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1.
Heliyon ; 9(11): e21041, 2023 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-37928005

RESUMO

The main aim of this study is to figure out how well cryptand-2.2.1 (C 2.2.1) and cryptand-2.1.1 (C 2.1.1) macrocyclic compounds (MCs) work as novel extractants for scandium (Sc) by using an artificial neural network (ANN) models in MATLAB software. Moreover, C2.2.1 and C2.1.1 have never been evaluated to recover Sc. The independent variables impacting the extraction process (concentration of MC, concentration of Sc, pH, and time), and a nonlinear autoregressive network with exogenous input (NARX) and feed-forward neural network (FFNN) models were used to estimate their optimum values. The greatest obstacle in the selective recovery process of the REEs is the similarity in their physicochemical properties, specifically their ionic radius. The recovery of Sc from the aqueous solution was experimentally evaluated, then the non-linear relationship between those parameters was predictively modeled using (NARX) and (FFNN). To confirm the extraction and stripping efficiency, an atomic absorption spectrophotometer (AAS) was employed. The results of the extraction investigations show that, for the best conditions of 0.008 mol/L MC concentration, 10 min of contact time, pH 2 of the aqueous solution, and 75 mg/L Sc initial concentration, respectively, the C 2.1.1 and C 2.2.1 extractants may reach 99 % of Sc extraction efficiency. Sc was recovered from a multi-element solution of scandium (Sc), yttrium (Y), and lanthanum (La) under these circumstances. Whereas, at a concentration of 0.3 mol/L of hydrochloric acid, the extraction of Sc was 99 %, as opposed to Y 10 % and La 7 %. The Levenberg-Marquardt training algorithm had the best training performance with an mean-squared-error, MSE, of 5.232x10-6 and 6.1387x10-5 for C 2.2.1 and C 2.1.1 respectively. The optimized FFNN architecture of 4-10-1 was constructed for modeling recovery of Sc. The extraction process was well modeled by the FFNN with an R2 of 0.999 for the two MC, indicating that the observed Sc recovery efficiency consistent with the predicted one.

2.
Data Brief ; 49: 109414, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37520651

RESUMO

Globally, wind turbines play a significant role in generating sustainable and clean energy. Ensuring optimal performance and reliability is crucial to minimize failures and reduce operating and maintenance costs. However, due to their conventional design, identifying faults in wind turbines is challenging. This dataset provides vibration data for faulty wind turbine blades, which covers common vibration excitation mechanisms associated with various faults and operating conditions, including wind speed. The introduced faults in the wind turbine blades include surface erosion, cracked blade, mass imbalance, and twist blade fault. This data article serves as a valuable resource for validating condition monitoring methods in industrial wind turbine applications and facilitates a better understanding of vibration signal characteristics associated with different faults.

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