UiO66-NH2-TiO2/NiF photoanode for photocatalytic fuel cell by towards simultaneous treatment of antibiotic wastewater and electricity generation.

Environmental destruction, water crisis, and clean energy are among the very important challenges worldwide based on sustainable development goals. Photocatalytic fuel cell, a potential candidate for converting chemical energy into electrical energy through a pollution-free method, holds promise in addressing these challenges. In this regard, we investigated the response of a photoanode covered with UiO66-NH2-TiO2/NiF on a porous nickel foam as an attractive electrochemical response to remove antibiotics from aqueous solution and simultaneously produce electricity using a one-step hydrothermal synthesis. Nickel foam with its fine structure provides a suitable space for the interaction of light, catalyst, and efficient mass transfer of reactive molecules. It appears that it can be used as a competitive electrode in fuel cells. In order to investigate the properties of the photocatalyst, structural analyses including XRD, FESEM, FTIR, and UV-vis DRS were utilized. Additionally, polarization and electrochemical tests such as chronoamperometry and EIS were measured to further examine the electrochemical features of the PFC photoanode system. The obtained results under optimal conditions (SMZ concentration = 20 ppm, pH = 6, irradiation time = 120 min) were as follows: removal efficiency of 91.7%, Pmax = 16.98 µW/cm2, Jsc = 96.75 µA/cm2, Voc = 644 mV. The light-induced current flow in UiO66-NH2-TiO2/NiF exhibited prominent and reproducible photocurrent responses, indicating efficient and stable charge separation in TiO2/NiF composite materials, which is a promising strategy for pollutant removal and simultaneous electricity generation.

Three-layer business model canvas (TLBMC) as a recycling support tool to achieve sustainable development goals in waste management systems.

Traditional strategies for waste management in developing countries face high-cost problems, severe pollution, limited viable data, lack of global coverage, inefficiency, and slowness. The rapid expansion of the Internet have made new opportunities in waste management, especially waste collection. Online waste management in developing countries can create a revolution and help the government and society to achieve the goals of sustainable development. In this study, a modified three-layer business model canvas (TLBMC) was used to describe the duties of each actors involved in waste management and interactions between different elements in order to show the existing capacities in view point of economic, social, and environmental dimensions. In this online marketplace, the flow of information, the flow of materials and the flow of money in any company or entity or person active in the field of waste, are effectively connected to each other. Supply and demand information is provided in the created platform, and various waste actors are connected to look for options to trade. After agreement between the customer and the buyer, the information is delivered from the website or platform created by the supplier to the applicant. This network can have its usual structural features and create appropriate mechanisms for the continuation of its business operation and the realization of sustainable development of waste management, especially the recycling industry.

Microbiological dataset of rural drinking water supplies in Zahedan, Iran.

The residual chlorine and microbial quality of drinking water in the Zahedan villages by a number of1221 samples from all 168 villages were collected between 2014-2015. Then the samples were evaluated using 9-tube fermentation methods and portable chlorine method test. Based on the microbial coliform and fecal coliform indices, the data indicated that the maximum and minimum controlling of the bacteria in the distribution network were in the winter (90.62%) and autumn (85.56%), respectively. Also in the reservoirs, the maximum and minimum controlling of the bacteria were in winter (93.49%) and autumn (87.35%), respectively. The residual chlorine was prepared in almost all of seasons.

Data on fluoride concentration levels in cold and warm season in City area of Sistan and Baluchistan Province, Iran.

The need for fluoride in drinking water to the extent that reduces the amount of tooth decay and the other hand does not cause dental fluorosis, has been well documented as an important fact. The aim of this research is to survey values of fluoride in drinking water in Sistan and Baluchestan. In this descriptive and analytical study, the number of 551 samples during 4 seasons of 2013 year from rural drinking water sources via rural water and Wastewater Company has been taken. The concentration of fluoride in water samples was measured using SPADNS method. Results shows that the average concentration of fluoride in drinking water supplies for the rural region of Khash, Sarbaz, Iranshahr, Saravan, Nickshahr city are 0.72 (±0.31), 0.55(±0.21), 0.33 (±0.127), 0.6 (±0.24), 0.435 (±0.23) respectively.

The concentration data of fluoride and health risk assessment in drinking water in the Ardakan city of Yazd province, Iran.

According to the World Health Organization (WHO) reports, Iran is located in the global fluoride belts, so that is why carrying out extended research on this contaminant anion in water supplies must be considered. Due to the various industries in the Ardakan city, this region is severely suffering from fluoride contamination. This study was designed to investigate the fluoride concentration and its distribution pattern as well as related health risk assessment in groundwater resources of 28 villages of the Ardakan city in Yazd province using SPADNS method according to standard instructions. Our results show that, the average concentration of fluoride was 2.92 mg/l (range: 0.9-6 mg/l), also in half of the villages, the concentration range of this element was over than standard level (1.5 mg/l) given by WHO rules. In addition, risk assessment results showed that HQ value is higher than 1 in 46.4% of samples of groundwater resources in age groups of infants, children, teenagers and adults. Therefore, it is necessary to take measures to reduce fluoride concentration in drinking water in order to control resultant fluorosis. Actions should be implemented to enhance monitoring of fluoride levels to avoid the potential risk of high Fluoride concentration.

