RESUMO
By Cu NMR we studied the spin and charge structure in Nd(2-x)Ce(x)CuO(4-delta). For x=0.15, starting from a superconducting sample, the low temperature magnetic order in the sample reoxygenated under 1 bar oxygen at 900 degrees C reveals a peculiar modulation of the internal field, indicative of a phase characterized by large charge droplets ("blob" phase). By prolonged reoxygenation at 4 bars the blobs break up and the spin structure changes to that of an ordered antiferromagnet. We conclude that the superconductivity in the n-type systems competes with a genuine type I Mott-insulating state.
RESUMO
The experimental observations of stripes in superconducting cuprates and insulating nickelates clearly show the modulation in charge and spin density. However, these have proven to be rather insensitive to the harmonic structure and (site or bond) ordering. Using (139)La NMR in La(2)NiO(4+delta) with delta = 0.17, we show that in the 1/3 hole doped nickelate below the freezing temperature the stripes are strongly solitonic and site ordered with Ni(3+) ions carrying S = 1/2 in the domain walls and Ni(2+) ions with S = 1 in the domains.