1.
Acta Crystallogr E Crystallogr Commun
; 78(Pt 11): 1118-1121, 2022 Nov 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-36380906
RESUMO
The title compound, C8H8O2S2, contains a cyclo-hexane-1,3-dione ring, which has a twist-boat conformation. The C2S2 ring is close to planar (r.m.s. deviation = 0.023â Å) and the dihedral angle between the mean planes of the cyclo-hexane and 1,3-dithietane rings is 9.1â (3)°. Short intra-molecular Sâ¯O contacts occur [2.719â (5) and 2.740â (5)â Å]. In the crystal, the mol-ecules are linked by weak C-Hâ¯S hydrogen bonds and short [3.165â (5)â Å] Sâ¯O contacts, forming (010) layers. The prevalence of these inter-actions is illustrated by an analysis of the three-dimensional Hirshfeld surface and by two-dimensional fingerprint plots.