Correction to "Facile Green Approach for Developing Electrochemically Reduced Graphene Oxide-Embedded Platinum Nanoparticles for Ultrasensitive Detection of Nitric Oxide".

[This corrects the article DOI: 10.1021/acsomega.0c05644.].

Facile Green Approach for Developing Electrochemically Reduced Graphene Oxide-Embedded Platinum Nanoparticles for Ultrasensitive Detection of Nitric Oxide.

Nitric oxide (NO) plays a crucial and important role in cellular physiology and also acts as a signaling molecule for cancer in humans. However, conventional detection methods have their own limitations in the detection of NO at low concentrations because of its high reactivity and low lifetime. Herein, we report a strategy to fabricate Pt nanoparticle-decorated electrochemically reduced graphene oxide (erGO)-modified glassy carbon electrode (GCE) with efficiency to detect NO at a low concentration. For this study, Pt@erGO/GCE was fabricated by employing two different sequential methods [first GO reduction followed by Pt electrodeposition (SQ-I) and Pt electrodeposition followed by GO reduction (SQ-II)]. It was interesting to note that the electrocatalytic current response for SQ-I (184 µA) was ∼15 and ∼3 folds higher than those of the bare GCE (11.7 µA) and SQ-II (61.5 µA). The higher current response was mainly attributed to a higher diffusion coefficient and electrochemically active surface area. The proposed SQ-I electrode exhibited a considerably low LOD of 52 nM (S/N = 3) in a linear range of 0.25-40 µM with a short response time (0.7 s). In addition, the practical analytical applicability of the proposed sensor was also verified.

Hollow Polypyrrole Composite Synthesis for Detection of Trace-Level Toxic Herbicide.

In this work, we successfully demonstrated the fabrication of a chemical sensor for toxic 1,1-dimethyl-3-phenylurea (fenuron) by using a hollow polypyrrole composite film. Here, we studied the interaction between negatively charged phosphate anions enclosed in the film with positively charged nitrogen atoms present in the fenuron. The electrochemical response of the film was characterized by cyclic voltammetry in which, interestingly, we observed that the bigger alkyl aryl sulphonate ions were replaced by smaller phosphate ions with the creation of hollow/pore composite films. Confirmation for ion replacement in the film and porosity of the film were studied by elemental analysis and field emission scanning electron microscopy, respectively. The tuning of hydrophilic to hydrophobic nature of the hollow composite film was tested by the wettability test (contact angle measurement). The electrocatalytic materials, as well as the fenuron sensing conditions such as pH and film thickness, were wisely optimized on glassy carbon (GC) electrodes for better performance. We can enhance the fenuron sensitivity by over 5 times as compared to that on the GC substrate. To our knowledge, this is the first electrochemical fenuron sensor based on a hollow polymer film by differential pulse voltammetry which can detect lower concentrations and show quick response compared to other reports. This method has potential applications in the electrochemical sensing platform with good sensitive and selective analysis in agriculture groundwater samples.