Nanomaze Lure: Pheromone Sandwich in Graphene Oxide Interlayers for Sustainable Targeted Pest Control.

The indiscriminate use of pesticides leads to irreparable damage to the ecosystem, which motivates for sustainable alternatives like pheromone-assisted pest management. The tomato pinworm Tuta absoluta is a major threat to tomato cultivation. Moreover, its green management technology uses a pheromone trap that has a short field life. To overcome this problem, a pheromone composite with graphene oxide (GO) and amine-modified graphene oxide (AGO) that can extend the diffusion path has been developed. The composite stimulates an effective electrophysiological response in the antenna, which results in trapping of a significantly higher number of insects as compared to the commercial septa, thus qualifying it for field evaluation. Compared to AGO, the GO composite has pheromones assembled into a multilayer, which increases the pheromone diffusion path. This in turn resulted in the extension of the pheromone life that proportionally increased the pest trapped. This technique will be beneficial to farmers as they have longer field efficacy to keep the pest damage low in an environmentally friendly manner.

Oxidative Dehydrogenation of Propane over a High Surface Area Boron Nitride Catalyst: Exceptional Selectivity for Olefins at High Conversion.

Developing environment-friendly active and selective catalysts for oxidative dehydrogenation of propane for on-purpose propene synthesis is challenging despite tremendous industrial potential for this reaction. Herein, we report on catalytic activity of high surface area hexagonal boron nitride, toward oxidative dehydrogenation of propane. It shows remarkable selectivity for alkenes (∼70%) at very high conversion (of ∼50%) of propane. Propene and ethene selectivities as high as 53 and 18%, respectively, were obtained at a conversion of 52%. The catalytic activity is retained continuously for 5 h. Regeneration in ammonia brings back the catalytic activity to its full potential. Oxidation of surface B-N bonds in oxygen leads to the diminishing catalytic activity after 5 h which, on heating in ammonia, reduced back to their native form, regaining the indigenous activity. Remarkably, the addition of ammonia in the reaction feed showed stable activity for more than 100 h.