Spreading and Capillary Imbibition of Viscous Oil Lens into an Open-Cell Porous Structure.

Oil pollution in the ocean is becoming more and more of a serious issue, which increases interest in both ways for combating its cause and methods for observing and monitoring how oil spreads. A promising approach based on an optical method with empirical relations for selected viscous oil-water systems is presented. Based on a modified melamine sponge (MMS), the microscopic spreading and oil capillary penetration phenomenon of the porous structure were investigated. The objective of this study is 2-fold: (i) to present a more thorough experimental description of the spreading of viscous oil lens on the water surface and capillary action of oil lens into MMS porous structure; and (ii) to provide a theoretical description that helps to explain some of the observed behavior. With knowledge of δ∞2=-2SρW/gρO(ρW-ρO), we can determine the spreading coefficient S. It needs to be pointed out that the oil lens floating on the water surface does satisfy Neumann's rule as the spreading coefficient of the air-oil-water system is negative (- 9.8 mN/m), indicating the ability to form a stable oil lens with thickness δO = 3.04 mm and radius RL = 38.64 mm after 60 min of spreading test. Furthermore, to better understand the capillary phenomena from a mechanical approach, an oil lens in contact with the surface of the MMS porous structure, by in-depth visualization, is properly defined as the balance of forces acting. Finally, as an illustration of this method, we utilized this approach to obtain the equilibrium height of the capillary rise and take it into account in terms of effective material thickness.

Nanostructured micro/mesoporous graphene: removal performance of volatile organic compounds.

In this study, we demonstrate an integrated synthesis strategy, which is conducted by the thermochemical process, consisting of pre- and post-activation by thermal treatment and KOH activation for the reduction of graphite oxide. A large number of interconnected pore networks with a micro/mesoporous range were constructed on a framework of graphene layers with a specific surface area of up to 1261 m2 g-1. This suggests a synergistic effect of thermally exfoliated graphene oxide (TEGO) on the removal efficiency of volatile organic compounds by generating pore texture with aromatic adsorbates such as benzene, toluene, and o-xylene (denoted as BTX) from an inert gaseous stream concentration of 100 ppm. As a proof of concept, TEGO, as well as pre- and post-activated TEGO, were used as adsorbents in a self-designed BTX gas adsorption apparatus, which exhibited a high removal efficiency of up to 98 ± 2%. The distinctive structure of TEGO has a significant effect on removal performance, which will greatly facilitate the strategy of efficient VOC removal configurations.

Advanced Boiling-A Scalable Strategy for Self-Assembled Three-Dimensional Graphene.

Currently, researchers are paying much attention to the development of effective 3D graphene for applications in energy storage and environmental purification. Before commercialization, however, it is necessary to develop a method that allows for the large-scale production of such materials and enables good control over their structural and chemical properties. With this objective, we herein developed a simple method for the formation of large-scale (4 in. wafer) 3D graphene networks via the self-assembly of graphene sheets at a superheated liquid-vapor interface. The structural morphology of this porous network could be modified by controlling the vaporization rate, surface temperature of the target substrate, and amount of discharged colloids. The key mechanism behind this intriguing result was investigated by high-speed visualization of microdroplet behavior and extensive thermal analysis. This self-assembled 3D graphene had excellent electrical and mechanical properties. Our approach can be directly used for the mass production of graphene-based materials.

Building with graphene oxide: effect of graphite nature and oxidation methods on the graphene assembly.

During nearly 2 centuries of history in graphene researches, numerous researches were reported to synthesize graphene oxide (GO) and build a proper graphene assembly. However, tons of research prevail without verifying the reproducibility of GO that can be sensitively attributed by the graphite nature, and chemical processes. Here, the structure and chemistry of GO products were analyzed by considering parent graphite sources, and three different oxidation methods based on Hummer's method and the addition of H3PO4. The oxidation level of GO was characterized by monitoring the C/O and sp2 carbon ratio from X-ray photoelectroscopy (XPS) spectra. It was observed that the oxidant intercalation behavior was dependent on the morphological differences of graphite; synthetic and natural flake graphite were compared based on their origins in shape and size from different suppliers. Thermal reduction and exfoliation were applied to GO powders to prepare thermally expanded graphene oxide (TEGO) as a graphene assembly. Gas releases from the reduction of oxygen functional groups split layered GO structure and build a porous structure that varied specific surface area regarding oxidation degrees of GO.

Virtual Loudspeaker Effect of Graphene-Based Hybrid Material To Improve Low-Frequency Acoustic Performance.

