Atomically Resolved Phase Coexistence in VO2 Thin Films.

Concurrent structural and electronic transformations in VO2 thin films are of 2-fold importance: enabling fine-tuning of the emergent electrical properties in functional devices, yet creating an intricate interfacial domain structure of transitional phases. Despite the importance of understanding the structure of VO2 thin films, a detailed real-space atomic structure analysis in which the oxygen atomic columns are also resolved is lacking. Moreover, intermediate atomic structures have remained elusive due to the lack of robust atomically resolved quantitative analysis. Here, we directly resolve both V and O atomic columns and discover the presence of intermediate monoclinic (M2) phase nanolayers (less than 2 nm thick) in epitaxially grown VO2 films on a TiO2 (001) substrate, where the dominant part of VO2 undergoes a transition from the tetragonal (rutile) phase to the monoclinic M1 phase. Strain analysis suggests that the presence of the M2 phase is related to local strain gradients near the TiO2/VO2 interface. We unfold the crucial role of imaging the spatial configurations of the oxygen anions (in addition to V cations) by utilizing atomic-resolution electron microscopy. Our approach can be used to unravel the structural transitions in a wide range of correlated oxides, offering substantial implications for, e.g., optoelectronics and ferroelectrics.

Evaluation of resistance and determination of stability of different sugar beet (Beta vulgaris L.) genotypes in rhizomania-infected conditions.

Plant diseases are considered one of the main factors reducing yield and quality of crops, which are constantly developing and creating more virulent races and cause the resistance of more genes to break. Identifying resistance sources and including them in breeding programs will improve resistant genotypes. Rhizomania is the most common, widespread, and devastating disease of sugar beet in Iran and worldwide. Breeding genotypes with disease resistance genes is one of the most important ways to deal with this destructive disease. Twenty sugar beet genotypes along with five controls were evaluated in a randomized complete block design with four replications in rhizomania-infected conditions in four regions of Mashhad, Shiraz, Miandoab, and Hamedan for 2 years. The results of genotypic reaction to rhizomania showed that the genotypes with resistance reaction were much more frequent than those with susceptibility reaction. The analysis of multiplicative effects of the AMMI model showed that the first six components were significant and explained 98.80% of the interaction variations. The biplot obtained from the mean white sugar yield and the first interaction principal component confirmed the superiority of the RM5 genotype due to its high white sugar yield and stability in infected conditions. The results obtained from the first three principal components biplot showed that the RM9 genotype with a mean white sugar yield of 11.91 t. ha-1 was a genotype with vast general stability in all disease-infected environments. Based on the results of the MTSI index, RM3, RM17, RM9, RM13, and RM15 are introduced as stable genotypes under rhizomania-infected conditions. In conclusion, it seems that the studied genotypes have valuable and useful genes inherited from their parents to deal with rhizomania disease. Applying these genotypes in sugar beet breeding programs can effectively prevent the threat of rhizomania.

Provision of extended producer responsibility system for products packaging: A case study of Iran.

A powerful legal tool in evolving solid waste management (SWM) systems is extended producer responsibility (EPR). It is a mechanism that shifts the responsibility of a product to manufacturers/importers at the 'end-of-life' stage. Yet, implementation of the EPR concept has faced difficulties in developing countries. In Iran, as one such country, the principle of EPR system was issued in executive regulation of SWM in 2005, however, so far, it has been limited to a voluntary scheme. The problem merits further investigation. Therefore, this study aims to shed light on the obstacles in the path of developing EPR system for product packaging. The research examines the current SWM systems in four functional classified frameworks: legal, institutional, financial and technical. The strengths, weaknesses, opportunities and threats of the system are elaborated through semi-structured interviews with a senior executive in the Ministry of Interior (MoI). Then, viable methods to increase resource efficiency and sustainable waste treatment are suggested. The change in the financing mechanism in the Budget Law 2020 forces the manufacturers/importers of products containing recyclable components to pay the revenue from one in 1000 products to MoI for developing recycling facilities and incinerators through partnerships with the private sector. This new strategy would promote proper management of product packaging, create more jobs and a market for international cooperation. However, poor source-separation of wet/dry waste, informal sector activities, exclusive focus on the economic aspect of waste management, lack of expertise and public awareness campaigns are the barriers in this regard.

