Impact of Processing Parameters on Contactless Emulsification via Corona Discharge.

A contactless emulsification method is presented using corona discharge. The corona discharge forms using a pin-to-plate configuration, creating a non-uniform electric field. This results in a simultaneous electrohydrodynamic (EHD) pumping of silicone oil and an electroconvection of water droplets that accelerate and submerge inside the oil, leading to a continuous water-in-oil (W/O) emulsion formation process. The impact of the oil viscosity and corona generating AC and DC electric fields (i.e., voltage and frequency) on the characteristics of the emulsions is studied. The emulsification power consumption using the AC and DC electric fields is calculated and compared to traditional emulsion formation methods. While using the DC electric field results in the formation of uniform emulsions, the AC electric field is readily available and uses less power for the emulsification. This is facile, contactless, and energy-efficient for the continuous formation of W/O emulsions.

Contactless Method of Emulsion Formation Using Corona Discharge.

Electroemulsification methods use electrohydrodynamic (EHD) forces to manipulate fluids and droplets for emulsion formation. Here, a top-down method is presented using a contactless corona discharge for simultaneous emulsion formation and its pumping/collection. The corona discharge forms using a sharp conductive electrode connected to a high-voltage source that ionizes water vapor droplets (formed by a humidifier) and creates an ionic wind (electroconvection), dragging them into an oil medium. The nonuniform electric field induced by the corona discharge also drives the motion of the oil medium via an EHD pumping effect utilizing a modulated bottom electrode geometry. By these two effects, this contactless method enables the immersion of the water droplets into the moving oil medium, continuously forming a water-in-oil (W/O) emulsion. The impact of corona discharge voltage, vertical and horizontal distances between the two electrodes, and depth of the silicone oil on sizes of the formed emulsions is studied. This is a low-cost and contactless process enabling the continuous formation of the W/O emulsions.

Universal Strain Energy-Mediated Dynamic Porosity in Physically Networked Elastomers and Their Applications.

Mechanical and physical properties of porous polymers are highly dependent on the arrangement of their internal pores, which once synthesized are widely considered static. However, here we introduce an unconventional dynamic porosity strategy in physically networked elastomer polymers, irrespective of their chemistry. This strategy allows for an omnidirectional and reversible reconfiguration of porosity in response to applied mechanical deformations, even at ambient conditions. In particular, the normal contact pressure between human fingers (just 0.62 MPa) applied on thin elastomer films results in a permanent reversion of the pores to a denser and more solid state. The porous-to-solid transition leads to a 3 order of magnitude reduction in pore density and up to a 22% relative volumetric shrinkage of the films, resulting in an opaque-to-transparent transition (OTT) that acts as a visual indication of porosity state (porous vs nonporous). It is shown that the pore reversion pressure onset is dependent on the average pore-to-pore distance that is controllable through process-specific parameters. Furthermore, the porosity transition is reversible for multiple cycles when the through-plane compression activation is coupled with an in-plane stretch (ε = 700%). A strain energy-mediated thermodynamic model is successfully implemented to confirm the effects of mechanical deformations on pore reversion and generation. Finally, applications of the newfound dynamic porosity concept are exploited for pressure indication, on-demand modulation of materials' mechanical and thermal characteristics, and flexible photomasks.