1.
Acta Crystallogr E Crystallogr Commun
; 79(Pt 9): 813-816, 2023 Sep 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37693675
RESUMO
The title indole derivative, C24H17Br3N2O6S, crystallizes with a partial occupancy [0.585â (4)] CHCl3 solvent mol-ecule. The dihedral angles between the indole ring system and pendant nitro-benzodioxolane rings system and phenyl-sulfonyl ring are 4.81â (14) and 72.24â (19)°, respectively. In the crystal, the indole mol-ecules are linked to each other and to the chloro-form mol-ecule by weak C-Hâ¯O, C-Hâ¯Cl, C-Hâ¯π, C-Brâ¯π and C-Clâ¯π and aromatic π-π stacking inter-actions. A Hirshfeld surface analysis was carried out and the inter-molecular contacts with the most significant contributions are Hâ¯O/Oâ¯H (24.3%), Hâ¯H (18.4%), Brâ¯H/Hâ¯Br (16.8%) and Câ¯H/Hâ¯C (8.4%).