Closed-box loudspeaker systems (CBLSSs) are compact and simple air-suspension loudspeaker systems, and their low-frequency responses are determined by two fundamental parameters: resonance frequency and total damping. Recently, electronic devices have come to require more compact designs, so the volumes of loudspeaker should be reduced. However, a small loudspeaker cannot retain sufficient acoustic space, resulting in poor low-frequency acoustic performance. Herein, we investigated acoustic characterization of the CBLSS with different filling materials such as thermally expanded graphene oxide (TEGO), activated carbon, graphene platelets, and melamine foam (MF). Upon the powder-based test, the resonance frequency of the loudspeaker decreased and resulted in a volume increasing effect inside of the loudspeaker. The TEGO shows almost double volume increase rate, compared to other particle-based filling materials. Employing hybrid filling material that consists of TEGO in an MF cage (TEGO@MF), the volume increase rate of the novel loudspeaker was over 24% at 300 cc. Because of the high adsorptive characteristics and thermal properties of TEGO, the acoustic performance in the low-frequency domain was clearly enhanced, despite the reduced mass loading. Furthermore, these properties were observed to be highly effective for enhancing the low-frequency acoustic performance of the larger loudspeaker, achieving a volume increase rate of 49.5% in a 700 cc enclosure.

Mesoporous graphene adsorbents for the removal of toluene and xylene at various concentrations and its reusability.

As novel technologies have been developed, emissions of gases of volatile organic compounds (VOCs) have increased. These affect human health and are destructive to the environment, contributing to global warming. Hence, regulations on the use of volatile organic compounds have been strengthened. Therefore, powerful adsorbents are required for volatile organic compounds gases. In this study, we used graphene powder with a mesoporous structure to adsorb aromatic compounds such as toluene and xylene at various concentrations (30, 50, 100 ppm). The configuration and chemical composition of the adsorbents were characterized using scanning electron microscopy (SEM), N2 adsorption-desorption isotherm measurements, and X-ray photoelectron spectroscopy (XPS). The adsorption test was carried out using a polypropylene filter, which contained the adsorbents (0.25 g), with analysis performed using a gas detector. Compared to graphite oxide (GO) powder, the specific surface area of thermally expanded graphene powder (TEGP800) increased significantly, to 542 m2 g-1, and its chemical properties transformed from polar to non-polar. Thermally expanded graphene powder exhibits high adsorption efficiency for toluene (92.7-98.3%) and xylene (96.7-98%) and its reusability is remarkable, being at least 91%.

Toluene and acetaldehyde removal from air on to graphene-based adsorbents with microsized pores.

Volatile organic compound (VOC) gases can cause harm to the human body with exposure over the long term even at very low concentrations (ppmv levels); thus, effective absorbents for VOC gas removal are an important issue. In this study, accordingly, graphene-based adsorbents with microsized pores were used as adsorbents to remove toluene and acetaldehyde gases at low concentrations (30ppm). Sufficient amounts of the adsorbents were prepared for use on filters and were loaded uniformly at 0.1-0.5g on a 50×50mm2 area, to evaluate their adsorption features with low gas concentrations. The morphology and chemical composition of the adsorbents were characterized using scanning electron microscopy, N2 adsorption-desorption isotherms, X-ray photoelectron spectroscopy, and Raman spectroscopy. Microwave irradiation and heat treatment near 800°C under KOH activation resulted in enlargement of the pristine graphene surface and its specific surface area; maximum volume capacities of 3510m3/g and 630m3/g were observed for toluene and acetaldehyde gas. The high removal efficiency for toluene (98%) versus acetaldehyde (30%) gas was attributed to π-π interactions between the pristine graphene surface and toluene molecules.

Loss of superhydrophobicity of hydrophobic micro/nano structures during condensation.

Condensed liquid behavior on hydrophobic micro/nano-structured surfaces is a subject with multiple practical applications, but remains poorly understood. In particular, the loss of superhydrophobicity of hydrophobic micro/nanostructures during condensation, even when the same surface shows water-repellant characteristics when exposed to air, requires intensive investigation to improve and apply our understanding of the fundamental physics of condensation. Here, we postulate the criterion required for condensation to form from inside the surface structures by examining the grand potentials of a condensation system, including the properties of the condensed liquid and the conditions required for condensation. The results imply that the same hydrophobic micro/nano-structured surface could exhibit different liquid droplet behavior depending on the conditions. Our findings are supported by the observed phenomena: the initiation of a condensed droplet from inside a hydrophobic cavity, the apparent wetted state changes, and the presence of sticky condensed droplets on the hydrophobic micro/nano-structured surface.