Neuro-fuzzy inference system Prediction of stability indices and Sodium absorption ratio in Lordegan rural drinking water resources in west Iran.

According to World Health Organization guidelines, corrosion control is an important aspect of safe drinking-water supplies. Water always includes ingredients, dissolved gases and suspended materials. Although some of these water ingredients is indispensable for human beings, these elements more than permissible limits, could be endanger human health. The aim of this study is to assess physical and chemical parameters of drinking water in the rural areas of Lordegan city, also to determine corrosion indices. This cross-sectional study has carried out with 141 taken samples during 2017 with 13 parameters, which has been analyzed based on standard method and to estimate the water quality indices from groundwater using ANFIS. Also with regard to standard conditions, results of this paper are compared with Environmental Protection Agency and Iran national standards. Five indices, Ryznar Stability Index (RSI), Langlier Saturation Index (LSI), Larson-Skold Index (LS), Puckorius Scaling Index (PSI), and Aggressive Index (AI) programmed by using Microsoft Excel software. Owing to its simplicity, the program, can easily be used by researchers and operators. Parameters included Sulfate, Sodium, Chloride, and Electrical Conductivity respectively were 13.5, 28, 10.5, and 15% more than standard level. The amount of Nitrate, in 98% of cases were in permissible limits and about 2% were more than standard level. Result of presented research indicate that water is corrosive at 10.6%,89.4%,87.2%,59.6% and 14.9% of drinking water supply reservoirs, according to LSI, RSI, PSI, LS and AI, respectively.

Groundwater quality assessment for irrigation purposes based on irrigation water quality index and its zoning with GIS in the villages of Chabahar, Sistan and Baluchistan, Iran.

The present study was conducted to evaluate the groundwater quality and its suitability for irrigation purpose through GIS in villages of Chabahr city, Sistan and Baluchistan province in Iran. This cross-sectional study was carried out from 2010 to 2011 the 1-year-monitoring period. The water samples were collected from 40 open dug wells in order to investigate the water quality. Chemical parameters including EC, SAR, Na+, Cl-, pH, TDS, HCO3- and IWQI were analyzed. In order to calculate the irrigation water quality index subsequent five water quality parameters (EC, SAR, Na+, Cl-, and HCO3- ) were utilized. Among the total of 40 samples were analyzed for IWQI, 40% of the samples classified as excellent water, 60% of the samples in good water category.

Data on assessment of groundwater quality for drinking and irrigation in rural area Sarpol-e Zahab city, Kermanshah province, Iran.

In present study 30 groundwater samples were collected from Sarpol-e Zahab area, Kermanshah province of Iran in order to assess the quality of groundwater in subjected area and determining its suitability for drinking and agricultural purposes. Also the variations in the quality levels of groundwater were compared over the years of 2015 and 2016. Statistical analyses including Spearman correlation coefficients and factor analysis display good correlation between physicochemical parameters (EC, TDS and TH) and Na+, Mg2+, Ca2+, Cl- and [Formula: see text] ionic constituents. Also in order to assess water quality for irrigation we used the United States Department of Agriculture (USDA) classification which is based on SAR for irrigation suitability assessment. In addition, the residual sodium carbonate (RSC), %Na, PI, KR, SSP, MH, EC characteristics were calculated for all samples and used for assessment of irrigation suitability. Based on these indicators, for every two years, the quality of water for agriculture is in good and excellent category. The Piper classification for hydro geochemical facies indicates that the water in the study area is of Ca-HCO3- type. However, the study of water hardness shows that more than 80% of samples are in hard and very hard water class. Therefore, there is a need for decisions to refine and soften the water.

Assessment of groundwater quality and evaluation of scaling and corrosiveness potential of drinking water samples in villages of Chabahr city, Sistan and Baluchistan province in Iran.

The aims of this study were to assess and analysis of drinking water quality of Chabahar villages in Sistan and Baluchistan province by water quality index (WQI) and to investigate the water stability in subjected area. The results illustrated that the average values of LSI, RSI, PSI, LS, and AI was 0.5 (±0.34), 6.76 (±0.6), 6.50 (±0.99), 2.71 (±1.59), and 12.63 (±0.34), respectively. The calculation of WQI for groundwater samples indicated that 25% of the samples could be considered as excellent water, 50% of the samples were classified as good water category and 25% of the samples showed poor water category.