 kWh/kg COD. Based on the results of present study, the applicability of a sequential electrocoagulation-electrooxidation process for treatment vegetable oil wastewaters is feasible.

Application of solar photo-electro-Fenton technology to petroleum refinery wastewater degradation: Optimization of operational parameters.

Industrial and agricultural advances have led to global issues such as contamination of water sources and lack of access to clean water. Wastewater from petroleum refineries must be subjected to treatment as it poses a significant environmental threat. The present research aimed to reduce the level of chemical oxygen demand (COD) of an effluent from Bijee petroleum refinery plant, Iraq, using solar photo-electro-Fenton (SPEF) process operated in a batch recycle model. The electrochemical reactor used in the present research was of a tubular design with an anode composed of porous graphite rod and a concentric cylindrical cathode made of the same material. The impacts of operating parameters such as current density (10-50 mA/cm2), Fe2+ concentration (0.2-0.8 mM), NaCl addition (0-1 g/L), and time (30-90 min) on the COD removal efficiency were explored based on the response surface methodology (RSM). Results showed that the impact of Fe2+ concentration was most prominent, with an effective contribution of 47.7%, followed by current density, with a contribution of 18.26%, and the addition of NaCl, with a contribution of 11.20%. COD removal was found to increase with an increase in current density, Fe2+ concentration, NaCl addition, and time, respectively, while energy consumption was found to increase significantly with an increase in current density and a decrease in Fe2+ concentration, respectively. The optimum conditions were observed to be an initial pH of 3, current density of 10 mA/cm2, Fe2+ concentration of 0.8 mM, NaCl addition of 0.747 g/L, and a duration of 87 min, upon which 93.20% COD removal efficiency was achieved, with an energy consumption of 15.97 kWh/kg COD.