Dynamics of contact line depinning during droplet evaporation based on thermodynamics.

For several decades, evaporation phenomena have been intensively investigated for a broad range of applications. However, the dynamics of contact line depinning during droplet evaporation has only been inductively inferred on the basis of experimental data and remains unclear. This study focuses on the dynamics of contact line depinning during droplet evaporation based on thermodynamics. Considering the decrease in the Gibbs free energy of a system with different evaporation modes, a theoretical model was developed to estimate the receding contact angle during contact line depinning as a function of surface conditions. Comparison of experimentally measured and theoretically modeled receding contact angles indicated that the dynamics of contact line depinning during droplet evaporation was caused by the most favorable thermodynamic process encountered during constant contact radius (CCR mode) and constant contact angle (CCA mode) evaporation to rapidly reach an equilibrium state during droplet evaporation.

Enhanced heat transfer is dependent on thickness of graphene films: the heat dissipation during boiling.

Boiling heat transfer (BHT) is a particularly efficient heat transport method because of the latent heat associated with the process. However, the efficiency of BHT decreases significantly with increasing wall temperature when the critical heat flux (CHF) is reached. Graphene has received much recent research attention for applications in thermal engineering due to its large thermal conductivity. In this study, graphene films of various thicknesses were deposited on a heated surface, and enhancements of BHT and CHF were investigated via pool-boiling experiments. In contrast to the well-known surface effects, including improved wettability and liquid spreading due to micron- and nanometer-scale structures, nanometer-scale folded edges of graphene films provided a clue of BHT improvement and only the thermal conductivity of the graphene layer could explain the dependence of the CHF on the thickness. The large thermal conductivity of the graphene films inhibited the formation of hot spots, thereby increasing the CHF. Finally, the provided empirical model could be suitable for prediction of CHF.

A novel role of three dimensional graphene foam to prevent heater failure during boiling.

We report a novel boiling heat transfer (NBHT) in reduced graphene oxide (RGO) suspended in water (RGO colloid) near critical heat flux (CHF), which is traditionally the dangerous limitation of nucleate boiling heat transfer because of heater failure. When the heat flux reaches the maximum value (CHF) in RGO colloid pool boiling, the wall temperature increases gradually and slowly with an almost constant heat flux, contrary to the rapid wall temperature increase found during water pool boiling. The gained time by NBHT would provide the safer margin of the heat transfer and the amazing impact on the thermal system as the first report of graphene application. In addition, the CHF and boiling heat transfer performance also increase. This novel boiling phenomenon can effectively prevent heater failure because of the role played by the self-assembled three-dimensional foam-like graphene network (SFG).

Self-assembled foam-like graphene networks formed through nucleate boiling.

Self-assembled foam-like graphene (SFG) structures were formed using a simple nucleate boiling method, which is governed by the dynamics of bubble generation and departure in the graphene colloid solution. The conductivity and sheet resistance of the calcined (400°C) SFG film were 11.8 S·cm(-1) and 91.2 Ω□(-1), respectively, and were comparable to those of graphene obtained by chemical vapor deposition (CVD) (~10 S·cm(-1)). The SFG structures can be directly formed on any substrate, including transparent conductive oxide (TCO) glasses, metals, bare glasses, and flexible polymers. As a potential application, SFG formed on fluorine-doped tin oxide (FTO) exhibited a slightly better overall efficiency (3.6%) than a conventional gold electrode (3.4%) as a cathode of quantum dot sensitized solar cells (QDSSCs).

Wicking and spreading of water droplets on nanotubes.

Recently, there has been intensive research on the use of nanotechnology to improve the wettability of solid surfaces. It is well-known that nanostructures can improve the wettability of a surface, and this is a very important safety consideration in regard to the occurrence of boiling crises during two-phase heat transfer, especially in the operation of nuclear power plant systems. Accordingly, there is considerable interest in wetting phenomena on nanostructures in the field of nuclear heat transfer. Much of the latest research on liquid absorption on a surface with nanostructures indicates that liquid spreading is generated by capillary wicking. However, there has been comparatively little research on how capillary forces affect liquid spreading on a surface with nanotubes. In this paper, we present a visualization of liquid spreading on a zircaloy surface with nanotubes, and establish a simple quantitative method for measuring the amount of water absorbed by the nanotubes. We successfully describe liquid spreading on a two-dimensional surface via one-dimensional analysis. As a result, we are able to postulate a relationship between liquid spreading and capillary wicking in the nanotubes.