Relation between Oral Health Status and Electrocardiogram ST Segment Changes in a Group of Patients with Myocardial Infarction.

Background and aims. Only half to two-thirds of cardiovascular diseases can be explained by the classic risk factors. It is believed that chronic oral inflammation is a potent risk factor for systemic diseases. Studies show that electrocardiogram ST segment changes can be predictive of myocardial infarction outcome. In this study the relation between electrocardio-gram ST segment changes and oral health is evaluated. Materials and methods. In this cross-sectional study, thirty-six patients (14 females and 22 males) with myocardial infarction were enrolled. Oral health indices including DMFT index, probing depth, clinical attachment loss and bleeding on probing were recorded for each patient. DMFT index, PD, CAL as continuous variables and BOP as a categorical variable were compared with ST segment changes by independent t-test and chi-squared test, respectively (α=0.05). Results. DMFT index, BOP and PD revealed no statistically significant relation with ST segment groups. CAL showed a statistically significant difference within ST segment groups (P=0.003, OR=1.68). Conclusion. Clinical attachment loss was significantly higher in patients with ST segment depression, while no correla-tion was seen between probing depth, bleeding on probing and DMFT index with ST segment elevation or depression.

A retrospective comparative study on clinico-pathologic features of oral lichen planus and oral lichenoid lesions.

INTRODUCTION: Oral Lichen Planus (OLP) and Oral Lichenoid Lesions (OLLs) are clinically and histopathologically similar lesions but with different etiologies and treatment plan, thus differentiating these two has been the center of many researches. Studies in different populations have been performed on clinical and histopathologic features of OLP and OLLs. Thus aim of the present study was to evaluate and also compare the clinical and histopathologic features of these two diseases in a 10-year period in Esfahan. MATERIALS AND METHODS: This descriptive-analytic study was based on retrospective survey of 232 records with clinical and histopathologic diagnosis of OLP and OLLs available from archive of oral pathology, Esfahan dental school 2000-2010. Data was statistically analyzed by use of independent t-test, Fisher exact, and Chi-square. RESULTS: Involvement of lip was the only clinically significant difference between OLP and OLLs, most seen in OLLs. Band-like inflammatory infiltrate mainly composed of lymphocyte, saw toothed rete ridges, Max Joseph space, and atrophic epithelium was significantly seen in OLP. While hyperkeratosis, deep connective tissue infiltrate composed of eosinophil, neutrophil, and plasma cell were seen in OLLs. CONCLUSION: Involvement of lip was the only clinically significant difference between OLP and OLLs. Histopathologically strict band like infiltration, atrophic epithelium, saw toothed rete ridges, and Max Joseph space are reliable criteria for differentiation of OLP as deep connective tissue infiltration and hyperparakeratosis are for diagnosis of OLLs.

Retinoic acid metabolism inhibition by 3-azolylmethyl-1H-indoles and 2, 3 or 5-(alpha-azolylbenzyl)-1H-indoles.

Among a library of 70 azoles, 8 indole derivatives substituted in the 2-, 3- or 5- position with an azolylmethyl or alpha-azolylbenzyl chain were evaluated for retinoic acid (RA) metabolism inhibitory activity. The most active inhibitors identified in this study were 5-bromo-1-ethyl-3-methyl-2-[(phenyl)(1H-1,2,4-triazol-1-yl)methyl]-1H-indole (3) (68.9% inhibition) and 5-bromo-1-ethyl-2-[(4-fluorophenyl) (1H-1,2,4-triazol-1-yl)methyl]-3-methyl-1H-indole (6) (60.4% inhibition). At the same concentration (100 microM) ketoconazole exerted similar inhibitory effect (70% inhibition).